3,5-Bis(trifluoromethyl)benzyl bromide
- CAS No.
- 32247-96-4
- Chemical Name:
- 3,5-Bis(trifluoromethyl)benzyl bromide
- Synonyms
- 1-(BROMOMETHYL)-3,5-BIS(TRIFLUOROMETHYL)BENZENE;5-Bis(trifluoroMethyl)benzyl broMide;3,5-Bis(trifluoremethyl)benzylbromide;3,5-BIS(TRIFLUOROMETHYL)BENZYL BROMIDE;3,5-DI(TRIFLUORO METHYL)BENZYL BROMIDE;3,5-Bis(trifluoromethyl)benzylbromiode;3,5-Bis(trifluoromethyl)benzylbromide98%;3,5-Bis(trifluoromethyl)benzyl bromide 98%;3,5-Bis(trifluoromethyl)benzyl Bromide >3,5-Bis(trifluoromethyl)benzyl bromide, 97+%
- CBNumber:
- CB8709789
- Molecular Formula:
- C9H5BrF6
- Molecular Weight:
- 307.03
- MDL Number:
- MFCD00009905
- MOL File:
- 32247-96-4.mol
- MSDS File:
- SDS
Melting point | 18°C |
---|---|
Boiling point | 136-140°C 14mm |
Density | 1.675 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | 79 °F |
storage temp. | Inert atmosphere,2-8°C |
solubility | Difficult to mix. |
form | Liquid |
color | Clear colorless to yellow-brown |
Specific Gravity | 1.675 |
Sensitive | Lachrymatory |
BRN | 656506 |
CAS DataBase Reference | 32247-96-4(CAS DataBase Reference) |
NIST Chemistry Reference | 3,5-Bis(trifluoromethyl)benzyl bromide(32247-96-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H226-H314 | |||||||||
Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | C,F | |||||||||
Risk Statements | 10-34 | |||||||||
Safety Statements | 26-36/37/39-45-25-16 | |||||||||
RIDADR | UN 2920 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Corrosive/Lachrymatory | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29039990 | |||||||||
NFPA 704 |
|
3,5-Bis(trifluoromethyl)benzyl bromide price More Price(33)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 263397 | 3,5-Bis(trifluoromethyl)benzyl bromide 97% | 32247-96-4 | 1g | $26.5 | 2024-03-01 | Buy |
Sigma-Aldrich | 263397 | 3,5-Bis(trifluoromethyl)benzyl bromide 97% | 32247-96-4 | 5g | $63 | 2024-03-01 | Buy |
TCI Chemical | B1867 | 3,5-Bis(trifluoromethyl)benzyl Bromide >96.0%(GC) | 32247-96-4 | 5g | $37 | 2024-03-01 | Buy |
TCI Chemical | B1867 | 3,5-Bis(trifluoromethyl)benzyl Bromide >96.0%(GC) | 32247-96-4 | 25g | $146 | 2024-03-01 | Buy |
Alfa Aesar | A19590 | 3,5-Bis(trifluoromethyl)benzyl bromide, 98% | 32247-96-4 | 1g | $37.6 | 2021-12-16 | Buy |
3,5-Bis(trifluoromethyl)benzyl bromide Chemical Properties,Uses,Production
Chemical Properties
White or Colorles to Yellow to Orange powder to lump to clear liquid
Uses
3,5-Bis(trifluoromethyl)benzyl bromide is used as derivatization reagent in detection of uracil in DNA by GC and negative chemical ionization mass spectrometry in enantioselective synthesis of non-peptidic neurokinin NK1 receptor antagonist.
Synthesis
Synthesis of 3, 5-bis (trifluoromethyl)-benzyl bromide:
In a 4-neck flask with capacity 1000 ml equipped with mechanical agitator, thermometer, bubble condenser and 100 ml loading funnel, 262.2 g of the product of Example 1 (ii) at 92. 8% (0. 988 moles), 550,2 g HBr 48% (3.2645 moles) are loaded; this is heated at 50°C so as to melt the alcohol, then one starts to dose 113 g of concentrated His04 (1.153 moles). Pouring is accomplished in 30 minutes, noting an increase of the internal temperature. This is heated to 100-105°C and left to react for 8 hours. The reaction is completed by reflux heating for per 1.5 hours. the mixture is left to settle and the phases are separated; the solvents are removed from the organic phase and the product in the title is obtained with a yield of 99.1 %.
3,5-Bis(trifluoromethyl)benzyl bromide Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20286 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29881 | 58 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
View Lastest Price from 3,5-Bis(trifluoromethyl)benzyl bromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-12-26 | 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2022-09-16 | 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
2019-09-02 | 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
|
US $7.00 / KG | 1KG | 99% | JD 500 | Career Henan Chemical Co |
- 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- 3,5-Bis(trifluoromethyl)benzyl bromide
32247-96-4
- US $7.00 / KG
- 99%
- Career Henan Chemical Co
32247-96-4(3,5-Bis(trifluoromethyl)benzyl bromide)Related Search:
1of4