3-Methyl-4-nitropyridine N-Oxide
- CAS No.
- 1074-98-2
- Chemical Name:
- 3-Methyl-4-nitropyridine N-Oxide
- Synonyms
- 3-Methyl-4-nitropyri;3-Methyl-4-nitro-1$l^{5;-4-nitropyridine N-Oxide;4-Nitro-B-picoline N-oxide;4-NITRO-3-PICOLINE N-OXIDE;4-Nitro-3-picoline 1-oxide;3-Picoline, 4-nitro-, 1-oxide;4-Nitro-beta-picoline N-oxide;4-Nitro-3-picoline-N-oxide 99%;3-Methyl-4-nitropyridin-1-oxid
- CBNumber:
- CB9205071
- Molecular Formula:
- C6H6N2O3
- Molecular Weight:
- 154.12
- MDL Number:
- MFCD00014626
- MOL File:
- 1074-98-2.mol
- MSDS File:
- SDS
Melting point | 135-139 °C |
---|---|
Boiling point | 277.46°C (rough estimate) |
Density | 1.4564 (rough estimate) |
refractive index | 1.5100 (estimate) |
storage temp. | 2-8°C |
pka | -1.22±0.10(Predicted) |
form | Crystalline Needles or Powder |
color | Yellow |
BRN | 140157 |
InChI | InChI=1S/C6H6N2O3/c1-5-4-7(9)3-2-6(5)8(10)11/h2-4H,1H3 |
InChIKey | SSOURMYKACOBIV-UHFFFAOYSA-N |
SMILES | C1[N+]([O-])=CC=C([N+]([O-])=O)C=1C |
CAS DataBase Reference | 1074-98-2(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 34OB5D19MK |
NIST Chemistry Reference | 4-Nitro-3-picoline-n-oxide(1074-98-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS08 |
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Signal word | Warning | |||||||||
Hazard statements | H302+H312+H332-H315-H319-H335-H351 | |||||||||
Precautionary statements | P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 40-20/21/22-36/37/38 | |||||||||
Safety Statements | 45-36/37-36-26-22 | |||||||||
RIDADR | 2811 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | UT5775000 | |||||||||
Hazard Note | Irritant/Possible Mutagen | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29333990 | |||||||||
NFPA 704 |
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3-Methyl-4-nitropyridine N-Oxide price More Price(23)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 370061 | 3-Methyl-4-nitropyridine N-oxide 98% | 1074-98-2 | 1g | $105 | 2024-03-01 | Buy |
Sigma-Aldrich | 370061 | 3-Methyl-4-nitropyridine N-oxide 98% | 1074-98-2 | 5g | $386 | 2024-03-01 | Buy |
TCI Chemical | N0527 | 3-Methyl-4-nitropyridine N-Oxide >97.0%(T) | 1074-98-2 | 5g | $123 | 2024-03-01 | Buy |
TCI Chemical | N0527 | 3-Methyl-4-nitropyridine N-Oxide >97.0%(T) | 1074-98-2 | 25g | $369 | 2024-03-01 | Buy |
Alfa Aesar | L06099 | 4-Nitro-3-picoline N-oxide, 98% | 1074-98-2 | 5g | $163 | 2021-12-16 | Buy |
3-Methyl-4-nitropyridine N-Oxide Chemical Properties,Uses,Production
Chemical Properties
yellow crystalline needles or powder
General Description
3-Methyl-4-nitropyridine N-Oxide (POM) is an efficient nonlinear optical organic material having a high nonlinear coefficient and achieving the parametric emission process within the desired spectral range (1–2 μm). POM crystallizes in the orthorhombic class, space group P212121, and point group 222. It is a positive biaxial crystal. It melts at 136°C and the nonlinear coefficient is deff=10 pm/V[1]. This compound exhibits a negative-linear-compressibility (NLC) region as well as exceptionally large positive thermal expansion. The initial compression of the weak supramolecular network in the molecular POM crystal is analogous to the hydrostatic responses of the framework crystals with much stronger cohesion forces. 3-Methyl-4-nitropyridine N-Oxide is a commercial NLO material for pico- and femtosecond optics in the near-IR range[2].
Synthesis
Nitration of picoline-N-oxide in the fourth position yields 3-Methyl-4-nitropyridine N-Oxide. Initially, Picoline-N-oxide (50 g) was melted at 38C and mixed with sulfuric acid (250 ml) in cold condition. Later, nitration of this mixture was done at room temperature by addition of sodium nitrate (70 g) and the solution was continuously stirred until all the solid particles dissolves. Temperature was increased slowly to 70C by keeping it in an oil bath and solution was stirred continuously for 2 h at this temperature. To ensure complete nitration, the solution was maintained about 95–100C for 12 h with continuous stirring. The reaction mixture was taken out from the oil bath and cooled. It is then poured over crushed ice and neutralized with ammonia solution till the pH reaches about 7–8. On cooling, bright yellow crystalline 3-Methyl-4-nitropyridine N-Oxide powder was obtained. It was washed and dried in vacuum[1].
References
[1] Boomadevi, S. , H. P. Mittal , and R. Dhansekaran . "Synthesis, crystal growth and characterization of 3-methyl 4-nitropyridine 1-oxide (POM) single crystals."Journal of Crystal Growth 261.1(2004):55-62.
[2] Cai, Weizhao , et al. "Anomalous compression of a weakly CHO bonded nonlinear optical molecular crystal." Journal of Materials Chemistry C 2.32(2014).
3-Methyl-4-nitropyridine N-Oxide Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 885 | 50 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29897 | 58 |
Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10260 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2967 | 58 |
Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10828 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
View Lastest Price from 3-Methyl-4-nitropyridine N-Oxide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2022-10-10 | 4-Nitro-3-picoline N-oxide
1074-98-2
|
US $0.00-0.00 / KG | 1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | ||
2021-10-19 | 4-Nitro-3-picoline N-oxide
1074-98-2
|
US $10.00 / KG | 1KG | 99% | 20 Tons | Hebei Zhanyao Biotechnology Co. Ltd | ||
2021-09-09 | 4-Nitro-3-picoline N-oxide
1074-98-2
|
US $1.10 / g | 1g | 99.00% | 100 Tons min | Dideu Industries Group Limited |
- 4-Nitro-3-picoline N-oxide
1074-98-2
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- 4-Nitro-3-picoline N-oxide
1074-98-2
- US $10.00 / KG
- 99%
- Hebei Zhanyao Biotechnology Co. Ltd
- 4-Nitro-3-picoline N-oxide
1074-98-2
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited