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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Structure
CAS No.
443347-10-2
Chemical Name:
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
Synonyms
(S)-Xyl-P-Phos;(S)-XYLYL-P-PHOS;(R)-XYLYL-P-PHOS;CTH-(S)-XYLYL-P-PHOS;CTH-(R)-XYLYL-P-PHOS;min.cth-(s)-xylyl-p-phos;(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS&;(S)-(-)-2,2'',6,6''-Tetramethoxy-4,4''-bis(di(3,5-xylyl)phosphi;(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE;(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
CBNumber:
CB1116203
Molecular Formula:
C46H50N2O4P2
Molecular Weight:
756.85
MOL File:
443347-10-2.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06
Request For Quotation

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Properties

Melting point 158-162°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color white to pale yellow
Water Solubility Sparingly soluble in water.
CAS DataBase Reference 443347-10-2

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36
WGK Germany  3
NFPA 704
1
1 0

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 675946 (S)-(−)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine 97% 443347-10-2 100MG ₹5499.1 2022-06-14 Buy
Sigma-Aldrich(India) 675946 (S)-(−)-2,2′,6,6′-Tetramethoxy-4,4′-bis[di(3,5-xylyl)phosphino]-3,3′-bipyridine 97% 443347-10-2 500MG ₹18489.1 2022-06-14 Buy
ALFA India ALF-044614-77 (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine 443347-10-2 0.1g ₹7080 2022-05-26 Buy
ALFA India ALF-044614-02 (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine 443347-10-2 0.5g ₹35400 2022-05-26 Buy
Product number Packaging Price Buy
675946 100MG ₹5499.1 Buy
675946 500MG ₹18489.1 Buy
ALF-044614-77 0.1g ₹7080 Buy
ALF-044614-02 0.5g ₹35400 Buy

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Chemical Properties,Uses,Production

Chemical Properties

White solid

Uses

(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine is used in Pharmaceutical and industry applications.

Reactions

  1. Chiral ligand for the asymmetric hydrogenation of β-keto esters.
  2. Chiral ligand for enantioselective rhodium-catalyzed [2+2+2] carbocyclization reactions.
  3. Chiral ligand for ruthenium catalyzed hydrogenation of (E)-β-(acylamino)acrylates to β-amino acids.
  4. The Rhodium complex gives higher enantioselectivity for hydrogenation of (Z)-β-(acylamino)acrylates to β-amino acids.
  5. Chiral ligand for copper-catalyzed asymmetric hydrosilylation of ketones.
  6. Chiral ligand for asymmetric allylic substitution reactions using boronic acids as nucleophiles.
  7. Gives useful selectivity in asymmetric Pauson-Khand-type cyclizations.
Reactions of 443347-10-2

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Suppliers

Global( 42)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 52927 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
Aikon International Limited 025-58851090 13611564524 China 15952 58 Inquiry
Shanghai Kaiwei Chemical Technology Co., Ltd. 021-58461859 15821823057 China 49323 58 Inquiry
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 15801484223; China 29778 58 Inquiry
Henan Weituxi Chemical Technology Co., Ltd. 0371-63284658 18135795563 China 10006 58 Inquiry
Riedel-de Haen AG 800 558-9160 United States 6825 87 Inquiry
Bide Pharmatech Ltd. 400-6005915 China 39661 58 Inquiry
Supplier Advantage
Alfa Aesar 58
CHEMSWORTH 30
Aladdin Scientific 58
ABCR GmbH & CO. KG 75
Aikon International Limited 58
Shanghai Kaiwei Chemical Technology Co., Ltd. 58
Beijing Jin Ming Biotechnology Co., Ltd. 58
Henan Weituxi Chemical Technology Co., Ltd. 58
Riedel-de Haen AG 87
Bide Pharmatech Ltd. 58

443347-10-2((R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE)Related Search:

(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine,min.95%CTH-(S)-Xylyl-P-Phos (r)-(+)-2,2',6,6'-tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine *cth-(r)-xylyl-p-phos* (s)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine *cth-(s)-xylyl-p-phos* (R)-(+)-2,2'',6,6''-TETRAMETHOXY-4,4''-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3''-BIPYRIDINE *CTH-(R)-XYLYL-P-PHO (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, CTH-(S)-Xylyl-P-Phos, 95% Application:Asymmetric hydrogenation Store N2Ar (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine *CTH-(S)-Xylyl-P-Pho (3S)-4,4'-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2',6,6'-tetramethoxy-3,3'-bipyridine (S)-Xyl-P-Phos (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis[di(3,5-xylyl)phosphino]-3,3'-bipyridine 97% CTH-(R)-XYLYL-P-PHOS CTH-(S)-XYLYL-P-PHOS (S)-XYLYL-P-PHOS (S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE (R)-XYLYL-P-PHOS (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE (S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS& min.cth-(s)-xylyl-p-phos (S)-4,4'-Bis(bis(3,5-dimethylphenyl)phosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine 3,3'-Bipyridine, 4,4'-bis[bis(3,5-dimethylphenyl)phosphino]-2,2',6,6'-tetramethoxy-, (3S)- (S)-4,4'-Bis(bis(3,5-dimethylphenyl)phosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine[(S)-Xylyl-P-Phos (S)-(-)-2,2'',6,6''-Tetramethoxy-4,4''-bis(di(3,5-xylyl)phosphi (S)-4,4'-Bis(bis(3,5-dimethylphenyl)phosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine 443347-10-2 C46H50N2O4P2 Hydrogenation Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents