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4-Bromobiphenyl

4-Bromobiphenyl Structure
CAS No.
92-66-0
Chemical Name:
4-Bromobiphenyl
Synonyms
92-66-0;4-BROMO-1,1'-BIPHENYL;pbb 3;P-BROMOBIPHENYL;PBB NO 3;4-Bromodipheny;4-Brom-biphenyl;4-BROMOBIPHENYL;4-BROMODIPHENYL;P-BROMODIPHENYL
CBNumber:
CB2489092
Molecular Formula:
C12H9Br
Molecular Weight:
233.1
MOL File:
92-66-0.mol
Modify Date:
2024/7/30 9:48:36
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4-Bromobiphenyl Properties

Melting point 82-86 °C(lit.)
Boiling point 310 °C(lit.)
Density 0.9327
refractive index 1.6565 (estimate)
Flash point 143 °C
storage temp. Sealed in dry,Room Temperature
solubility dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow
form Crystalline Flakes
color Almost white to slightly yellow
Water Solubility Insoluble
BRN 1907453
Stability Stable. Incompatible with oxidizing agents.
InChIKey PKJBWOWQJHHAHG-UHFFFAOYSA-N
CAS DataBase Reference 92-66-0(CAS DataBase Reference)
NIST Chemistry Reference 1,1'-Biphenyl, 4-bromo-(92-66-0)
EPA Substance Registry System 4-Bromobiphenyl (92-66-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302-H315-H318-H335-H400
Precautionary statements  P273-P280-P301+P312+P330-P305+P351+P338+P310-P391
Hazard Codes  Xi,N,Xn
Risk Statements  36/37/38-50/53-41-37/38-22
Safety Statements  22-24/25-37/39-26-61-60-39
RIDADR  UN 3152 9/PG 2
WGK Germany  3
RTECS  DV1750100
TSCA  T
HazardClass  IRRITANT
PackingGroup  Ⅲ
HS Code  29036990
NFPA 704
1
2 0

4-Bromobiphenyl price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 281999 4-Bromobiphenyl 98% 92-66-0 10G ₹2553.1 2022-06-14 Buy
Sigma-Aldrich(India) 281999 4-Bromobiphenyl 98% 92-66-0 50G ₹7817.55 2022-06-14 Buy
Product number Packaging Price Buy
281999 10G ₹2553.1 Buy
281999 50G ₹7817.55 Buy

4-Bromobiphenyl Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators.  It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.

Uses

4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.

General Description

Colorless crystals. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.

Fire Hazard

Combustible.

Synthesis

Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.

Purification Methods

Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]

4-Bromobiphenyl Preparation Products And Raw materials

Raw materials

PotassiuM iodide starch pa Biphenyl Dextrin 4-Bromoaniline Triphenylindium
1-(4-bromo-phenyl)-cyclohexanol 4-Bromophenylboronic acid 4-BROMOBENZENEDIAZONIUM TETRAFLUOROBORATE TRIBUTYLPHENYLTIN 1-Bromo-4-iodobenzene
BENZENEDIAZONIUM,TETRAFLUOROBORATE
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Preparation Products

1-(4'-Bromobiphenyl-4-yl)-3-phenylpropenone Bromadiolone Brodifacoum 4-Iodobiphenyl 4-Biphenylboronic acid
N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine 4-Ethynyl-4'-pentyl-1,1'-biphenyl 4-(4-BIPHENYLYL)BUTYRIC ACID 4,4'-DIPHENYLBENZOPHENONE
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4-Bromobiphenyl Suppliers

Global( 669)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
GLR Innovations +91 9891111994 New Delhi, India 4542 58 Inquiry
Element Chemilink Pvt. Ltd. +91-6358814008 +91-6358814008 Gujarat, India 31 58 Inquiry
REDDY N REDDY PHARMACEUTICALS +91-9848096759 +91-9848096759 Hyderabad, India 1989 58 Inquiry
JSK Chemicals +919879767970 Gujarat, India 3756 58 Inquiry
VASIN BIO LIFE SCIENCES PVT LTD 9491644688 Hyderabad, India 2096 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6913 58 Inquiry
SynZeal Research Pvt Ltd +1 226-802-2078 Gujarat, India 6522 58 Inquiry
NSC Organics 08069013898Ext 371 Hyderabad, India 166 58 Inquiry
Supplier Advantage
GLR Innovations 58
Element Chemilink Pvt. Ltd. 58
REDDY N REDDY PHARMACEUTICALS 58
JSK Chemicals 58
VASIN BIO LIFE SCIENCES PVT LTD 58
A.J Chemicals 58
CLEARSYNTH LABS LTD. 58
Alfa Aesar 58
SynZeal Research Pvt Ltd 58
NSC Organics 58

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