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[Bis(trifluoroacetoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene structure

CAS No.: 2712-78-9

Chemical Name:: [Bis(trifluoroacetoxy)iodo]benzene

Synonyms: PIFA;BTI;DFAIB;Bacillus thuringiensis israelensis;[Bis(trifluoroacetox;LABOTEST-BB LT00454809;uoroacetoxy)iodo]benzene;[Bis(trifluoroacetoxy)iodo]ben;1Bis-trifluoroacetoxyiodobenzene;BIS(TRIFLUORACETOXY)- IODOBENZENE

CBNumber:: CB9419191

Molecular Formula:: C10H5F6IO4

Molecular Weight:: 430.04

MDL Number:: MFCD00009672

MOL File:: 2712-78-9.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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[Bis(trifluoroacetoxy)iodo]benzene Properties

Melting point	121-125 °C(lit.)
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
solubility	Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form	Crystalline Powder
color	White to pale yellow
Water Solubility	insoluble
Sensitive	Moisture & Light Sensitive
BRN	764767
Stability	Air and Moisture Sensitive
CAS DataBase Reference	2712-78-9(CAS DataBase Reference)
FDA UNII	659SFV27XS
UNSPSC Code	12352002
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-37/39

WGK Germany

4.10-8-9-21

Hazard Note

Irritant/Keep Cold

HazardClass

IRRITANT, KEEP COLD, LIGHT SENSITIVE

HS Code

29036990

NFPA 704

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[Bis(trifluoroacetoxy)iodo]benzene price More Price(39)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	15230	[Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT)	2712-78-9	10g	$91.2	2024-03-01	Buy
Sigma-Aldrich	15230	[Bis(trifluoroacetoxy)iodo]benzene purum, ≥95.0% (AT)	2712-78-9	50g	$200	2024-03-01	Buy
Alfa Aesar	L15141	[Bis(trifluoroacetoxy)iodo]benzene, 97%	2712-78-9	5g	$45.8	2024-03-01	Buy
Alfa Aesar	L15141	[Bis(trifluoroacetoxy)iodo]benzene, 97%	2712-78-9	25g	$118	2024-03-01	Buy
Sigma-Aldrich	232130	[Bis(trifluoroacetoxy)iodo]benzene 97%	2712-78-9	10g	$91.9	2024-03-01	Buy

Product number	Packaging	Price	Buy
15230	10g	$91.2	Buy
15230	50g	$200	Buy
L15141	5g	$45.8	Buy
L15141	25g	$118	Buy
232130	10g	$91.9	Buy

[Bis(trifluoroacetoxy)iodo]benzene Chemical Properties,Uses,Production

Chemical Properties

White to pale yellow crystalline powder

Uses

In oxidation, cyclization, dehydrogenation, and dearomatization reactions.

Uses

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

reaction suitability

reagent type: oxidant

Purification Methods

Crystallise the iodo compound from warm trifluoroacetic acid and dry it over NaOH pellets. Recrystallise it also from Me2CO/pet ether. Its melting point depends on the heating rate. [Spyroudis & Varvoglis Synthesis 445 1975, application: Almond et al. Org Synth 66 132 1988.]

[Bis(trifluoroacetoxy)iodo]benzene Preparation Products And Raw materials

Raw materials

Iodobenzene Hexane Hydrogen peroxide Sodium percarbonate Trifluoroacetic anhydride

Dichloromethane

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Preparation Products

T-BUTYL TRIFLUOROACETATE

[Bis(trifluoroacetoxy)iodo]benzene Suppliers

Global( 336)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-29-81148696 +86-15536356810	1022@dideu.com	China	3883	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7906	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20233	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29730	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-+86-371-66670886	info@dakenam.com	China	19805	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21628	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3009	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29858	58
NINGBO INNO PHARMCHEM CO., LTD.	13867897135	sales@nbinno.com	CHINA	923	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2930	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Shanghai UCHEM Inc.	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
career henan chemical co	58
NINGBO INNO PHARMCHEM CO., LTD.	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58

View Lastest Price from [Bis(trifluoroacetoxy)iodo]benzene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-04-28	[Bis(trifluoroacetoxy)iodo]benzene 2712-78-9	US $0.00 / kg	1kg	99%	100mt	Jinan Finer Chemical Co., Ltd
2025-04-28	[Bis(trifluoroacetoxy)iodo]benzene 2712-78-9	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2025-04-04	[Bis(trifluoroacetoxy)iodo]benzene 2712-78-9	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.

[Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $0.00 / kg
99%
Jinan Finer Chemical Co., Ltd

[Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

[Bis(trifluoroacetoxy)iodo]benzene
2712-78-9
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

[Bis(trifluoroacetoxy)iodo]benzene Spectrum

[Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)¹HNMR [Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)IR1 [Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)IR2 [Bis(trifluoroacetoxy)iodo]benzene(2712-78-9)Raman

2712-78-9([Bis(trifluoroacetoxy)iodo]benzene)Related Search:

(Trifluoromethoxy)benzene Iodine Ethylbenzene Anisole Allylbenzene

Sodium triacetoxyborohydride (Diacetoxyiodo)benzene Acetoxyacetic acid Benzene Acetoxyacetyl chloride

Povidone iodine 2-Phenoxyethanol Sliver bis(trifluoromethane sulfonimide) Cobalt bis(trifluoroMethylsulfonyl)iMide Silicon tetraacetate

BIS(DICYCLOHEXYLPHOSPHINO)METHANE Bis(dibenzylideneacetone)palladium Bis(2-dicyclohexylphosphinophenyl)ether, 98%

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IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE) IODINE, PHENYLBIS(TRIFLUOROACETATO)- IODOBENZENE BIS(TRIFLUOROACETATE) IODOBENZENE I,I-BIS(TRIFLUOROACETATE) BIS(TRIFLUORACETOXY)- IODOBENZENE [BIS(TRIFLUOROACETOXY)IODO]BENZENE [Bis(trifluoroacetoxy)](phenyl)iodane Iodobenzene 1,1-bis(trifluoroacetate) [Bis(trifluoroacetoxy)iodo]benzene purum, >=95.0% (AT) [Bis(trifluoroacetoxy)iodo]benzene SynonyMs Phenylbis(trifluoroacetato-O)iodine [phenyl-(2,2,2-trifluoroacetyl)oxy-3-iodanyl] 2,2,2-trifluoroacetate BTI~Iodosobenzene bis(trifluoroacetate)~Phenyliodine(III) bis(trifluoroacetate)~PIFA phenylbis(trifluoroacetato-O)iodine Bis-Trifluoroacetoxyiodobenzene99% Bis-Trifluoroacetoxyiodobenzene 99% Iodosobenzene-bis(trifluoroacetate) Phenyliodine(III)bis(trifluoroacetate) Bis(trifluoroacetoxy)iodoübenzene, 97% BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetoxy)iodo(III)]benzene [Di(trifluoroacetoxy)iodo(III)]benzene Bis(trifluoroacetic acid)phenyliodine(III) salt Phenylbis(trifluoroacetyloxy) iodine(III) Iodine, phenylbis(trifluoroacetato-.kappa.O)- bis(I,I-trifluoroacetoxy)iodobenzene [Bis(trifluoroacetoxy)iodo]benzene,98% 1Bis-trifluoroacetoxyiodobenzene [Bis(trifluoroethoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene,BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA [Bis(trifluoroacetox [Bis(trifluoroacetoxy)iodo]benzene, 98% 10GR [Bis(trifluoroacetoxy)iodo]benzene, 98% 50GR LABOTEST-BB LT00454809 BIS(TRIFLUOROACETOXY)IODOBENZENE FOR SYN [Bis(trifluoroacetoxy)iodo]ben [phenyl-(2,2,2-trifluoroacetyl)oxy-λ³-iodanyl] 2,2,2-trifluoroacetate uoroacetoxy)iodo]benzene [Bis(trifluoroacetoxy)iodo]benzene, 98%, for synthesis [Bis(trifluoroacetoxy)iodo]benzene > Iodine, phenylbis(2,2,2-trifluoroacetato-κO)- [Bis(trifluoroacetoxy)iodo]benzene ISO 9001：2015 REACH [phenyl-(2,2,2-trifluoroacetyl)oxy- BTI DFAIB Bacillus thuringiensis israelensis PIFA [Bis(trifluoroacetoxy)iodo]benzene, 97% 2712-78-9 C10H5F6IO4 C10H5O4F6I CF3CO22IC6H5 C10F6H5I1O4 C10H9F6IO2 C10H3F6IO4 Oxidation Synthetic Reagents Hypervalent Iodine Carbazoles