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N-Formylpiperidine

CAS No.
2591-86-8
Chemical Name:
N-Formylpiperidine
Synonyms
PIPERIDINE-1-CARBALDEHYDE;1-FORMYLPIPERIDINE;nfp;1-PIPERIDINECARBOXALDEHYDE;FORMYLPIPERIDINE;N-Formylpiperidin;1-FormyL;N-Formylpiperdine;1-formyl-piperidin;N-FORMYLPIPERIDINE
CBNumber:
CB9149092
Molecular Formula:
C6H11NO
Molecular Weight:
113.16
MDL Number:
MFCD00006483
MOL File:
2591-86-8.mol
MSDS File:
SDS
Last updated:2024-12-18 14:15:30

N-Formylpiperidine Properties

Melting point -31 °C
Boiling point 222 °C(lit.)
Density 1.019 g/mL at 25 °C(lit.)
vapor pressure 0.1 mm Hg ( 25 °C)
refractive index n20/D 1.484(lit.)
Flash point 197 °F
storage temp. Store below +30°C.
form Liquid
pka -0.44±0.20(Predicted)
Specific Gravity 1.02
color Clear colorless to slightly yellow
Water Solubility freely soluble
BRN 107697
Dielectric constant 26.149999999999999
CAS DataBase Reference 2591-86-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII ZIQ29H6CZG
NIST Chemistry Reference 1-Piperidinecarboxaldehyde(2591-86-8)
EPA Substance Registry System N-Formylpiperidine (2591-86-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H302-H311-H319
Precautionary statements  P264-P270-P280-P301+P312-P302+P352+P312-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  21/22-36/37/38
Safety Statements  26-36/37-36
RIDADR  UN 2810 6.1/PG 3
WGK Germany  3
RTECS  TN0380000
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29333999
NFPA 704
2
2 0

N-Formylpiperidine price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich F17407 1-Formylpiperidine 99% 2591-86-8 100g $70.8 2024-03-01 Buy
Sigma-Aldrich F17407 1-Formylpiperidine 99% 2591-86-8 500g $167.4 2024-03-01 Buy
TCI Chemical F0234 1-Formylpiperidine >98.0%(GC) 2591-86-8 25mL $26 2024-03-01 Buy
TCI Chemical F0234 1-Formylpiperidine >98.0%(GC) 2591-86-8 100mL $45 2024-03-01 Buy
Alfa Aesar B23452 1-Formylpiperidine, 99% 2591-86-8 50g $42.65 2024-03-01 Buy
Product number Packaging Price Buy
F17407 100g $70.8 Buy
F17407 500g $167.4 Buy
F0234 25mL $26 Buy
F0234 100mL $45 Buy
B23452 50g $42.65 Buy

N-Formylpiperidine Chemical Properties,Uses,Production

Description

This simple piperidine base has recently been discovered in the oxygenated fraction from Piper nigrum. The structure has been elucidated from chemical and spectroscopic data.

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID

Uses

Reactant for:

  • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate
  • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride
  • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides
  • Synthesis of alternating copolymers for organic photovoltaic applications
  • One-pot double functionalization of π-deficient heterocyclic lithium reagents
  • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds

Uses

Solvent for polar and nonpolar compounds, as well as many high polymers; gas absorption; plastics modifiers.

Definition

ChEBI: 1-Piperidinecarboxaldehyde is a member of piperidines.

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 42, p. 1655, 1994 DOI: 10.1248/cpb.42.1655
Synthetic Communications, 20, p. 447, 1990 DOI: 10.1080/00397919008052787

References

Debrauwere, Verzale, Bull. Soc. Chim. Belg., 84, 167 (1975)

110-89-4
64-18-6
2591-86-8
Synthesis of N-Formylpiperidine from Piperidine and Formic acid
Global( 336)Suppliers
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CONIER CHEM AND PHARMA LIMITED
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View Lastest Price from N-Formylpiperidine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Formylpiperidine pictures 2024-01-11 Formylpiperidine
2591-86-8
US $122.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Piperidine-1-carboxaldehyde pictures 2022-08-05 Piperidine-1-carboxaldehyde
2591-86-8
US $0.00-0.00 / kg 1kg 99% 10 tons Changzhou Rokechem Technology Co., Ltd.
n-formylpiperidine pictures 2021-11-15 n-formylpiperidine
2591-86-8
US $73.00 / g 100g 99% 500ton/Month Qiuxian Baitai New Material Co., LTD
1-formyl-piperidin 1-Piperidinecarbaldehyde N-Formylpiperdine 1-Formylpiperidine,99% N-Carbaldehyde piperidine N-Formylpiperidine for synthesis N-ForMylpiperidine, 99% 250ML 1-forMylpiperidin-1-iuM-1-yl N-Piperidinecarboxaldehyde 1-PIPERIDINECARBOXALDEHYDE, N-PIPERIDINECARBOXALDEHYDE 1-(2-ISOPROPYL PHENYL)PIPERAZINE N-FORMYL PIPERIDINE PIPERIDINE-1-CARBALDEHYDE TIMTEC-BB SBB004316 piperidine-N-carbaldehyde N-FORMYLPIPERIDINE 99+% Piperidine, 1-formyl- Piperidinoformamide PIPERIDINE-1-CARBOXALDEHYDE N'-FORMYL PIPERIDINE N-FORMYLPIPERIDINE 1-FormyL 1-Formylpiperidine> N-Formylpiperidin nfp 1-PIPERIDINECARBOXALDEHYDE 1-FORMYLPIPERIDINE FORMYLPIPERIDINE PIPERIDINE-1-CARBALDEHYDE 1-Piperidinecarboxaldehyde (6CI, 7CI, 8CI, 9CI, ACI) 2591-86-8 Alphabetic Analytical Chromatography Product Catalog Analytical Standards Building Blocks Piperidines FM - FZ Heterocyclic Building Blocks Piperidine