ChemicalBook >> CAS DataBase List >>3,5-Bis(trifluoromethyl)benzyl bromide

3,5-Bis(trifluoromethyl)benzyl bromide

CAS No.
32247-96-4
Chemical Name:
3,5-Bis(trifluoromethyl)benzyl bromide
Synonyms
1-(BROMOMETHYL)-3,5-BIS(TRIFLUOROMETHYL)BENZENE;5-Bis(trifluoroMethyl)benzyl broMide;3,5-Bis(trifluoremethyl)benzylbromide;3,5-BIS(TRIFLUOROMETHYL)BENZYL BROMIDE;3,5-DI(TRIFLUORO METHYL)BENZYL BROMIDE;3,5-Bis(trifluoromethyl)benzylbromiode;3,5-Bis(trifluoromethyl)benzylbromide98%;3,5-Bis(trifluoromethyl)benzyl bromide 98%;3,5-Bis(trifluoromethyl)benzyl Bromide >3,5-Bis(trifluoromethyl)benzyl bromide, 97+%
CBNumber:
CB8709789
Molecular Formula:
C9H5BrF6
Molecular Weight:
307.03
MDL Number:
MFCD00009905
MOL File:
32247-96-4.mol
MSDS File:
SDS
Last updated:2023-12-25 17:47:29

3,5-Bis(trifluoromethyl)benzyl bromide Properties

Melting point 18°C
Boiling point 136-140°C 14mm
Density 1.675 g/mL at 25 °C(lit.)
refractive index n20/D 1.445(lit.)
Flash point 79 °F
storage temp. Inert atmosphere,2-8°C
solubility Difficult to mix.
form Liquid
color Clear colorless to yellow-brown
Specific Gravity 1.675
Sensitive Lachrymatory
BRN 656506
CAS DataBase Reference 32247-96-4(CAS DataBase Reference)
NIST Chemistry Reference 3,5-Bis(trifluoromethyl)benzyl bromide(32247-96-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C,F
Risk Statements  10-34
Safety Statements  26-36/37/39-45-25-16
RIDADR  UN 2920 8/PG 2
WGK Germany  3
Hazard Note  Corrosive/Lachrymatory
HazardClass  8
PackingGroup  III
HS Code  29039990
NFPA 704
3
3 0

3,5-Bis(trifluoromethyl)benzyl bromide price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 263397 3,5-Bis(trifluoromethyl)benzyl bromide 97% 32247-96-4 1g $26.5 2024-03-01 Buy
Sigma-Aldrich 263397 3,5-Bis(trifluoromethyl)benzyl bromide 97% 32247-96-4 5g $63 2024-03-01 Buy
TCI Chemical B1867 3,5-Bis(trifluoromethyl)benzyl Bromide >96.0%(GC) 32247-96-4 5g $37 2024-03-01 Buy
TCI Chemical B1867 3,5-Bis(trifluoromethyl)benzyl Bromide >96.0%(GC) 32247-96-4 25g $146 2024-03-01 Buy
Alfa Aesar A19590 3,5-Bis(trifluoromethyl)benzyl bromide, 98% 32247-96-4 1g $37.6 2021-12-16 Buy
Product number Packaging Price Buy
263397 1g $26.5 Buy
263397 5g $63 Buy
B1867 5g $37 Buy
B1867 25g $146 Buy
A19590 1g $37.6 Buy

3,5-Bis(trifluoromethyl)benzyl bromide Chemical Properties,Uses,Production

Chemical Properties

White or Colorles to Yellow to Orange powder to lump to clear liquid

Uses

3,5-Bis(trifluoromethyl)benzyl bromide is used as derivatization reagent in detection of uracil in DNA by GC and negative chemical ionization mass spectrometry in enantioselective synthesis of non-peptidic neurokinin NK1 receptor antagonist.

Synthesis

Synthesis of 3, 5-bis (trifluoromethyl)-benzyl bromide:
In a 4-neck flask with capacity 1000 ml equipped with mechanical agitator, thermometer, bubble condenser and 100 ml loading funnel, 262.2 g of the product of Example 1 (ii) at 92. 8% (0. 988 moles), 550,2 g HBr 48% (3.2645 moles) are loaded; this is heated at 50°C so as to melt the alcohol, then one starts to dose 113 g of concentrated His04 (1.153 moles). Pouring is accomplished in 30 minutes, noting an increase of the internal temperature. This is heated to 100-105°C and left to react for 8 hours. The reaction is completed by reflux heating for per 1.5 hours. the mixture is left to settle and the phases are separated; the solvents are removed from the organic phase and the product in the title is obtained with a yield of 99.1 %.
Synthesis of 3, 5-bis (trifluoromethyl)-benzyl bromide.png

3,5-Bis(trifluoromethyl)benzyl bromide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 301)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20286 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29881 58
Changzhou Ansciep Chemical Co., Ltd.
+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 8497 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10821 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58

View Lastest Price from 3,5-Bis(trifluoromethyl)benzyl bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3,5-Bis(trifluoromethyl)benzyl bromide pictures 2023-12-26 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
3,5-Bis(trifluoromethyl)benzyl bromide pictures 2022-09-16 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
	3,5-Bis(trifluoromethyl)benzyl bromide pictures 2019-09-02 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
US $7.00 / KG 1KG 99% JD 500 Career Henan Chemical Co
3,5-Bis(trifluoromethyl)benzyl bromide, 97+% 5-Bis(trifluoroMethyl)benzyl broMide 3,5-Bis(trifluoremethyl)benzylbromide 1,3-Bis(trifluoromethyl)-5-(bromomethyl)benzene 3,5-Bis(trifluoromethyl)benzylbromiode {[3,5-bis(trifluoroMethyl)phenyl]Methyl}broManuide 3,5-Bis(trifluoroMethyl)benzyl broMide, 97% 1GR Benzene,1-(broMoMethyl)-3,5-bis(trifluoroMethyl)- 3, 5 - double three fluorinated Methyl benzyl broMide 3,5-DI(TRIFLUORO METHYL)BENZYL BROMIDE 3,5-BIS(TRIFLUOROMETHYL)BENZYL BROMIDE 1-(BROMOMETHYL)-3,5-DI(TRIFLUOROMETHYL)BENZENE 3,5-Di(Trifluoro Methyl)Benzyl Bromide 3,5-bis(Trifluoromethyl)benzyl Bromide 3,5-Bis(trifluoromethyl)benzyl bromide 98% 3,5-Bis(trifluoromethyl)benzylbromide98% 1-(Bromomethyl)-3,5-bis(trifluoromethyl)benzene1,3-Ditrifluoromethyl-5-bromobenzene 3,5-Bis(trifluoromethyl)benzyl Bromide > 3,5-Bis(trifluoromethyl)benzyl bromide ISO 9001:2015 REACH 1-(BROMOMETHYL)-3,5-BIS(TRIFLUOROMETHYL)BENZENE 32247-96-4 CF32C6H3CH2Br C9H5BrF6 Organic Building Blocks Halogenated Hydrocarbons Building Blocks C9 to C12 Aryl Aromatic Halides (substituted) Fluorides