5-Bromopyrimidine
- CAS No.
- 4595-59-9
- Chemical Name:
- 5-Bromopyrimidine
- Synonyms
- 5-bromo-pyrimidin;5-pyriMidine;5-BROMOPYRIMIDINE;5-Bromo-1,3-diazine;PYRIMIDINE, 5-BROMO-;PYRIMIDINE, 2-BROMO-;5-Bromopyrimidine,98%;5-Bromopyrimidine >5-BROMOPYRIMIDINE 0.98;5 - broMine pyriMidine
- CBNumber:
- CB8853640
- Molecular Formula:
- C4H3BrN2
- Molecular Weight:
- 158.98
- MDL Number:
- MFCD00006117
- MOL File:
- 4595-59-9.mol
- MSDS File:
- SDS
Melting point | 67-73 °C (lit.) |
---|---|
Boiling point | 168°C(lit.) |
Density | 1.6448 (rough estimate) |
refractive index | 1.5260 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | Soluble in chloroform. |
pka | 1.40±0.10(Predicted) |
form | Crystalline Powder or Chunks |
color | Yellow to beige-brown |
BRN | 107326 |
CAS DataBase Reference | 4595-59-9(CAS DataBase Reference) |
FDA UNII | 5Z9X6MAT38 |
NIST Chemistry Reference | Pyrimidine, 5-bromo-(4595-59-9) |
EPA Substance Registry System | Pyrimidine, 5-bromo- (4595-59-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38-36/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | T | |||||||||
HazardClass | IRRITANT, KEEP COLD | |||||||||
HS Code | 29335990 | |||||||||
NFPA 704 |
|
5-Bromopyrimidine price More Price(40)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 219142 | 5-Bromopyrimidine 97% | 4595-59-9 | 5g | $49.2 | 2024-03-01 | Buy |
Sigma-Aldrich | 219142 | 5-Bromopyrimidine 97% | 4595-59-9 | 25g | $85.3 | 2024-03-01 | Buy |
TCI Chemical | B2229 | 5-Bromopyrimidine >98.0%(GC) | 4595-59-9 | 5g | $62 | 2024-03-01 | Buy |
TCI Chemical | B2229 | 5-Bromopyrimidine >98.0%(GC) | 4595-59-9 | 25g | $247 | 2024-03-01 | Buy |
Alfa Aesar | L14172 | 5-Bromopyrimidine, 98% | 4595-59-9 | 5g | $22.65 | 2024-03-01 | Buy |
5-Bromopyrimidine Chemical Properties,Uses,Production
Chemical Properties
yellow solid crystalline, insoluble in water, soluble in organic solvents such as benzene and toluene.
Uses
5-Bromopyrimidine was used in the synthesis of:
N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction
(5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol
Intermediate for the synthesis of plant growth regulator flurprimidol
Uses
5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction, (5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol.
Application
5-Bromopyrimidine is a compound useful in organic synthesis.
Preparation
5-Bromopyrimidine is prepared by reacting dibromodifuranone with formamide in the presence of B2O2 catalyst at 180-185°C to obtain the product.
General Description
Rapid nucleophilic displacement reactions of 5-bromopyrimidine with nucleophiles under microwave irradiation has been studied. 5-Bromopyrimidine undergoes direct metallation with lithuium diisopropylamide to yield 4-lithio-5-bromopyrimidine.
5-Bromopyrimidine Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7514 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5893 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18154 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18779 | 58 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9214 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2136 | 58 |
View Lastest Price from 5-Bromopyrimidine manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-22 | 5-Bromopyrimidine
4595-59-9
|
US $0.00 / kg | 1kg | 98%min | 100kg | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2024-11-04 | 5-Bromopyrimidine
4595-59-9
|
US $30.00-10.00 / KG | 50KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | ||
2024-11-04 | 5-Bromopyrimidine
4595-59-9
|
US $238.00 / g | 1g | 97% min. | 300kg | Zhengzhou Alfa Chemical Co.,Ltd |
- 5-Bromopyrimidine
4595-59-9
- US $0.00 / kg
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- 5-Bromopyrimidine
4595-59-9
- US $30.00-10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- 5-Bromopyrimidine
4595-59-9
- US $238.00 / g
- 97% min.
- Zhengzhou Alfa Chemical Co.,Ltd