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Methabenzthiazuron

CAS No.
18691-97-9
Chemical Name:
Methabenzthiazuron
Synonyms
s25128;B-74283;bay74283;TRIBUNIL;Trubunil;BAY-5653;bayer5633;TRIBUNIL(R);preparation5633;methbenzthiazuron
CBNumber:
CB9197088
Molecular Formula:
C10H11N3OS
Molecular Weight:
221.28
MDL Number:
MFCD00055498
MOL File:
18691-97-9.mol
Last updated:2023-05-04 17:34:35

Methabenzthiazuron Properties

Melting point 119-120.5°
Density 1.2527 (rough estimate)
refractive index 1.6740 (estimate)
Flash point 11 °C
storage temp. APPROX 4°C
solubility DMSO, Methanol (Sparingly)
pka 12.83±0.46(Predicted)
color Off-White to Pale Beige
Water Solubility 59mg/L(20 ºC)
Merck 14,5939
BRN 196633
EWG's Food Scores 1
FDA UNII 82NPF43P0X
EPA Substance Registry System Methabenzthiazuron (18691-97-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS09
Signal word  Warning
Hazard statements  H410
Precautionary statements  P273-P391-P501
Hazard Codes  N,T,F
Risk Statements  50/53-39/23/24/25-23/24/25-11
Safety Statements  60-61-45-16-7
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  YR8980000
HazardClass  9
PackingGroup  III
HS Code  29342000
Toxicity LD50 in mice (mg/kg): >1000 orally; in male, female rats (mg/kg): >2500, >2500 orally; 540, 315 i.p. (Kimmerle, Lser)

Methabenzthiazuron price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 36156 Methabenzthiazuron PESTANAL 18691-97-9 100mg $51.2 2022-05-15 Buy
TCI Chemical M2334 Methabenzthiazuron 18691-97-9 100MG $55 2024-03-01 Buy
TRC M258880 Methabenzthiazuron 18691-97-9 5g $1110 2021-12-16 Buy
American Custom Chemicals Corporation AGR0000069 METHABENZTHIAZURON 95.00% 18691-97-9 5G $1520 2021-12-16 Buy
Medical Isotopes, Inc. 41292 Methabenzthiazuron 18691-97-9 5G $2120 2021-12-16 Buy
Product number Packaging Price Buy
36156 100mg $51.2 Buy
M2334 100MG $55 Buy
M258880 5g $1110 Buy
AGR0000069 5G $1520 Buy
41292 5G $2120 Buy

Methabenzthiazuron Chemical Properties,Uses,Production

Chemical Properties

White crystalline solid; melts at 120°C(248°F); insoluble in water [~59 ppm at20°C (68°F)], soluble in organic solvents.

Uses

Methabenzthiazuron is a benzothiazole and urea based herbicide used to control a spectrum of broad-leaved weeds and grasses crops. Methabenzthiazuron works via the inhibition of photosynthetic electron transport chain.

Uses

Selective herbicide.

Definition

ChEBI: Methabenzthiazuron is a member of benzothiazoles.

Health Hazard

Gupta and Singh (1985) investigated thetoxicity of tribunil in calves. Animals treatedwith 500 mg/kg orally developed toxicityin 36–48 hours. The symptoms includedincrease in body temperature, depression,and a progressive decrease in respiration rateand pulse rate. Necropsy findings in animalsthat died showed congestion of the lungs.Other organs affected were liver, kidney,urinary bladder, spleen, heart, and brain.A 75-mg/kg dose produced toxicity after2–3 weeks.

Metabolic pathway

When methabenzthiazuron is presowing applied to the soil of pea fields, three degradation products are detected as (2-benzothiazoyl)urea, 2- (methylamino)benzothiazole and 2- aminobenzothiazole. The latter two amines represent a majority of the soil bound residues.

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1-(2-benzothiazolyl)-1,3-dimethyl-ure 1,3-dimethyl-3-(2-benzthiazolyl)-harnstoff bay74283 bayer5633 metabenzthiazuron methbenzthiazuron n-methyl-n’-methyl-n’-(2-benzothiazolyl)urea preparation5633 1-(1,3-benzothiazol-2-yl)1,3-dimethylurea,methabenzthiazuron (ISO) Methabenzthiazuron 100mg [18691-97-9] 1-(benzo[d]thiazol-2-yl)-1,3-diMethylurea s25128 methyl-n'-methyl-n'-(2-benzothiazolyl)urea METHABENZTHIAZURON 1-(1,3-BENZOTHIAZOL-2-YL)-1,3-DIMETHYLUREA 1,3-dimethyl-3-(2-benzothiazolyl)urea 1-(2-BENZOTHIAZOLYL)-1,3-DIMETHYLUREA N-2-Benzothiazolyl-N,N'-dimethylurea METHABENZTHIAZURON PESTANAL(1(BENZOTHIA& METHABENZTHIAZURON PESTANAL METHABENZTHIAZURON, 100MG,NEAT Urea, N-2-benzothiazolyl-N,N-dimethyl- (9CI) Urea, N-2-benzothiazolyl-N,N-dimethyl- 1-(benzothiazol-2-yl)-1,3-dimethylurea methabenzthiazuron (iso,bsi) methabenzthiazuron solution methibenzuron (wssa) TRIBUNIL TRIBUNIL(R) METHABENTHIAZURONE methabenzthiazuron (ISO) 1-(1,3-benzothiazol-2-yl)1,3-dimethylurea Trubunil B-74283 BAY-5653 N-(Benzothiazol-2-yl)-N,N'-dimethylurea Methabenzthiazuron Solution, 100ppm Methabenzthiazuron@1000 μg/mL in Acetone Methabenzthiazuron @100 μg/mL in MeOH Methabenzthiazuron Standard C14960000 Methabenzthiazuron L14960000ALMethabenzthiazuron 10μg/mLin Acet XA14960000ALMethabenzthiazuron 100μg/mLin Ace Methabenzthiazuron 1000 μg/ml Ethyl acetate Demeton Impurity 3 18691-97-9 BENZOTHIAZOLE