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Polycaprolactone

CAS No.
24980-41-4
Chemical Name:
Polycaprolactone
Synonyms
Ploycarprolactone;POLYCAPROLACTONE AVERAGE MN CA. 42 500;PCL20000;CURESORB-PCL;Lactel? BP-0800;POLYCAPROLACTONE;Caprolactone polymer;Caprolactone oligomer;Dyed Polycaprolactone;POLYCAPROLACTONE AVER
CBNumber:
CB9498981
Molecular Formula:
C6H10O2
Molecular Weight:
114.1424
MDL Number:
MFCD00084404
MOL File:
24980-41-4.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02

Polycaprolactone Properties

Melting point 60 °C(lit.)
Density 1.146 g/mL at 25 °C
Tg -60
storage temp. -20°C
form pellets
Odor odorless
Viscosity 400-1000mPa.s50wt. % in xylene
InChI InChI=1S/C6H10O2/c7-6-4-2-1-3-5-8-6/h1-5H2
InChIKey PAPBSGBWRJIAAV-UHFFFAOYSA-N
SMILES O1CCCCCC1=O
EPA Substance Registry System 2-Oxepanone, homopolymer (24980-41-4)
UNSPSC Code 41116100
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280-P261-P271
WGK Germany  3
RTECS  TR4708000
TSCA  TSCA listed
HS Code  3907998090

Polycaprolactone price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 769762 Resomer® C 209, Poly(caprolactone) ester terminated 24980-41-4 5G $171 2024-03-01 Buy
Sigma-Aldrich 900288 Polycaprolactone viscosity 0.40 dL/g 24980-41-4 5g $211 2024-03-01 Buy
Sigma-Aldrich 769762 Resomer® C 209, Poly(caprolactone) ester terminated 24980-41-4 25G $564 2024-03-01 Buy
Sigma-Aldrich 900824 Polycaprolactone viscosity0.20?dL/g 24980-41-4 5G $203 2023-06-20 Buy
Sigma-Aldrich 900296 Polycaprolactone viscosity 2.7dL/g 24980-41-4 5g $201 2023-06-20 Buy
Product number Packaging Price Buy
769762 5G $171 Buy
900288 5g $211 Buy
769762 25G $564 Buy
900824 5G $203 Buy
900296 5g $201 Buy

Polycaprolactone Chemical Properties,Uses,Production

Description

Polycaprolactone is a semi-crystalline polymer, a chemically synthesized biodegradable polymer material, its structural repeating unit has 5 non-polar methylene-CH2 starch, etc. Substance blending can make completely biodegradable materials.Poly(ε-caprolactone).png

Chemical Properties

intrinsic viscosity 1.00-1.30

Uses

Extrusion aid, die lubricant, mold release, pigment and filler dispersion aid and polyester segments in urethanes and block polyesters.

Uses

Research applications of this material include:

  • Tissue engineering scaffolds.
  • 3D Bioprinting.
  • Drug delivery applications such as sustained release.

Uses

Biodegradable, biocompatible, and bioresorbable polymer composed of ε-caprolactone. This semi-crystalline material has been used in the fabrication of research medical devices and research tissue engineering solutions, such as orthopedic or soft tissue fixation devices. Degradation of this material has been thoroughly studied and has been shown to be safely resorbed by the body after implantation. Modification of molecular weight and polymer composition allows for control of the degradation rate and mechanical stability of the polymer.

Definition

ChEBI: Hexano-6-lactone is a epsilon-lactone that is oxepane substituted by an oxo group at position 2.

Properties and Applications

Polycaprolactone (PCL) is a biodegradable, semicrystalline polyester for use in tissue engineering and drug delivery research applications. Due to the increased length of the aliphatic chain, polycaprolactone degrades significantly slower than other common biodegradable polymers, such as polylactide. PCL features a low melting point (55-60 °C), making it ideal for thermal processing and increasing its use in novel applications such as 3D bioprinting. In addition to its favorable thermal properties, PCL also features high solubility in organic solvent allowing for a multitude of other processing options. This product features low residual water, monomer, and catalyst (tin) making it an ideal choice for use in tissue engineering and 3D bioprinting research.

Reactivity Profile

Polycaprolactone (PCL) is biodegradable polyester with a low melting point of around 60 °C and a glass transition temperature of about 60 °C. PCL is prepared by ring-opening polymerization of ε-caprolactone using a catalyst such as stannous octanoate[1]. Polycaprolactone is a semicrystalline linear polyester produced by ring-opening polymerisation of epsilon-caprolactone, which is commonly derived from fossil carbon. It has a much lower glass-transition temperature (Tg = ? 60 °C) than other biodegradable polymers, which assists its biodegradability despite its high degree of crystallinity, typically 50%[2].

Solubility in organics

Chloroform, THF, toluene

References

[1] McKeen, L. “1 – Introduction to Use of Plastics in Food Packaging.” 2013. 1-15.
[2] Abdelhamid, Hani Nasser. “Biodegradable Polymer Nanocomposites.” 2023. 0.

Polycaprolactone Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 252)Suppliers
Supplier Tel Email Country ProdList Advantage
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58
Hebei Mujin Biotechnology Co.,Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12824 58
Hebei Yanxi Chemical Co., Ltd.
+8617531153977 allison@yan-xi.com China 5855 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325 sales1@chuanghaibio.com China 5878 58
Hebei Dangtong Import and export Co LTD
+86-86-4001020630 +8619831957301 admin@hbdangtong.com China 1000 58
Hebei Chuanghai Biotechnology Co., Ltd
+8615531151365 mina@chuanghaibio.com China 18141 58
Hebei Kingfiner Technology Development Co.Ltd
+86-15532196582 +86-15373005021 lisa@kingfinertech.com China 3007 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20255 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3692 58
Hebei Shengyang Water Conservancy Engineering Co., Ltd.
+8615373025980 clara@hbshengyang.com China 896 58

Related articles

View Lastest Price from Polycaprolactone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Poly(ε-caprolactone) pictures 2025-03-14 Poly(ε-caprolactone)
24980-41-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
Polycaprolactone pictures 2025-03-14 Polycaprolactone
24980-41-4
US $10.00 / kg 1kg 99% 5000 Hebei Zhuanglai Chemical Trading Co.,Ltd
2-Oxepanone pictures 2025-03-07 2-Oxepanone
24980-41-4
US $0.00 / kg 1kg 0.99 20tons Hebei Yanxi Chemical Co., Ltd.
  • Polycaprolactone pictures
  • Polycaprolactone
    24980-41-4
  • US $10.00 / kg
  • 99%
  • Hebei Zhuanglai Chemical Trading Co.,Ltd
  • 2-Oxepanone pictures
  • 2-Oxepanone
    24980-41-4
  • US $0.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
caprolactone homopolymer Polycaprolactone,2-Oxepanone homopolymer, 6-Caprolactone polymer 2-Oxepanone polyesters 6-Hexanolide homopolymer Caprolactone oligomer Polycaprolactone,viscosity >11.25 dL/g Polycaprolactone,viscosity 0.30~0.75 dL/g Polycaprolactone,viscosity 0.75~1.25 dL/g Polycaprolactone,viscosity 1.25~1.75 dL/g Polycaprolactone,viscosity 1.75~2.25 dL/g Polycaprolactone,viscosity 2.25~3.00 dL/g Polycaprolactone,viscosity 3.00~4.25 dL/g Poly(caprolactone), Av. Mn (by GPC) 80,000, Pellets Poly(caprolactone), Flakes Polycaprolactone average Mn 45,000 Polycaprolactone average Mn 80,000 Polycaprolactone average Mw ~14,000, average Mn ~10,000 by GPC, flakes Polycaprolactone - 81200 Lactel? BP-0800 Polycaprolactone,viscosity 4.25~6.00 dL/g Polycaprolactone,viscosity 6.00~8.25 dL/g polycaprolactone (average MW 1000-1000000) Polycaprolactone,viscosity 8.25~11.25 dL/g POLYCAPROLACTONE, AVERAGE MN CA. 80,000 POLY(EPSILON-CAPROLACTONE) (AVERAGE MW ABOUT 10,000) Polycaprolactone average Mw ~14,000, average Mn ~10,000 by GPC Polycaprolactone,ester terminated,viscosity ~01.5 dL/g Polycaprolactone,ester terminated,viscosity 3.00~4.25 dL/g Dyed Polycaprolactone .epsilon.-Caprolactone,homopolymer 2-Oxepanone,homopolymer POLYCAPROLACTONE, AVERAGE MN CA. 10,000 aquaplast,caprolactone Polycaprolactone Standard (Mw 2,000) Polycaprolactone Standard (Mw 4,000) Polycaprolactone Standard (Mw 13,000) Polycaprolactone Standard (Mw 20,000) Polycaprolactone Standard (Mw 40,000) Polycaprolactone Standard (Mw 60,000) Polycaprolactone Standard (Mw 100,000) Polycaprolactone Standard (Mw 120,000) Polycaprolactone Standard (Mw 200,000) CURESORB-PCL Poly(ε-caprolactone), medical grade, ester terminated, average M.W. 106,000 - 188,000 Poly(ε-caprolactone), medical grade, ester terminated, average M.W. 188,000 - 282,000 Poly(ε-caprolactone), medical grade, ester terminated, average M.W. 282,000 - 499,000 Poly(ε-caprolactone), medical grade, ester terminated, average M.W. 4,000 - 40,000 Poly(ε-caprolactone), medical grade, ester terminated, average M.W. 40,000 - 106,000 Poly(ε-caprolactone) ,PCL PolycaprolactoneMn 70,000-90,000 Resomer(R) C 209, Poly(caprolactone) Resomer(R) C 212, Poly(caprolactone) Resomer(R) C 212, Poly(caprolactone) ester terminated OLYCAPROLACTONE AVERAGE MN CA. 42 500 POLYCAPROLACTONE AVERAGE MN CA. 42 500 ISO 9001:2015 REACH Caprolactone polymer POLYCAPROLACTONE AVERAGE MN CA. 42 500 Ploycarprolactone