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2-Bromophenylboronic acid

2-Bromophenylboronic acid structure

CAS No.: 244205-40-1

Chemical Name:: 2-Bromophenylboronic acid

Synonyms: o-BBBA;2-broMoborate;AKOS BRN-0929;RARECHEM AH PB 0074;2-Bromophenylboronic;2-BROMOPHENYLBORONIC ACID;O-BROMOPHENYLBORONIC ACID;(2-bromophenyl)boronicaci;2-BROMOBENZENEBORONIC ACID;2-Bromobenzeneboronicacid,98%

CBNumber:: CB9421532

Molecular Formula:: C6H6BBrO2

Molecular Weight:: 200.83

MDL Number:: MFCD01114672

MOL File:: 244205-40-1.mol

MSDS File:: SDS

Last updated:2024-04-08 13:48:25

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2-Bromophenylboronic acid Properties

Melting point	113 °C(lit.)
Boiling point	329.2±44.0 °C(Predicted)
Density	1.67±0.1 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly)
form	Powder
pka	8.25±0.58(Predicted)
color	White to off-white
Water Solubility	Soluble in methanol. Slightly soluble in water.
BRN	8542615
CAS DataBase Reference	244205-40-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Xn,Xi

Risk Statements

36/37/38-22

Safety Statements

37/39-26

WGK Germany

HazardClass

IRRITANT

HS Code

29319090

NFPA 704

	1
2		0

2-Bromophenylboronic acid price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	473804	2-Bromophenylboronic acid ≥95.0%	244205-40-1	5g	$31.6	2024-03-01	Buy
Sigma-Aldrich	473804	2-Bromophenylboronic acid ≥95.0%	244205-40-1	25g	$150	2024-03-01	Buy
TCI Chemical	B2889	2-Bromophenylboronic Acid (contains varying amounts of Anhydride)	244205-40-1	5g	$64	2024-03-01	Buy
Alfa Aesar	L18581	2-Bromobenzeneboronic acid, 98%	244205-40-1	1g	$30.65	2024-03-01	Buy
Alfa Aesar	L18581	2-Bromobenzeneboronic acid, 98%	244205-40-1	5g	$78.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
473804	5g	$31.6	Buy
473804	25g	$150	Buy
B2889	5g	$64	Buy
L18581	1g	$30.65	Buy
L18581	5g	$78.65	Buy

2-Bromophenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

White to off-white powder

Uses

2-Bromobenzeneboronic acid is a boronic acid derivative that is widely used in organic synthesis for carbon-carbon bond formation. In Suzuki coupling, aryl halides and boronic acid aryl or vinyl esters or boronic acids are coupled using Pd(PPh3)4.

Application

2-Bromophenylboronic Acid is used as an inhibitor of the hormone sensitive lipase.
Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
It is also an important intermediate for Organic Light-Emitting Diod ( OLED) .

Preparation

2-Bromophenylboronic acid synthesis: take 2-bromoaniline as raw material, synthesize the intermediate 1-Bromo-2-iodobenzene through diazotization and iodination, and then carry out magnesium iodide exchange with isopropylmagnesium bromide to synthesize o-bromophenylmagnesium bromide, It is then subjected to substitution reaction with trimethyl borate to synthesize methyl o-bromophenylboronic acid, and then hydrolyzed to synthesize 2-bromophenylboronic acid.

2-Bromophenylboronic acid synthesis

Synthesis of 2-Bromophenylboronic acid from Trimethyl borate and 1-Bromo-2-iodobenzene

2-Bromophenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate

Preparation Products

4-fluoro-N-(1-hydroxy-3,3-dimethyl-1,3-dihydrobenzo[c][1,2]oxaborol-6-yl)-2-(trifluoromethyl)benzamide(WXG02326) 4-BROMOPHENYL TRIFLUOROMETHANESULFONATE 5,11-dihydro-5-phenylindolo[3,2-b]carbazole 3,3-diMethylbenzo[c][1,2]oxaborol-1(3H)-ol 2'-BROMOBIPHENYL-2-YLCARBOXALDEHYDE

2-BROMO-3'-METHYLBENZOPHENONE

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2-Bromophenylboronic acid Suppliers

Global( 384)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Tianjin Xinshengjiahe Science & Technology Development Co,.Ltd	+86-86-22-87899925 +86-8618522618860	18522618860@163.com	China	694	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20286	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18775	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
Beijing Green Guardee Technology Co., Ltd	86-010-69706062	sales2@greenguardee.com	CHINA	650	58
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29881	58
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	904	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2963	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	17453	58

Supplier	Advantage
Tianjin Xinshengjiahe Science & Technology Development Co,.Ltd	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
Beijing Green Guardee Technology Co., Ltd	58
career henan chemical co	58
Shanghai Arbor Chemical Co., Ltd.	58
Jinan Finer Chemical Co., Ltd	58
Accela ChemBio Inc.	58

View Lastest Price from 2-Bromophenylboronic acid manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-08	2-Bromophenylboronic acid 244205-40-1	US $34.00-1.20 / kg	1kg	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-05-04	2-Bromophenylboronic acid 244205-40-1	US $48.00-40.00 / KG	1KG	99%	200tons	Guangzhou Sunton Biotechnology Co., Ltd.
2023-03-13	2-Bromophenylboronic acid 244205-40-1	US $0.00-0.00 / kg	1kg	98%Min	1000kg	LY Global chemicals co.,ltd .

2-Bromophenylboronic acid
244205-40-1
US $34.00-1.20 / kg
99%
Henan Fengda Chemical Co., Ltd

2-Bromophenylboronic acid
244205-40-1
US $48.00-40.00 / KG
99%
Guangzhou Sunton Biotechnology Co., Ltd.

2-Bromophenylboronic acid
244205-40-1
US $0.00-0.00 / kg
98%Min
LY Global chemicals co.,ltd .

2-Bromophenylboronic acid Spectrum

2-Bromophenylboronic acid(244205-40-1)IR

244205-40-1(2-Bromophenylboronic acid)Related Search:

1,3-Dibromobenzene Phenylboronic acid 2-Bromobenzonitrile Citric acid 2-Bromophenylacetic acid

3-Bromoanisole Zinc borate Triphenylphosphine 1,2-Dibromobenzene 2-Phenylphenol

2-Bromofluorobenzene Ascoric Acid Phenylacetone 2-BROMO-3-ETHOXY-6-FLUOROPHENYLBORONIC& 2-Bromo-6-fluoro-3-methoxyphenylboronic acid

(2,6-DIBROMO-5-METHOXY)BENZENEBORONIC ACID 2-BROMO-5-METHOXYPHENYLBORONIC ACID 3-BROMO-6-FLUORO-3-PROPOXYPHENYLBORONIC&

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2-broMoborate o-BBBA 2-Bromophenylboronic acid >=95.0% Boronic acid,B-(2-bromophenyl)- AKOS BRN-0929 RARECHEM AH PB 0074 O-BROMOPHENYLBORONIC ACID 2-BROMOPHENYLBORONIC ACID 2-BROMOBENZENEBORONIC ACID 2-Bromophenylboronic 2-Bromophenylboronic Acid (contains varying amounts of Anhydride) 2-Bromobenzeneboronicacid,98% 2-Bromophenylboronic acid,97% 2-BroMophenylboronic Acid 2-BroMophenylboronic acid, 97% 5GR 2-Bromophenylboronic acid ,98% VLOOKUP(C12,[1]Export!$D:$H,5,0) 2-Bromobenzeneboronic acid 98% (2-bromophenyl)boronicaci Boronic acid, B-(2-bromopheny!)- 244205-40-1 C6H6BBrO2 Organometallic Reagents Aryl Boronic Acids Boronic Acids and Derivatives Boronic Acids and Derivatives Boronate Ester Boronic Acid Potassium Trifluoroborate Pyridines blocks BoronicAcids Bromides B (Classes of Boron Compounds) Boronic Acids Aryl Boronic Acids