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2-(2-Bromoethyl)-1,3-dioxane

2-(2-Bromoethyl)-1,3-dioxane structure

CAS No.: 33884-43-4

Chemical Name:: 2-(2-Bromoethyl)-1,3-dioxane

Synonyms: )-1,3-dioxane;2-Bromopropionaldehy;LABOTEST-BB LT00233134;2-(2-bromoethyl)-3-dioxane;2-(2-Bromethyl)-1,3-dioxane;2-(2-BROMOETHYL)-1,3-DIOXANE;1,3-Dioxane, 2-(2-bromoethyl)-;2-(2-Bromoethyl)-1,3-dioxane>2-(2-Bromoethyl)-1,3-dioxane 98%;2-(2-BROMOETHYL)-1,3-DIOXANE, STAB.

CBNumber:: CB9715024

Molecular Formula:: C6H11BrO2

Molecular Weight:: 195.05

MDL Number:: MFCD00006567

MOL File:: 33884-43-4.mol

MSDS File:: SDS

Last updated:2024-09-04 16:41:36

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2-(2-Bromoethyl)-1,3-dioxane Properties

Melting point	157-161 °C
Boiling point	67-70 °C2.8 mm Hg(lit.)
Density	1.431 g/mL at 25 °C(lit.)
refractive index	n20/D 1.481(lit.)
Flash point	206 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
solubility	ethanol: soluble50 (μg/mL)
form	Liquid
color	Clear colorless
Water Solubility	It is not soluble in water but soluble in organic solvent such as ethanol.
BRN	1421628
InChI	InChI=1S/C6H11BrO2/c7-3-2-6-8-4-1-5-9-6/h6H,1-5H2
InChIKey	WMDHQEHPOVOEOG-UHFFFAOYSA-N
SMILES	O1CCCOC1CCBr
CAS DataBase Reference	33884-43-4(CAS DataBase Reference)
NIST Chemistry Reference	2(2-Bromoethyl)-1,3-dioxane(33884-43-4)
EPA Substance Registry System	1,3-Dioxane, 2-(2-bromoethyl)- (33884-43-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-24/25

WGK Germany

8-10

TSCA

Yes

HS Code

29349990

NFPA 704

	1
2		0

2-(2-Bromoethyl)-1,3-dioxane price More Price(36)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	269131	2-(2-Bromoethyl)-1,3-dioxane 98%	33884-43-4	10g	$79.7	2023-06-20	Buy
Sigma-Aldrich	269131	2-(2-Bromoethyl)-1,3-dioxane 98%	33884-43-4	50g	$300	2023-06-20	Buy
TCI Chemical	B1182	2-(2-Bromoethyl)-1,3-dioxane >97.0%(GC)	33884-43-4	5g	$39	2024-03-01	Buy
TCI Chemical	B1182	2-(2-Bromoethyl)-1,3-dioxane >97.0%(GC)	33884-43-4	25g	$154	2024-03-01	Buy
Alfa Aesar	L00958	2-(2-Bromoethyl)-1,3-dioxane, 98%	33884-43-4	10g	$34.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
269131	10g	$79.7	Buy
269131	50g	$300	Buy
B1182	5g	$39	Buy
B1182	25g	$154	Buy
L00958	10g	$34.65	Buy

2-(2-Bromoethyl)-1,3-dioxane Chemical Properties,Uses,Production

Uses

2-(2-Bromoethyl)-1,3-dioxane was used in the synthesis of ketone adducts 2-[3-oxo-4(S)-(triphenylmethyl) amino-6-methylheptyl]-1,3-dioxane and 2-[3-oxo-4(S)-(triphenylmethyl)amino-6-methylheptyl]-1,3-dioxolane.

General Description

The reaction of Grignard reagent prepared from 2-(2-bromoethyl)-1,3-dioxane and N-tert-butanesulfinyl aldimines was studied.

Synthesis

A 2-L, three-necked flask has a mechanical stirrer, thermometer, and gas inlet tube. In the flask, 750 mL of dichloromethane, 112 g (2.00 mol) of acrolein (Note 1), and 0.10 g of dicinnamalacetone indicator are placed under nitrogen. The yellow solution is cooled to 0–5°C with an ice bath. Gaseous hydrogen bromide is bubbled into the solution with stirring until the indicator becomes deep red. The ice bath is removed, and 1.0 g of p-toluenesulfonic acid monohydrate and 152.2 g (2.00 mol, 144 mL) of 1,3-propanediol are added. The yellow solution is stirred at room temperature for 8 hr and then concentrated with a rotary evaporator. The residual oil is washed with two 250-mL portions of saturated aqueous sodium bicarbonate and dried over anhydrous potassium carbonate. Vacuum distillation through a 30-cm Vigreux column yields 252 g (65%) of 2-(2-Bromoethyl)-1,3-dioxane as a colourless liquid.

storage

This bromide is recognized to possess irritant properties and should therefore invariably be handled with gloved hands inside an efficient hood. It is also advisable that these reagents be refrigerated for long-term storage in order to minimize the potential for acid liberation.

2-(2-Bromoethyl)-1,3-dioxane synthesis

Synthesis of 2-(2-Bromoethyl)-1,3-dioxane from Acrolein and 1,3-Propanediol

2-(2-Bromoethyl)-1,3-dioxane Preparation Products And Raw materials

Raw materials

1,3-Dioxane, 2-(2-iodoethyl)- 3-bromopropanal 1,3-Propanediol 1,2-Dibromoethane Acrolein

Preparation Products

2-(2-Bromoethyl)-1,3-dioxane Suppliers

Global( 205)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Finetech Industry Limited	+86-27-87465837 +8618971612321	info@finetechnology-ind.com	China	9640	58
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-18789408387	1057@dideu.com	China	3957	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29798	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18628	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21663	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32836	60
Zjartschem	+86-571 87238903	jocelynpan@zjarts.com	CHINA	993	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10311	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8348	58

Supplier	Advantage
Finetech Industry Limited	58
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Zjartschem	58
Shenzhen Nexconn Pharmatechs Ltd	58
Jinan Carbotang Biotech Co.,Ltd.	58

View Lastest Price from 2-(2-Bromoethyl)-1,3-dioxane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-08-15	2-(2-Bromoethyl)-1,3-dioxane 33884-43-4	US $1.00 / KG	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd
2022-10-01	2-(2-Bromoethyl)-1,3-dioxane 33884-43-4	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.
2019-12-23	2-(2-Bromoethyl)-1,3-dioxane 33884-43-4	US $1.00 / g	1g	99%	1000KGS	Career Henan Chemical Co

2-(2-Bromoethyl)-1,3-dioxane
33884-43-4
US $1.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

2-(2-Bromoethyl)-1,3-dioxane
33884-43-4
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

2-(2-Bromoethyl)-1,3-dioxane
33884-43-4
US $1.00 / g
99%
Career Henan Chemical Co

2-(2-Bromoethyl)-1,3-dioxane Spectrum

2-(2-Bromoethyl)-1,3-dioxane(33884-43-4)MS 2-(2-Bromoethyl)-1,3-dioxane(33884-43-4)¹HNMR 2-(2-Bromoethyl)-1,3-dioxane(33884-43-4)¹³CNMR 2-(2-Bromoethyl)-1,3-dioxane(33884-43-4)IR1 2-(2-Bromoethyl)-1,3-dioxane(33884-43-4)Raman

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1,3-Dioxane, 2-(2-bromoethyl)- 2-(2-bromoethyl)-3-dioxane 3-BROMOPROPIONALDEHYDE TRIMETHYLENE ACETAL 2-(2-BROMOETHYL)-1,3-DIOXANE LABOTEST-BB LT00233134 2-Bromopropanal 1,3-propanediol acetal~2-Bromopropionaldehyde trimethylene acetal 2-Bromopropionaldehyde trimethylene acetal 2-(2-BROMOETHYL)-1,3-DIOXANE, STAB. 2-bromopropanal 1,3-propanediol acetal 2-Bromopropionaldehy 2-(2-BroMoethyl)-1,3-dioxane, 97.0%(GC) 2-(2-Bromoethyl)-1,3-dioxane 98% 2,2,6-trimethyl-4H -1,3-dioxene-4-ketone 2-(2-Bromoethyl)-1,3-dioxane> )-1,3-dioxane 2-(2-Bromethyl)-1,3-dioxane 33884-43-4 Dioxanes & Dioxolanes Dioxanes HALOGEN Acetals/Ketals/Ortho Esters Organic Building Blocks Oxygen Compounds Building Blocks Acetals/Ketals/Ortho Esters Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Aliphatics Halides Dioxanes Dioxanes & Dioxolanes