ChemicalBook >> CAS DataBase List >>(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) structure

CAS No.: 490023-37-5

Chemical Name:: (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

Synonyms: Reaxys ID: 23113812;3,4-a′]dinaphthalen-4-yl)MethylaMine;3,4-a']dinaphthalen-4-yl)methylamine;(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D;1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS);3,4-a']dinaphthalen-4-yl)methylamine 97%;(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%;3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98%

CBNumber:: CB9465976

Molecular Formula:: C28H22NO2P

Molecular Weight:: 435.45

MDL Number:: MFCD04117686

MOL File:: 490023-37-5.mol

MSDS File:: SDS

Last updated:2023-05-04 15:16:07

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Properties

Melting point	155-159 °C
Boiling point	635.4±48.0 °C(Predicted)
alpha	+356° (c 0.32, CHCl3)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	0.08±0.20(Predicted)
form	Powder
color	white
Sensitive	moisture sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H335-H319-H315
Precautionary statements	P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) price More Price(16)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	665355	(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine 97%	490023-37-5	100mg	$26.24	2024-03-01	Buy
Strem Chemicals	15-1510	(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%	490023-37-5	100mg	$68	2024-03-01	Buy
Strem Chemicals	15-1510	(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%	490023-37-5	500mg	$267	2024-03-01	Buy
Sigma-Aldrich	665355	(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)methylamine 97%	490023-37-5	500mg	$258	2023-01-07	Buy
Matrix Scientific	090135	N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%	490023-37-5	250mg	$492	2021-12-16	Buy

Product number	Packaging	Price	Buy
665355	100mg	$26.24	Buy
15-1510	100mg	$68	Buy
15-1510	500mg	$267	Buy
665355	500mg	$258	Buy
090135	250mg	$492	Buy

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties,Uses,Production

Reaction

The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.

Uses

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Suppliers

Global( 40)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18775	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6114	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131957	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40228	62
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44688	61
Tianjin Derchemist Science & Technology Co., Ltd.	22-58627059 13920586291	zdcomcon@126.com	China	3461	50
Shanghai Incat Chemtech Co.,Ltd.	021-57603038 13601791340	307593986@qq.com	China	475	58
Bide Pharmatech Ltd.	400-164-7117 13681763483	product02@bidepharm.com	China	41462	60

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Shaoxin Catsyn Co., Ltd.	58
Aladdin Scientific	58
Amadis Chemical Company Limited	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Energy Chemical	61
Tianjin Derchemist Science & Technology Co., Ltd.	50
Shanghai Incat Chemtech Co.,Ltd.	58
Bide Pharmatech Ltd.	60

490023-37-5((+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS))Related Search:

Benzophenone (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (R)-MONOPHOS (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

1of2

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99% (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL& 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99% 3,4-a′]dinaphthalen-4-yl)MethylaMine N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 3,4-a']dinaphthalen-4-yl)methylamine 97% (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE,99% Reaxys ID: 23113812 (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D 1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N-methyl-N-(phenylmethyl)-, (11bS)- (11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine (11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 3,4-a']dinaphthalen-4-yl)methylamine 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,98% 490023-37-5 Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents DSM MonoPhos Phosphoramidites Privileged Ligands Chiral Phosphine CPN