METSULFURON METHYL | 74223-64-6

METSULFURON METHYL Properties

Melting point	158°C
Boiling point	181°C (rough estimate)
Density	1.4561 (rough estimate)
refractive index	1.6460 (estimate)
storage temp.	0-6°C
solubility	DMSO (Slightly), Methanol (Slightly, Heated)
form	Solid
pka	2.55±0.10(Predicted)
color	White to Off-White
Water Solubility	27mg/L(temperature not stated)
BRN	587472
LogP	2.200
CAS DataBase Reference	74223-64-6(CAS DataBase Reference)
EWG's Food Scores	2
FDA UNII	2589ET7417
Pesticides Freedom of Information Act (FOIA)	Metsulfuron-methyl
EPA Substance Registry System	Metsulfuron-methyl (74223-64-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS09
Signal word	Warning
Hazard statements	H410
Precautionary statements	P273-P391-P501
Hazard Codes	N
Risk Statements	50/53
Safety Statements	60-61
RIDADR	UN3077 9/PG 3
WGK Germany	2
RTECS	DH3563000
HS Code	29339900
Toxicity	LD50 in male and female rats, in male and female rabbits (mg/kg): >5000, >2000 orally; LC50 (96 hour) in American perch, rainbow trout: 150 ppm; LD50 in wild ducks: 2510 mg/kg (Lefebvre)

METSULFURON METHYL price More Price(9)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	46432	Metsulfuron-methyl PESTANAL	74223-64-6	100mg	$110	2024-03-01	Buy
Sigma-Aldrich	N12482	Metsulfuron-methyl analytical standard	74223-64-6	100mg	$99.3	2022-05-15	Buy
TRC	M227748	Metsulfuron-methyl	74223-64-6	1g	$330	2021-12-16	Buy
Usbiological	283408	Metsulfuron methyl	74223-64-6	50mg	$360	2021-12-16	Buy
AK Scientific	G186	Metsulfuronmethyl	74223-64-6	1g	$413	2021-12-16	Buy

Product number	Packaging	Price	Buy
46432	100mg	$110	Buy
N12482	100mg	$99.3	Buy
M227748	1g	$330	Buy
283408	50mg	$360	Buy
G186	1g	$413	Buy

METSULFURON METHYL Chemical Properties,Uses,Production

Chemical Properties

White, off-white or pale yellow crystalline solid. Slight, sweet odor; ester-like.

Chemical Properties

Light yellow solid

Uses

Herbicide.

Uses

Metsulfuron-methyl is an organic micro-pollutant.

Uses

Metsulfuron-methyl is a triazine urea herbicide used to control broad-leaved weeds in barley and wheat.

Definition

ChEBI: A N-sulfonylurea in which the sulfonyl group is attached to a 2-(methoxycarbonyl)phenyl group while a (4-methoxy-6-methyl-1,3,5-triazin-2-yl group replaces one of the amino hydrogens of the remaining urea group.

Agricultural Uses

Herbicide: Metsulfuron-methyl is a pre-emergence and post-emergence herbicide used to control annual grasses, brush, woody plants and broadleaf weeds. It can be applied to cereals including barley, rye and wheat and to pastures. It is primarily used to control brush, woody plants and broadleaf weeds on rights-of-way, fence rows, storage areas, highways and other non-crop areas.

Trade name

ALLIE®; ALLY®; ALLY-20DF®; ANSWER®; BRUSH-OFF®; CANVAS®; CIMARRON®; DMC® WEED CONTROL; DPD 63760H®; DPX 6376®; DPX-T 6376®; ESCORT®; FINESSE®; GROPPER®; NUP®; PARTISAN ®; PASTURE® MD; RIVERDALE®; ROSULFURON®

Potential Exposure

Metsulfuron-methyl is a preemergence and postemergence sulfonylurea herbicide used to control annual grasses, brush, woody plants and broadleaf weeds. It can be applied to cereals including barley, rye and wheat and to pastures. It is primarily used to control brush, woody plants and broadleaf weeds on rights-of-way, fence rows, storage areas, highways and other noncrop areas.

Environmental Fate

Soil/Plant. Hydrolyzes in soil and plants to nontoxic products (Hartley and Kidd, 1987). The half-life in soil varies from 7 days to 1 month (Hartley and Kidd, 1987).
Ismail and Lee (1995) studied the persistence of metsulfuron-methyl in a sandy loam (pH 5.1) and clay soil (3.1) under laboratory conditions. Degradation was more rapid in non-sterilized than in sterilized soil. In non-sterilized soil, the rate of degradation increased with increasing soil moisture content. When the moisture level in the sandy loam and clay soil was increased from 20 to 80% of field capacity at 35°C, the half-lives were reduced from 9.0 to 5.7 and 11.2 to 4.6, days, respectively. The investigators concluded that the disappearance of metsulfuron-methyl in soil resulted from microbial degradation and chemical hydrolysis.

Metabolic pathway

In soils, under aerobic conditions, metsulfuron methyl is degraded by the cleavage of the sulfonylurea linkage, resulting in the formation of methyl 2- (aminosulfonyl)benzoate, 4-methoxy-6-methyl-2-amino- 1,3,5-triazine, and saccharin as major products. Under anaerobic conditons, free acid of metsulfuron methyl and the resulting O-demethylation product are identified. The formation of two ring-opening products at the triazine moiety is observed. Under acidic conditions, hydrolytic degradation products identified are involved in the soil degradation products. In plants, the specific metabolites are identified as the hydroxylation product of the phenyl ring of metsulfuron methyl and 4-methoxy-6-hydroxymethyl-2-amino-1,3,5- triazine. Mammalian metabolites are also included in the soil metabolites.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Strong oxidizers. Stable in air to about 140 C. It is hydrolyzed in acid solutions.

Waste Disposal

It is the responsibility of chemical waste generators to determine the toxicity and physical properties and of a discarded chemical and to properly identify its classification and certification as a hazardous waste and to determine the disposal method. United States Environmental Protection Agency guidelines for the classification determination are listed in 40 CFR Parts 261.3. In addition, waste generators must consult and follow all regional, national, state and local hazardous waste laws to ensure complete and accurate classification and disposal methods. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Offer surplus and nonrecyclable solutions to a licensed disposal company. Dissolve or mix the pesticide with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

METSULFURON METHYL Preparation Products And Raw materials

Raw materials

Triazine B orthoacetic acid O-Methylisourea hydrochloride Saccharin Dicyandiamide

N-OCTANE Ethylenediamine Sodium sulfide Acetyl chloride Sodium

Methyl 2-sulfonamidobenzoate 1-Chlorobutane 2-Amino-4-methoxy-6-methyl-1,3,5-triazine o-Toluic acid CREAM

1-Methylpyrazole-4-ethoxycarbonyl-5-ethoxycarbonylsulfonamide DBU N-2,4-DIMETHYLPHENYL-N'-METHYLFORMAMIDINE PHOSGENE Hydrochloric acid

Chlorsulfuron Methanol Sodium hydroxide Butyl isocyanate Methyl formate

1,3,5-Triazine Sulfuric acid

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Preparation Products

Ethametsulfuron-methyl Acetochlor+Bensulfuron-methyl+Methsulfuron-methyl,W.P. Sulfometuron-methyl Tribenuron methyl Chlorsulfuron

4-Methoxy-N,6-dimethyl-1,3,5-triazin-2-amine

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METSULFURON METHYL Suppliers

Global( 250)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Qingdao Trust Agri Chemical Co.,Ltd	+8613573296305	aroma@qdtrustagri.com	China	301	58
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18779	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29884	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
TargetMol Chemicals Inc.	+1-781-999-5354 +1-00000000000	marketing@targetmol.com	United States	32165	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30240	58
Weifang Yuanye Biotechnology Co., Ltd	15053681231 13354462013 15053681231	tina@yuanyechemical.com	CHINA	67	58

Supplier	Advantage
Qingdao Trust Agri Chemical Co.,Ltd	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
TargetMol Chemicals Inc.	58
Career Henan Chemica Co	58
Weifang Yuanye Biotechnology Co., Ltd	58

View Lastest Price from METSULFURON METHYL manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-19	Metsulfuron-methyl 74223-64-6	US $62.00-39.00 / mg		98.60%	10g	TargetMol Chemicals Inc.
2024-08-27	METSULFURON METHYL 74223-64-6	US $0.00 / kg	100kg	20%	20tons	qingdao trust agri chemical co.,ltd
2024-04-24	Metsulfuron methyl 74223-64-6	US $850.00 / g	1g	98	500 Kg	R&D Scientific Inc.

Metsulfuron-methyl
74223-64-6
US $62.00-39.00 / mg
98.60%
TargetMol Chemicals Inc.

METSULFURON METHYL
74223-64-6
US $0.00 / kg
20%
qingdao trust agri chemical co.,ltd

Metsulfuron methyl
74223-64-6
US $850.00 / g
98
R&D Scientific Inc.

METSULFURON METHYL Spectrum

METSULFURON METHYL(74223-64-6)¹HNMR

74223-64-6(METSULFURON METHYL)Related Search:

Methyl formate DPX Metsulfuron Tribenuron methyl Iodosulfuron methyl sodium

METSULFURON METHYL Tritosulfuron Iodosulfuron-methyl METSULFURON-METHYL D3 Metsulfuron methyl 20 WP

Methsulfuron-methyl+Acetochlor,W.P. Methsulfuron-methyl W.P. Acetochlor+Bensulfuron-methyl+Methsulfuron-methyl,W.P. Bensulfuron-methyl+Methsulfuron-methyl,W.P. Methsulfuron-methyl+Isoproturon,W.P.

Methsulfuron-methyl water-dispersion granule

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QUIT allie ally20df benzoicacid,2-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino Benzoicacid,2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]-,methylester brush-off dpd63760h dpx6376 methyl2-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfo methyl2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2yl)ureidosulfonyl)benzoate methyl2-(3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulphonyl)benzoate Methyl2-[3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulphonyl]benzoate n-((4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl)-2-methoxycarbonylbenz nyl)benzoate oicacidmethylester 2-(((((4-methoxy-6-methyl-1,3,5-triazin-2yl)amino)carbonyl)amino)sulfonyl)benz ALLY ALLY 60 DF WEED KILLER(R) DPX-T6376 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester Methyl 2-(N-((4-Methoxy-6-Methyl-1,3,5-triazin-2-yl)carbaMoyl)sulfaMoyl)benzoate escort Gropper METHYL 2[[[[(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL)AMINO]CARBONYL]AMINO]-SULFONYL]BENZOATE MALBAN Metsulfuron Me METSULFURON-METHYL metsulfuron-methyl DPX-6376 Messulfuron-methyl METSULFURON METHYL, 100MG,NEAT Ally[R] Escort[R] Gropper[R] Methsulfuron Methyl Sodium METASULFURONMETHYL METSULPHURON-METHYL METSULFRON-METHYL metsulfuron-methyl 2-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl) benzoic acid Methsulfuron-methyl methyl-2-[3-(4-methoxyl-6-methyl-1,3,5-triazin-2-yl) ureidosulphonyl] benzoate Metsulfuron-methyl ,95% 2-[[[[(4-METHOXY-6-METHYL-1,3,5-TRIAZIN-2-YL)AMINO]CARBONYL]AMINO]SULFONYL]BENZOIC ACIDETHYL ESTER 1-(4-(methylsulfonyl)phenoxy)-4-(trifluoromethoxy)benzene Metsulfuron methyl 100mg [74223-64-6] methyl 2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate Metsulfuron-methyl @100 μg/mL in MeOH Metsulfuron-methylSolution,1000mg/L,1ml Metsulfuron-methyl Standard 74223-64-6 Metsulfuron Methyl herbicide for broadleaf weeds , annual grasses TIANFU-CHEM CAS:74223-64-6 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester C15210000 Metsulfuron-methyl Metsulfuron-methyl 10.0 μg/ml Acetonitrile 74223-64-6 76223-64-6 C14H15N5O6S Pesticides intermediate Others chemical reagents Herbicide