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Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Structure
CAS No.
31277-98-2
Chemical Name:
Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
Synonyms
Pd(dppe)2;PD(DIPHOS)2;Bis[1,2-bis(diphenyL;phosphino)ethane]paL;Pd(DIPHOS)2 Pd(dppe)2;Bisbisdiphenylphosphi;BIS(DIPHOS)PALLADIUM(0);Bis[1,2-bis(diphenylphosphino);Bis(DIPHOS)palladium(0), Pd(DIPHOS)2;Bis[1,2-bis(diphenylphosphino)ethane]
CBNumber:
CB1230635
Molecular Formula:
C52H48P4Pd
Molecular Weight:
903.25
MOL File:
31277-98-2.mol
MSDS File:
SDS
Modify Date:
2025/1/27 9:38:02

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Properties

Melting point 219-225 °C
storage temp. -20°C
solubility sol nonprotic solvents
form Powder
color orange
Water Solubility insoluble
Sensitive Air Sensitive
InChI InChI=1S/2C26H24P2.Pd/c2*1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h2*1-20H,21-22H2;
InChIKey UTBLWXFSGOYWOH-UHFFFAOYSA-R
SMILES P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Pd]
CAS DataBase Reference 31277-98-2

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38
Safety Statements  36-37/39-26
RIDADR  1479
WGK Germany  3
HazardClass  5.1
PackingGroup  III
HS Code  28439000
NFPA 704
0
2 0

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 230278 Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2 1G ₹8447.1 2022-06-14 Buy
TCI Chemicals (India) B3224 Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2 1G ₹8500 2022-05-26 Buy
TCI Chemicals (India) B3224 Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 31277-98-2 5G ₹18800 2022-05-26 Buy
Product number Packaging Price Buy
230278 1G ₹8447.1 Buy
B3224 1G ₹8500 Buy
B3224 5G ₹18800 Buy

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Chemical Properties,Uses,Production

Chemical Properties

yellow to orange crystalline powder

Uses

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) is a homogeneous catalyst most widely used in allylic substitution reactions; good catalyst for bulky substrates; slowly dissociating ligand that gives good stereoselectivity.

storage

air and light sensitive. If stored under nitrogen or argon it is stable for  about one month. Avoid inhalation. Use in a fume hood.

Purification Methods

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) can be recrystallized from benzene-ethanol or ethanol.

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 179)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6100 58 Inquiry
Mehta Enterprise 08068442230Ext 607 Mumbai, India 155 58 Inquiry
Souvenier Chemicals 08048372762Ext 645 Mumbai, India 396 58 Inquiry
Shaoxin Catsyn Co., Ltd. +undefined-0575-82040869 +86-0575-82040869; China 6114 58 Inquiry
Capot Chemical Co.,Ltd. +86-(0)57185586718 +86-13336195806 China 29730 60 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-+86-371-66670886 China 19809 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29859 58 Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
SIMAGCHEM CORP +86-13806087780 China 17365 58 Inquiry

Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Spectrum

BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PALLADIUM BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(0) BIS(DIPHOS)PALLADIUM(0) PD(DIPHOS)2 bis(ethylenebis(diphenylphosphine))palladium Bisbisdiphenylphosphinoethanepalladium Bis[1,2-bis(diphenylphosphino)ethane]palladium(0),98% Pd(dppe)2 Bis1,2-bis(diphenylphosphino)ethaneüpalladium (0) Bis(DIPHOS)palladium(0), Pd(DIPHOS)2 1,2-Bis(diphenylphosphino)ethaneüpalladium Bis[1,2-bis(diphenylphosphino)ethane] Bis{1,2-bis(diphenylphosphino)ethane}palladium (O), 98% Bis[1,2-bis(diphenylphosphino)ethane]palladiuM (0),98% Pd(DPPE)2 Pd(DIPHOS)2 Pd(dppe)2 Bis[1,2-bis(diphenylphosphiNA)ethane]palladiuM(0) Bis[1,2-bis(diphenylphosphino) 2-diphenylphosphanylethyl(diphenyl)phosphane,palladium Bisbisdiphenylphosphi Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)> Bis[1,2-bis(diphenyL phosphino)ethane]paL Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) ISO 9001:2015 REACH 31277-98-2 PdC6H52PCH2CH2PC6H522 C6H52PCH2CH2PC6H522Pd C52H48P4Pd 2C26H24P2Pd Homogeneous Pd Catalysts Catalysis and Inorganic Chemistry Pd Pyrimidines metal-phosphine complexes Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes Pd (Palladium) Compounds Synthetic Organic Chemistry Transition Metal Compounds