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(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole

CAS No.: 148461-16-9

Chemical Name:: (4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole

Synonyms: (S)-t-BuPHOX;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%;(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline,98%;(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole;(S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole;(S)-4-(tert-butyl)-2-(2-(diphenylphosphanyl)phenyl)-4,5-dihydrooxazole;(S)-4-(tert-butyl)-2-(2-(diphenylphosphaneyl)phenyl)-4,5-dihydrooxazole;2-[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]-diphenylphosphane;(4S)-4-tert-butyl-2-[2-(diphenylphosphanyl)phenyl]-4,5-dihydro-1,3-oxazole

CBNumber:: CB02093048

Molecular Formula:: C25H26NOP

Molecular Weight:: 387.45

MOL File:: 148461-16-9.mol

MSDS File:: SDS

Modify Date:: 2025/3/19 22:01:29

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(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Properties

Melting point	111-116 °C
Boiling point	498.9±28.0 °C(Predicted)
storage temp.	-20°C
pka	4.44±0.70(Predicted)
form	solid
optical activity	[α]22/D -57.0°, c = 1 in chloroform
InChI	InChI=1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChIKey	DMOLTNKQLUAXPI-HSZRJFAPSA-N
SMILES	O1C[C@H](C(C)(C)C)N=C1C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338
Safety Statements	24/25
WGK Germany	3
HS Code	29319090

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole price More Price(2)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	688495	(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%	148461-16-9	100MG	₹12416.28	2022-06-14	Buy
Sigma-Aldrich(India)	688495	(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97%	148461-16-9	500MG	₹49394.48	2022-06-14	Buy

Product number	Packaging	Price	Buy
688495	100MG	₹12416.28	Buy
688495	500MG	₹49394.48	Buy

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Chemical Properties,Uses,Production

Chemical Properties

Colorless solid

Uses

(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline can be used as a ligand for enantioselective Heck reaction without any C=C double bond migration byproduct. It can also be used in a rhodium(I)-catalyzed enantioselective desymmetrization reaction of meso-3,5-dimethyl glutaric anhydride, to form substituted syn-deoxypolypropionate fragments in a single transformation.

General Description

The product is a phosphinooxazoline (PHOX) ligand introduced by Pfaltz and coworkers. These non-symmetrical modular P,N-ligands are particularly useful in cases where double bond migration leads to undesired products or mixtures of isomers.

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Preparation Products And Raw materials

Raw materials

Preparation Products

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole Suppliers

Global( 73)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6100	58	Inquiry
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-+86-371-66670886	China	19777	58	Inquiry
Zhengzhou Alfa Chemical Co.,Ltd	+8618530059196	China	12132	58	Inquiry
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	China	30231	58	Inquiry
RR Scientific LLC	+86-13917743231	United States	878	58	Inquiry
Aladdin Scientific		United States	57505	58	Inquiry
Shaanxi Dideu New Materials Co. Ltd	+86-18192503167 +86-18192503167	China	3455	58	Inquiry
Amadis Chemical Company Limited	571-89925085	China	131957	58	Inquiry
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	025-66028182 18626450290	China	16684	50	Inquiry
Jinan Kabotang Biological Technology Co.,Ltd.	0531-61320525 15866703830	China	7563	58	Inquiry

Supplier	Advantage
A.J Chemicals	58
Shanghai Daken Advanced Materials Co.,Ltd	58
Zhengzhou Alfa Chemical Co.,Ltd	58
Career Henan Chemica Co	58
RR Scientific LLC	58
Aladdin Scientific	58
Shaanxi Dideu New Materials Co. Ltd	58
Amadis Chemical Company Limited	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	50
Jinan Kabotang Biological Technology Co.,Ltd.	58

148461-16-9((4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole)Related Search:

tert-Butyl methyl ether Diphenyl-t-Butylsilanol (S)-4-benzyl-2-(quinolin-2-yl)-4,5-dihydrooxazole (4R)-4-(1,1-diMethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-Oxazole

(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline (4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole (S)-4-(tert-Butyl)-2-(2-(diphenylphosphino)phenyl)-4,5-dihydrooxazole (4S)-4-(1,1-Dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole,99%e.e. (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline,98% (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 97% Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-, (4S)- 2-[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]phenyl]-diphenylphosphane (S)-4-(tert-butyl)-2-(2-(diphenylphosphanyl)phenyl)-4,5-dihydrooxazole (S)-4-(tert-butyl)-2-(2-(diphenylphosphaneyl)phenyl)-4,5-dihydrooxazole (S)-t-BuPHOX (4S)-4-tert-butyl-2-[2-(diphenylphosphanyl)phenyl]-4,5-dihydro-1,3-oxazole (S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline 148461-16-9 C25H26NOP Chiral Phosphine PHOX Series