3-Chloro-2-methylpropene
- CAS No.
- 563-47-3
- Chemical Name:
- 3-Chloro-2-methylpropene
- Synonyms
- METHALLYL CHLORIDE;Mac;3-chloro-2-methylprop-1-ene;3-CHLORO-2-METHYL-1-PROPENE;Isobutenyl chloride;beta-methylallylchloride;Methylallyl chloride;BETA-METHALLYL CHLORIDE;1-CHLORO-2-METHYL-2-PROPENE;NCI-C54820
- CBNumber:
- CB9402043
- Molecular Formula:
- C4H7Cl
- Molecular Weight:
- 90.55
- MDL Number:
- MFCD00000953
- MOL File:
- 563-47-3.mol
- MSDS File:
- SDS
Melting point | -80 °C (lit.) |
---|---|
Boiling point | 71-72 °C (lit.) |
Density | 0.925 g/mL at 20 °C (lit.) |
vapor density | 3.12 (vs air) |
vapor pressure | 102 mm Hg ( 20 °C) |
refractive index |
n |
Flash point | 9 °F |
storage temp. | 2-8°C |
solubility | H2O: insoluble |
form | Liquid |
color | Clear |
explosive limit | 2.2-10.4%(V) |
Water Solubility | 0.5 g/L (20 ºC) |
Merck | 14,2148 |
BRN | 878160 |
CAS DataBase Reference | 563-47-3(CAS DataBase Reference) |
EWG's Food Scores | 3-4 |
FDA UNII | 7A9X1C3I3O |
Proposition 65 List | 3-Chloro-2-methylpropene |
NIST Chemistry Reference | 1-Propene, 3-chloro-2-methyl-(563-47-3) |
IARC | 2B (Vol. 63, 115) 2018 |
EPA Substance Registry System | 3-Chloro-2-methyl-1-propene (563-47-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05,GHS07,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H302+H332-H314-H317-H411 | |||||||||
Precautionary statements | P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | F,C,N | |||||||||
Risk Statements | 11-20/22-34-43-51/53 | |||||||||
Safety Statements | 9-16-29-36/37/39-45-61-26 | |||||||||
RIDADR | UN 2554 3/PG 2 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | UC8050000 | |||||||||
Autoignition Temperature | 899 °F | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29032900 | |||||||||
NFPA 704 |
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3-Chloro-2-methylpropene price More Price(32)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 8.05905 | 3-Chloro-2-methyl-1-propene for synthesis | 563-47-3 | 100mL | $45.7 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.05905 | 3-Chloro-2-methyl-1-propene for synthesis | 563-47-3 | 500mL | $77.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 108030 | 3-Chloro-2-methyl-1-propene technical grade, 90% | 563-47-3 | 100ml | $47 | 2024-03-01 | Buy |
Sigma-Aldrich | 108030 | 3-Chloro-2-methyl-1-propene technical grade, 90% | 563-47-3 | 1l | $72 | 2024-03-01 | Buy |
TCI Chemical | C0209 | 3-Chloro-2-methyl-1-propene >98.0%(GC) | 563-47-3 | 25mL | $21 | 2024-03-01 | Buy |
3-Chloro-2-methylpropene Chemical Properties,Uses,Production
Description
3-Chloro-2-methylpropene is used as an intermediate to produce carbofuran, herbicides, plastics, pharmaceuticals and other organics. It is also used as an additive in textile and perfumes. It was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate and cationic polymerization of 3-Chloro-2-methylpropene with AICI3 and AIBr3 as initiators. It is also the reactant for the synthesis of cyclobutanone.
Chemical Properties
clear liquid
Uses
3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.
Uses
In organic synthesis.
Uses
3-Chloro-2-methylpropene has been used as reactant in the synthesis of cyclobutanone. It is used as an intermediate in the production of plastics, pharmaceuticals and other organic chemicals.
Definition
ChEBI: 3-Chloro-2-methylpropene is an organochlorine compound.
Biological Functions
MAC is a valuable index for clinical anesthesia, but it is seldom employed without taking other factors into consideration. For example, inhibiting movement in only 50% of patients is not acceptable. Consequently, if an inhalational agent were being used alone—that is, without the administration of other anesthetics or analgesic drugs—the anesthesiologist would employ a multiple of its MAC value to ensure immobility.MAC is frequently multiplied by a factor of 1.3 to achieve nearly 100% clinical efficacy. On the other hand, useful clinical results may be achieved with doses of anesthetics below MAC levels. For example, mild analgesia and amnesia often occur with doses of inhalational agents that are near 0.5 MAC. In this state, it may even be possible to communicate with patients intraoperatively, while their recall is limited.
Synthesis Reference(s)
The Journal of Organic Chemistry, 46, p. 824, 1981 DOI: 10.1021/jo00317a041
General Description
A colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0°F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.
Air & Water Reactions
Highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. . Insoluble in water.
Reactivity Profile
3-Chloro-2-methylpropene is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. 3-Chloro-2-methylpropene is incompatible with strong bases. 3-Chloro-2-methylpropene may react with water at elevated temperatures. .
Hazard
Irritant; poison; anesthetic; questionable carcinogen; toxic.
Health Hazard
Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.
Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.
Carcinogenicity
3-Chloro-2-methylpropene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
3-Chloro-2-methylpropene Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12839 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5892 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20286 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1803 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29881 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8618959220845 | sales@amoychem.com | China | 6383 | 58 |
View Lastest Price from 3-Chloro-2-methylpropene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-13 | 3-Chloro-2-methylpropene
563-47-3
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | ||
2024-10-11 | 3-Chloro-2-methylpropene
563-47-3
|
US $50.00-20.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | ||
2023-12-26 | 3-Chloro-2-methylpropene
563-47-3
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
- 3-Chloro-2-methylpropene
563-47-3
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- 3-Chloro-2-methylpropene
563-47-3
- US $50.00-20.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
- 3-Chloro-2-methylpropene
563-47-3
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd