1,6-Dibromopyrene
- CAS No.
- 27973-29-1
- Chemical Name:
- 1,6-Dibromopyrene
- Synonyms
- 6-DibroMopyrene;1,6-Dibromopyrene;1,6-dlbrornopyrone;Pyrene, 1,6-dibromo-;1,6-Dibromopyrene>1,6-Dibromopyrene ISO 9001：2015 REACH
- CBNumber:
- CB8947912
- Molecular Formula:
- C16H8Br2
- Molecular Weight:
- 360.04
- MDL Number:
- MFCD09263746
- MOL File:
- 27973-29-1.mol
- MSDS File:
- SDS
| Melting point | 228.0 to 232.0 °C |
|---|---|
| Boiling point | 469.6±18.0 °C(Predicted) |
| Density | 1.852±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform (Very Slightly, Heated), Methanol (Very Slightly, Heated) |
| form | Solid |
| color | White to Off-White |
| λmax | 246nm(EtOH)(lit.) |
| InChI | InChI=1S/C16H8Br2/c17-13-8-4-10-2-6-12-14(18)7-3-9-1-5-11(13)16(10)15(9)12/h1-8H |
| InChIKey | JRCJYPMNBNNCFE-UHFFFAOYSA-N |
| SMILES | C1(Br)=C2C3=C4C(C=C2)=CC=C(Br)C4=CC=C3C=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P305+P351+P338 | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39 | |||||||||
| HS Code | 29039990 | |||||||||
| NFPA 704 |
|
1,6-Dibromopyrene price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | D3167 | 1,6-Dibromopyrene >98.0%(GC) | 27973-29-1 | 1g | $31 | 2024-03-01 | Buy |
| TCI Chemical | D3167 | 1,6-Dibromopyrene >98.0%(GC) | 27973-29-1 | 5g | $89 | 2024-03-01 | Buy |
| TRC | D426073 | 1,6-Dibromopyrene | 27973-29-1 | 500mg | $60 | 2021-12-16 | Buy |
| TRC | D426073 | 1,6-Dibromopyrene | 27973-29-1 | 1g | $70 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD62827 | 1,6-Dibromopyrene | 27973-29-1 | 1g | $82 | 2021-12-16 | Buy |
1,6-Dibromopyrene Chemical Properties,Uses,Production
Description
1, 6-dibromopyrene is a kind of pyrene chemical. It is majorly used as organic intermediate, OLED (organic light-emitting diodes) materials and photoelectric material. It, together with its 1, 8- isomer, can be produced by the double bromination of pyrene with bromine. It can be applied to the synthesis of bipyridine and terpyridine based ruthenium metallosynthons.
Chemical Properties
white powder
Uses
1,6-Dibromopyrene is an important intermediate for the synthesis of perylene diimide (PDI) derivative host structures. Perylene diimide derivatives are one of several important classes of discotic liquid crystal molecules.
Synthesis
Specifically, pyrene (12.2g, 60 mmol) and 300 ml carbon tetrachloride are placed into a three-necked flask with a dropping funnel. Under room temperature, stirring, and nitrogen protection, bromine (11.5ml, 0.23mol) is dissolved in 50ml carbon tetrachloride, and then the solution is added to the reactor (the molar ratio of pyrene to bromine is 1:3.83). The mixed reaction solution is stirred at room temperature for 59 hours, then filtered, and the crude product is washed three times with 100ml methanol. The crude product is recrystallized with a mixed solvent of 260ml carbon tetrachloride and tetrahydrofuran to obtain 19.77g of pure 1,6-dibromopyrene, with a yield of 90.9% and a purity of 99.8%.
References
Goze, Christine, et al. "Synthesis of bipyridine and terpyridine based ruthenium metallosynthons for grafting of multiple pyrene auxiliaries."Tetrahedron letters 44.48 (2003): 8713-8716.
Kaplunov, Mikhail G., et al. "Novel 1, 8-bis(diarylamino)pyrenes as OLED materials." Mendeleev Communications 26.5(2016):437-439.
Gong, Xiaojie, et al. "Two Symmetrically Bis‐substituted Pyrene Derivatives: Synthesis, Photoluminescence, and Electroluminescence." Chinese Journal of Chemistry 33.8 (2015): 967-973.
1,6-Dibromopyrene Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shengyan (Shanghai) New Material Co., Ltd. | +86-021-37596312 +8613585706261 | ken@syanchem.com | China | 178 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7688 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18151 | 58 |
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1085 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20283 | 58 |
| Hebei Ganmiao New material Technology Co., LTD | +86-17332992504 +86-17332992504 | sales8@hbganmiao.com | China | 300 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
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View Lastest Price from 1,6-Dibromopyrene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-26 | 1,6-Dibromopyrene
27973-29-1
|
US $12.00 / KG | 1KG | 99% | 100mt | Jinan Finer Chemical Co., Ltd | |
 |
2024-11-01 | 1,6-Dibromopyrene
27973-29-1
|
US $90.50-1235.00 / g | 5g | 0.99 | 10kg | Shanghai UCHEM Inc. | |
 |
2024-10-25 | 1,6-Dibromopyrene
27973-29-1
|
US $0.00 / kg | 1kg | 0.99 | 20 tons | Hebei Yanxi Chemical Co., Ltd. |
-
- 1,6-Dibromopyrene
27973-29-1
- US $12.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
-
- 1,6-Dibromopyrene
27973-29-1
- US $90.50-1235.00 / g
- 0.99
- Shanghai UCHEM Inc.
-
- 1,6-Dibromopyrene
27973-29-1
- US $0.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.