phosphorodiamidic acid

CAS No.
10043-91-1
Chemical Name:
phosphorodiamidic acid
Synonyms
diaminophosphinic acid;Diamidophosphoric acid;phosphorodiamidic acid
CBNumber:
CB8911052
Molecular Formula:
H5N2O2P
Molecular Weight:
96.03
MDL Number:
MOL File:
10043-91-1.mol
Last updated:2022-12-21 16:56:50

phosphorodiamidic acid Properties

Density 1.668±0.06 g/cm3(Predicted)
pka 0.12±0.50(Predicted)
FDA UNII E0D8P3MX2C
EPA Substance Registry System Phosphorodiamidic acid (10043-91-1)

phosphorodiamidic acid Chemical Properties,Uses,Production

Synthesis

In the Stokes method, the synthesis of diamidophosphoric acid starts from the phenyl ester of dichlorophosphoric acid obtained from POC13 and phenol. This is converted with aqueous NH3 to the phenyl ester of diamidophosphoric acid. This ester is then saponified with Ba(OH)s ; the Ba2+ is precipitated as BaCO3, and the silver salt of diamidophosphoric acid is then obtained by precipitation with AgNO3. After reprecipitation of the silver salt, treatment with HBr results in very pure, free diamidophosphoric acid. The phenyl ester of diamidophosphoric acid can also be saponified with potassium hydroxide, and after acidification with acetic acid, the free diamidophosphoric acid can be precipitated with ethanol, yielding a somewhat less pure product. synthesis of diamidophosphoric acid

phosphorodiamidic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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phosphorodiamidic acid Diamidophosphoric acid diaminophosphinic acid 10043-91-1