4-Bromobiphenyl
- CAS No.
- 92-66-0
- Chemical Name:
- 4-Bromobiphenyl
- Synonyms
- 92-66-0;4-BROMO-1,1'-BIPHENYL;pbb 3;P-BROMOBIPHENYL;PBB NO 3;4-Bromodipheny;4-Brom-biphenyl;4-BROMOBIPHENYL;4-BROMODIPHENYL;P-BROMODIPHENYL
- CBNumber:
- CB2489092
- Molecular Formula:
- C12H9Br
- Molecular Weight:
- 233.1
- MOL File:
- 92-66-0.mol
- Modify Date:
- 2024/12/18 14:07:02
Melting point | 82-86 °C(lit.) |
---|---|
Boiling point | 310 °C(lit.) |
Density | 0.9327 |
refractive index | 1.6565 (estimate) |
Flash point | 143 °C |
storage temp. | Sealed in dry,Room Temperature |
solubility | dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow |
form | Crystalline Flakes |
color | Almost white to slightly yellow |
Water Solubility | Insoluble |
BRN | 1907453 |
Stability | Stable. Incompatible with oxidizing agents. |
InChIKey | PKJBWOWQJHHAHG-UHFFFAOYSA-N |
CAS DataBase Reference | 92-66-0(CAS DataBase Reference) |
NIST Chemistry Reference | 1,1'-Biphenyl, 4-bromo-(92-66-0) |
EPA Substance Registry System | 4-Bromobiphenyl (92-66-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS07,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H302-H315-H318-H335-H400 | |||||||||
Precautionary statements | P273-P280-P301+P312+P330-P305+P351+P338+P310-P391 | |||||||||
Hazard Codes | Xi,N,Xn | |||||||||
Risk Statements | 36/37/38-50/53-41-37/38-22 | |||||||||
Safety Statements | 22-24/25-37/39-26-61-60-39 | |||||||||
RIDADR | UN 3152 9/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | DV1750100 | |||||||||
TSCA | T | |||||||||
HazardClass | IRRITANT | |||||||||
PackingGroup | Ⅲ | |||||||||
HS Code | 29036990 | |||||||||
NFPA 704 |
|
4-Bromobiphenyl price More Price(2)
4-Bromobiphenyl Chemical Properties,Uses,Production
Chemical Properties
White powder
Uses
4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators. It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.
Uses
4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.
General Description
Colorless crystals. Insoluble in water.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.
Fire Hazard
Combustible.
Synthesis
Into a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.
Purification Methods
Crystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]
4-Bromobiphenyl Preparation Products And Raw materials
Raw materials
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GLR Innovations | 58 |
Element Chemilink Pvt. Ltd. | 58 |
REDDY N REDDY PHARMACEUTICALS | 58 |
JSK Chemicals | 58 |
VASIN BIO LIFE SCIENCES PVT LTD | 58 |
A.J Chemicals | 58 |
CLEARSYNTH LABS LTD. | 58 |
Alfa Aesar | 58 |
SynZeal Research Pvt Ltd | 58 |
NSC Organics | 58 |
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