2-ethoxy-1-naphthylamine

2-ethoxy-1-naphthylamine Structure
CAS No.
118-30-9
Chemical Name:
2-ethoxy-1-naphthylamine
Synonyms
2-ethoxy-1-naphthylamine;2-Ethoxy-1-naphthalenamine;2-ethoxynaphthalen-1-amine;1-Amino-2-ethoxynaphthalene;1-Naphthalenamine, 2-ethoxy-
CBNumber:
CB2874782
Molecular Formula:
C12H13NO
Molecular Weight:
187.24
MOL File:
118-30-9.mol
Modify Date:
2023/11/6 14:39:47

2-ethoxy-1-naphthylamine Properties

Melting point 48-49 °C(Solv: ethanol (64-17-5))
Boiling point 339.5±17.0 °C(Predicted)
Density 1.125±0.06 g/cm3(Predicted)
pka 3.40±0.10(Predicted)

2-ethoxy-1-naphthylamine Chemical Properties,Uses,Production

Uses

Sulfonation (H2SO4, 60℃) of 158 gives 1-amino-2-ethoxynaphthalene-6-sulfonic acid for use principally as an intermediate component in azo direct green dyes.

Synthesis

?A solution of 2-ethoxynaphthalene in 1,2-dichlorobenzene is reacted with nitric acid at 45℃. The organic layer is separated and washed at 60℃ before cooling to crystallize 1-nitro-2-ethoxynaphthalene (mp 95 – 100℃) in 80 % yield. Reduction with iron gives 2-ethoxy-1-naphthylamine in 74 % yield.

2-ethoxy-1-naphthylamine Preparation Products And Raw materials

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2-ethoxynaphthalen-1-amine 2-Ethoxy-1-naphthalenamine 1-Amino-2-ethoxynaphthalene 2-ethoxy-1-naphthylamine 1-Naphthalenamine, 2-ethoxy- 118-30-9