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Dihydromyrcenol

Dihydromyrcenol Structure
CAS No.
53219-21-9
Chemical Name:
Dihydromyrcenol
Synonyms
DIHYDROMERCENOL;Dihydrolaurenol;DITHDRO MYRCENOL;Dihydrop Myrcenol;DIHYDROMYRCENOL(SG);Dihydro myrcene alcohol;(R)-2,6-Dimethyl-7-octen-2-ol;2-Methyl-6-methylene-2-octanol;2-Methyl-6-methylideneoctan-2-ol;dihydromyrcenol dihydro derivative
CBNumber:
CB2161684
Molecular Formula:
C10H20O
Molecular Weight:
156.27
MOL File:
53219-21-9.mol
Modify Date:
2024/5/15 13:17:26

Dihydromyrcenol Properties

Boiling point 91 °C(Press: 10 Torr)
color A colourless, somewhat viscous oil
CAS DataBase Reference 53219-21-9
EPA Substance Registry System 7-Octen-2-ol, 2-methyl-6-methylene-, dihydro deriv. (53219-21-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Hazard Codes  Xi
Risk Statements  36
Safety Statements  26
Toxicity The acute oral LD50 in rats was reported as 3.6 g/kg (3.0-4.2 g/kg) (Mor eno, 1973). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1973).
NFPA 704
2
1 0

Dihydromyrcenol Chemical Properties,Uses,Production

Description

Dihydromyrcenol is a colorless liquid with a fresh citrus-like odor and a lavender note. It is obtained from 3,7-dimethyl-1,6- octadiene (citronellene), the pyrolysis product of cis-pinane and can be prepared by three different processes: (i) by addition of hydrogen chloride and subsequent hydrolysis of the resulting 2,6-dimethyl-2-chloro-7-octene; or (ii) by addition of formic acid and subsequent saponification of the resulting dihydromycrenyl formate; or (iii) by direct hydroxylation with 60–80% sulfuric acid.Dihydromyrcenol is used in fine fragrances as well as in soap and detergent perfumes for fresh lime and citrus-like floral notes.

Chemical Properties

Clear Colorless liquid, insoluble in water, soluble in 4-6 volumes of 55% ethanol or 1-2 volumes of 70% ethanol, also soluble in oily fragrances. The aroma is sweet and powerful, with fresh and spicy citrus, pine and cypress, lavender, fruity, floral, sweet and sour aromas, and has white lemon and cologne flavors.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Dihydromyrcenol is an organic compound from the group of the acyclic terpenoidal alcohols. It is a fragrance with a powerful, fresh, lavender like, sweet citrus and floral fragrance, which is synthetically prepared. The pure substance appears as a colorless viscous liquid, which is practically insoluble in water.

Preparation

Dihydromyrcenol is prepared by addition of dihydromyrcene (generated from the cleavage of pinane, the hydrogenation product of pinene), with water and formic acid under acid catalysis.
By controlled, partial hydrogenation of myrcenol (Arctander, 1969).

Dihydromyrcenol Preparation Products And Raw materials

Raw materials

Preparation Products

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DIHYDROMYRCENOL(SG) DIHYDROMERCENOL 2-Methyl-6-methylenoct-7-en-ol, Dihydroderivat 2-Methyl-6-methylene-2-octanol 2-Methyl-6-methylideneoctan-2-ol (R)-2,6-Dimethyl-7-octen-2-ol Dihydro myrcene alcohol 7-Octen-2-ol,2-methyl-6-methylene-,dihydroderiv. 2-methyl-6-methylene-7-octen-2-odihydroderiv. Dihydromyrcenol2-Methyl-6-methylene-2-octanol 2-methyl-6-methyleneoct-7-en-2-ol, dihydro derivative Dihydrop Myrcenol DITHDRO MYRCENOL dihydromyrcenol dihydro derivative Dihydrolaurenol 53219-21-9 Aroma Chemicals