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1,4-Dibromopentane

1,4-Dibromopentane Structure
CAS No.
626-87-9
Chemical Name:
1,4-Dibromopentane
Synonyms
1,4-Dibrompentan;1,4-DIBROMOPENTANE;1,4-dibromo-pentan;pentane,1,4-dibromo-;1,4-Dibromopentane >1,4-Dibromopentane,97%;(RS)-1,4-Dibromopentane;1,4-DibroMopentane, 97% 25GR;1,4-DibromopentaneDISC 05/09/02;1,4-Dibromopentane ISO 9001:2015 REACH
CBNumber:
CB0496070
Molecular Formula:
C5H10Br2
Molecular Weight:
229.94
MOL File:
626-87-9.mol
MSDS File:
SDS
Modify Date:
2023/12/28 18:13:10

1,4-Dibromopentane Properties

Melting point -34.4 °C (lit.)
Boiling point 98-99 °C/25 mmHg (lit.)
Density 1.687 g/mL at 25 °C (lit.)
refractive index n20/D 1.508
Flash point >110°C
storage temp. 2-8°C
form clear liquid
Specific Gravity 1.687
color Colorless to Light orange to Yellow
Water Solubility Insoluble in water.
BRN 605295
CAS DataBase Reference 626-87-9(CAS DataBase Reference)
NIST Chemistry Reference Pentane, 1,4-dibromo-(626-87-9)
EPA Substance Registry System Pentane, 1,4-dibromo- (626-87-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-36/38-22
Safety Statements  26-36-37/39
WGK Germany  3
TSCA  Yes
HS Code  29033919
NFPA 704
0
2 0

1,4-Dibromopentane price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 252077 1,4-Dibromopentane 97% 626-87-9 25G ₹3171.73 2022-06-14 Buy
TCI Chemicals (India) D1408 1,4-Dibromopentane min. 95.0 % 626-87-9 5G ₹1500 2022-05-26 Buy
ALFA India ALF-L09842-22 1,4-Dibromopentane, 97% 626-87-9 100g ₹10295 2022-05-26 Buy
TCI Chemicals (India) D1408 1,4-Dibromopentane min. 95.0 % 626-87-9 25G ₹3800 2022-05-26 Buy
ALFA India ALF-L09842-14 1,4-Dibromopentane, 97% 626-87-9 25g ₹5385 2022-05-26 Buy
Product number Packaging Price Buy
252077 25G ₹3171.73 Buy
D1408 5G ₹1500 Buy
ALF-L09842-22 100g ₹10295 Buy
D1408 25G ₹3800 Buy
ALF-L09842-14 25g ₹5385 Buy

1,4-Dibromopentane Chemical Properties,Uses,Production

Chemical Properties

clear colorless to light yellow-brown liquid with a wine smell.

Uses

1,4-Dibromopentane is used in the preparation of pharaoh ant trail pheromone stereoisomer, indolizidine alkaloid. It is also involved in the preparation 1,2-dimethyl-1-phenylcyclopentane and boc-L-2-amino-6-bromoheptanoic acid.

Preparation

1,4-Dibromopentane is synthesized by ring-opening bromination of 2-methyltetrahydrofuran with hydrobromic acid and sulfuric acid. First, add hydrobromic acid into the reaction pot for cooling, slowly add 2-methyltetrahydrofuran and sulfuric acid in turn under stirring, and finish the addition when the temperature does not exceed 40°C. The temperature was raised to 60°C, reacted for 2h, and then reacted at 80-85°C for 4h. After cooling, the bromide was separated and washed with water until neutral to obtain 1,4-dibromopentane as an oily substance. Yield 92.5%.

Synthesis Reference(s)

Journal of the American Chemical Society, 74, p. 917, 1952 DOI: 10.1021/ja01124a016

1,4-Dibromopentane Preparation Products And Raw materials

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1,4-DibroMopentane, 97% 25GR 1,4-DIBROMOPENTANE (RS)-1,4-Dibromopentane 1,4-dibromo-pentan 1,4-DibromopentaneDISC 05/09/02 pentane,1,4-dibromo- 1,4-Dibromopentane,97% 1,4-Dibrompentan sodium 1-amino-4-(2,4-dimethylanilino)-9,10-dioxo-2-anthracenesulfonate 1,4-Dibromopentane > 1,4-Dibromopentane ISO 9001:2015 REACH 626-87-9 BrCH23CHBrCH3 C5H10Br2 626879 CH3CHBrCH2CH2CH2Br Alkyl Organic Building Blocks Building Blocks Halogenated Hydrocarbons Alkyl Halogenated Hydrocarbons Organic Building Blocks