α,α'-(2,6-Piperidinediyl)bis(acetophenone)
- CAS No.
- 6035-31-0
- Chemical Name:
- α,α'-(2,6-Piperidinediyl)bis(acetophenone)
- Synonyms
- Norlobelanine;Isolobelanine;α,α'-(2,6-Piperidinediyl)bis(acetophenone);Ethanone, 2,2'-(2R,6S)-2,6-piperidinediylbis[1-phenyl-, rel-
- CBNumber:
- CB92358344
- Molecular Formula:
- C21H23NO2
- Molecular Weight:
- 321.41
- MDL Number:
- MOL File:
- 6035-31-0.mol
Last updated:2022-12-21 16:56:50
Melting point | 120-121° |
---|---|
Boiling point | 484.1±10.0 °C(Predicted) |
Density | 1.084±0.06 g/cm3(Predicted) |
pka | 9.05±0.10(Predicted) |
FDA UNII | 93749AEP09 |
α,α'-(2,6-Piperidinediyl)bis(acetophenone) Chemical Properties,Uses,Production
Description
This alkaloid from Lobelia in/lata Linn, and L. sessili/lora was originally designated isolobelanine but later shown to be norlobelanine. It gives well_x0002_crystallized salts including the hydrochloride, m.p. 201-2°C; nitrate, m.p. 193°C (dec.); methiodide, m.p. 183-4°C and the N-benzoyl derivative, m.p. l25-6°C. The N-methyl compound is lobelanine (q.v.). On reduction it gives first norlobeline and finally norlobelanidine (q.v.).
References
Wieland, Hermsen., Annalen, 444, 63 (1926)
Wieland, Drishaus., ibid, 473, 117 (1929)
Wieland, Koschkara, Dane., ibid, 473, 118 (1929)
Wieland, Koschkara., ibid, 473, 122 (1929)
α,α'-(2,6-Piperidinediyl)bis(acetophenone) Preparation Products And Raw materials
Raw materials
Preparation Products
Isolobelanine
Norlobelanine
α,α'-(2,6-Piperidinediyl)bis(acetophenone)
Ethanone, 2,2'-(2R,6S)-2,6-piperidinediylbis[1-phenyl-, rel-
6035-31-0