(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Structure
CAS No.
174467-31-3
Chemical Name:
(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Synonyms
]-2,2'-bis(diphenyL;(SP,S'P)-1,1'-Bis[(R)-aL; (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe;(SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene;(2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;(1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene;(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene;(R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
CBNumber:
CB23357015
Molecular Formula:
C52H48FeN2P2
Molecular Weight:
818.76
MOL File:
174467-31-3.mol
Modify Date:
2023/4/23 13:52:06

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Properties

alpha -320.0° (c 1.0, CHCl3)
form solid
color orange-red
Stability store cold

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
WGK Germany  3

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Chemical Properties,Uses,Production

Uses

Chlorotricarbonyl(4,4'-di-t-butyl-2,2'-bipyridine)rhenium(I) is used for the reduction of carbon dioxide as a catalyst.

Reactions

  1. Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate.
  2. Ligand used for the gold-catalyzed phenol synthesis from furyldialkyne.
  3. Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [( 6 -benzylamine)Cr(CO)3]
  4. Ligand used for the palladium-catalyzed asymmetric synthesis of α-allyl-α-aryl α-amino acids by tandem alkylation/π-allylation of α-iminoesters
Reactions of 174467-31-3_1 Reactions of 174467-31-3_2 Reactions of 174467-31-3_3 Reactions of 174467-31-3_4

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene Suppliers

Global( 23)Suppliers
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Bide Pharmatech Ltd. 400-164-7117 13681763483 China 41463 60 Inquiry
(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene (2R,2'R)-1,1'-BIS[(R)-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (SP,S'P)-1,1'-Bis[(R)-aL (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phe (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene ]-2,2'-bis(diphenyL (S,S)Fc-1,1’- Bis(diphenylphosphino)-2,2'- bis[(R,R)C-(N,Ndimethylamino)phenylmethyl]fer rocene (SP,S′P)-1,1′-Bis[(R)-α-(dimethylamino)benzyl]-2,2′-bis(diphenylphosphino)ferrocene (1R,1'R)-1,1'-bis(diphenylphosphino)-2,2'-bis[(R)-(dimethylamino) phenylmethyl]ferrocene (SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene (S,S)-(-)-2,2''-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1''-bis(diphenylphosphino)ferrocene (Sp,Sp)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene (R,R)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene 174467-31-3