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Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Structure
CAS No.
137203-34-0
Chemical Name:
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
Synonyms
DABAL-Me3;DABAL-trimethylaluminum;Bis(trimethylaluminum)-DABCO(R) adduct;Triethylenediaminine bis(trimethylaluminum);1,4-diazabicyclo[2.2.2]octane,trimethylalumane;DABAL-Me3 (adduct of trimethylaluminum and DABCO);1,4-DIAZABICYLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX;1,4-Diazabicyclo[2.2.2]Octane Bis(Trimethylaluminum) Complex;Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct;Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3)
CBNumber:
CB32095513
Molecular Formula:
C12H24Al2N2
Molecular Weight:
250.3
MOL File:
137203-34-0.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06
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Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Properties

Melting point >250 °C
Flash point 23°C (73°F)
storage temp. Hygroscopic, Room Temperature, Under inert atmosphere
solubility Benzene (Slightly), DMSO (Slightly)
form Solid
color White to Off-White
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Stability Hygroscopic, Moisture Sensitive, Unstable in Aqueous Solution

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H260-H302-H315-H319-H335
Precautionary statements  P231+P232-P301+P312+P330-P302+P352-P305+P351+P338
Hazard Codes  F,Xn
Risk Statements  14-15-22-36/37/38
Safety Statements  16-26-43
RIDADR  UN 3395 4.3/PG 1
WGK Germany  3

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 682101 Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct 137203-34-0 5G ₹13444.65 2022-06-14 Buy
Product number Packaging Price Buy
682101 5G ₹13444.65 Buy

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Chemical Properties,Uses,Production

Uses

Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) is a non-pyrophoric alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.1

General Description

Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere.

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Preparation Products And Raw materials

Raw materials

Preparation Products

1-Cyclopentene-1-carboxylic acid, 2-methyl-, ethyl ester

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Suppliers

Global( 31)Suppliers
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CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6257 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49374 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 13505 58 Inquiry
Dayang Chem (Hangzhou) Co.,Ltd. 571-88938639 +8617705817739 China 52849 58 Inquiry
Hangzhou MolCore BioPharmatech Co.,Ltd. +86-057181025280; +8617767106207 China 49734 58 Inquiry
PT CHEM GROUP LIMITED China 35425 58 Inquiry
GIHI CHEMICALS CO.,LIMITED +8618058761490 China 49979 58 Inquiry
Shanghai Jianchao Biotechnology Co., LTD 13621743886 13621743886 China 4563 58 Inquiry
Changzhou Bojia Biomedical Technology Co., Ltd. 2122619822 China 18478 58 Inquiry
Suzhou Haiben Pharmaceutical Co., Ltd 14760821013 13564957716 China 7437 58 Inquiry
Supplier Advantage
CLEARSYNTH LABS LTD. 58
CONIER CHEM AND PHARMA LIMITED 58
Zhengzhou Alfa Chemical Co.,Ltd 58
Dayang Chem (Hangzhou) Co.,Ltd. 58
Hangzhou MolCore BioPharmatech Co.,Ltd. 58
PT CHEM GROUP LIMITED 58
GIHI CHEMICALS CO.,LIMITED 58
Shanghai Jianchao Biotechnology Co., LTD 58
Changzhou Bojia Biomedical Technology Co., Ltd. 58
Suzhou Haiben Pharmaceutical Co., Ltd 58
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) DABAL-trimethylaluminum Bis(trimethylaluminum)-DABCO(R) adduct Triethylenediaminine bis(trimethylaluminum) Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3) DABAL-Me3 (adduct of trimethylaluminum and DABCO) 1,4-DIAZABICYLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX 1,4-Diazabicyclo[2.2.2]Octane Bis(Trimethylaluminum) Complex 1,4-diazabicyclo[2.2.2]octane,trimethylalumane DABAL-Me3 137203-34-0 C12H30Al2N2 CH33AlC6H12N2AlCH33 Greener Alternatives and Technologies Greener Alternatives: Reagents DABAL - Me3 Chemical Synthesis Organoaluminum Organometallic Reagents