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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Structure
CAS No.
95464-05-4
Chemical Name:
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms
Pd(dppf)2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;ex with dichL;adium(II),compL;Pd(dppf)Cl2 DCM
CBNumber:
CB1347621
Molecular Formula:
C34H28Cl2FeP2Pd.CH2Cl2
Molecular Weight:
816.63
MOL File:
95464-05-4.mol
MSDS File:
SDS
Modify Date:
2024/8/11 15:28:25

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Properties

Melting point 275-280 °C(lit.)
Density 1 g/cm3
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color orange-red
Water Solubility Insoluble in water.
Stability Light Sensitive
CAS DataBase Reference 95464-05-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-40-67-48/20/22
Safety Statements  23-24/25-26-36/37
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
1
2 1

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 1G ₹4220 2022-06-14 Buy
Sigma-Aldrich(India) 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 5G ₹16061.7 2022-06-14 Buy
Sigma-Aldrich(India) 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 25G ₹70485 2022-06-14 Buy
Sigma-Aldrich(India) 379670 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane 95464-05-4 250G ₹296358.9 2022-06-14 Buy
TCI Chemicals (India) B2064 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct 95464-05-4 1G ₹5500 2022-05-26 Buy
Product number Packaging Price Buy
379670 1G ₹4220 Buy
379670 5G ₹16061.7 Buy
379670 25G ₹70485 Buy
379670 250G ₹296358.9 Buy
B2064 1G ₹5500 Buy

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Uses,Production

Chemical Properties

orange/red solid

Uses

suzuki reaction

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Synthesis

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Spectrum

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloMethane coMplex (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladiuM-dichloroMethane (1:1) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(TM) tablets Loading: 2mumol per tablet 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride dichloromethane adduct 1, 1-Bis(diphenylphosphino)Ferrocene] dichloropalaldium(II) complex with DCM Palladium, [1,1'-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-, compd. with dichloromethane Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1) Bis(diphenylphosphino)ferrocene palladium dichloride, dichloromethane solvate Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose? tablets 1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE ADDUCT DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE COMPLEX [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1) 1,1'-Bis(diphenylphosphiNA)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHA 1,1'-Bis(diphenylphosphino)fer Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), coMplex with dichloroMethane (1:1), Pd 13% 1,1'-Bis(diphenylphosphino)ferrocene palladium(Ⅱ)chloride dichloromethane complex PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd 13% [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(R) tablets ChemDose(R), [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE-PALLADIUM(II)DICHLORIDE DICHLOROMETHANE ADDUCT [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DCM ADDUCT [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DICHLOROMETHANE ADDUCT [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II) DICHLOROMETHANE COMPLEX 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) CHLORIDE, 1:1 COMPLEX WITH DICHLOROMETHANE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE, COMPLEX WITH DICHLOROMETHANE 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane [1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladiuM(II) coMplex with dichlor 1,1'-Bis(diphenylphosphino)ferrocene-palladiuMdichloride dichloroMethanecoMplex [1,1'-bis (diphenylphosphino) ferrocene] dichloropalladiuM dichloroMethane coMplex [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1) Pd(dppf)Cl2 DCM [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1) [1,1Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)H2Cl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex.dichloromethane [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex [Pd(dppf)Cl2.CH2Cl2] [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane,Pd(dppf)Cl2 · DCM 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dic 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane com 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex ,97% [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloroMethane adduct, (DPPF)PdCl2·CH2Cl2 Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane, 99% cyclopenta-2,4-dien-1-yl(diphenyl)phosphane DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)F dichloride dichloromethane complex [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct>