Glycidyl methacrylate
- CAS No.
- 106-91-2
- Chemical Name:
- Glycidyl methacrylate
- Synonyms
- 2,3-EPOXYPROPYL METHACRYLATE;oxiran-2-ylmethyl methacrylate;Glycidyl methacylate;2-Propenoicacid,2-methyl-,oxiranylmethylester;cp105;sr379;CP 105;SR-379;blemmerg;blemmergma
- CBNumber:
- CB3258080
- Molecular Formula:
- C7H10O3
- Molecular Weight:
- 142.15
- MOL File:
- 106-91-2.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/26 17:49:17
| Melting point | -52°C |
|---|---|
| Boiling point | 189 °C(lit.) |
| Density | 1.075 g/mL at 20 °C |
| vapor pressure | 4.2hPa at 25℃ |
| refractive index |
n |
| Flash point | 169 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Liquid |
| color | Clear |
| Water Solubility | 0.5-1.0 g/100 mL at 20 ºC |
| BRN | 2506 |
| Stability | Unstable. Light sensitive. May be stabilized with around 100ppm MEHQ. Refrigerate. |
| InChIKey | VOZRXNHHFUQHIL-UHFFFAOYSA-N |
| LogP | 0.96 at 25℃ |
| CAS DataBase Reference | 106-91-2(CAS DataBase Reference) |
| IARC | 2A (Vol. 125) In prep. |
| NIST Chemistry Reference | 2-Propenoic acid, 2-methyl-, oxiranylmethyl ester(106-91-2) |
| EPA Substance Registry System | Glycidyl methacrylate (106-91-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H311-H314-H317-H335-H341-H350-H360F-H372 | |||||||||
| Precautionary statements | P202-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,T,T+ | |||||||||
| Risk Statements | 20/21/22-36/38-43-60-45-68-39/26-34 | |||||||||
| Safety Statements | 26-28-28A-45-36/37-53-36/37/39 | |||||||||
| RIDADR | UN 2810 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | OZ4375000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161490 | |||||||||
| Toxicity | dog,LCLo,inhalation,1400mg/m3/6H (1400mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,National Technical Information Service. Vol. OTS0530684, | |||||||||
| NFPA 704 |
|
Glycidyl methacrylate price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 779342 | Glycidyl methacrylate ≥97.0% (GC) | 106-91-2 | 100ML | ₹3323.28 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 779342 | Glycidyl methacrylate ≥97.0% (GC) | 106-91-2 | 500ML | ₹7739.88 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 151238 | Glycidyl methacrylate 97%, contains 100?ppm monomethyl ether hydroquinone as inhibitor | 106-91-2 | 100G | ₹2284.08 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 151238 | Glycidyl methacrylate 97%, contains 100?ppm monomethyl ether hydroquinone as inhibitor | 106-91-2 | 500G | ₹9590.95 | 2022-06-14 | Buy |
| ALFA India | ALF-L11133-30 | Glycidyl methacrylate, 97%, stab. with 100ppm 4-methoxyphenol | 106-91-2 | 250g | ₹3300 | 2022-05-26 | Buy |
Glycidyl methacrylate Chemical Properties,Uses,Production
Description
Glycidyl Methacrylate (GMA) is a clear, colorless liquid with a potent ester and fruity odor. It comprises a polymerizable methacrylate functional group on one end and a reactive epoxy group on the other. It is slightly miscible with water, soluble in most organic solvents, and has relatively low volatility. Its vapor is heavier than air. It copolymerizes readily with various functional groups, such as phenols, ketones, acids, and amines. The added epoxy group imparts durability, mechanical strength, optical transparency, and adhesiveness.
Chemical Properties
Glycidyl methacrylate (GMA) is a colorless liquid with a fruity odor. Floats on water. (USCG, 1999)
Glycidyl methacrylate is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.
Uses
Glycidyl methacrylate (GMA) is a common monomer used in the creation of epoxy resins. It is used to provide epoxy functionalization to polyolefins and other acrylate resins.
Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.
Glycidyl methacrylate dextran has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.
Preparation
Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.
Reactions
Glycidyl methacrylate (GMA) is a kind of functional monomer. Its active vinyl and epoxy groups could be grafted with polyolefin and reacted with the polar groups such as amine, hydroxyl and carboxyl group, respectively. It can also undergo polymerization to form poly (glycidyl methacrylate).
General Description
Colorless liquid with a fruity odor. Floats on water.
Air & Water Reactions
Flammable. Slightly water soluble.
Reactivity Profile
Epoxides, such as Glycidyl methacrylate, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Health Hazard
The liquid irritates eyes about as much as soap. Prolonged contact with skin produces irritation and dermatitis.
Fire Hazard
Special Hazards of Combustion Products: Irritating vapors are generated when heated
Glycidyl methacrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Triveni chemicals | 08048762458 | New Delhi, India | 6093 | 58 | Inquiry |
| A. B. Enterprises | +91-8048077585 | Mumbai, India | 1396 | 58 | Inquiry |
| Poly Dye Chem Corporation | 08068441141Ext 288 | Mumbai, India | 1 | 58 | Inquiry |
| Shriji Chemicals | 08048371958Ext 105 | Maharashtra, India | 8 | 58 | Inquiry |
| Watertech Servicing & Engineers | 08048371604Ext 547 | Uttar Pradesh, India | 1 | 58 | Inquiry |
| Oswal Udhyog | 08048981722 | Mumbai, India | 68 | 58 | Inquiry |
| Organic Chemicals | 08048372709Ext 384 | Pune, India | 75 | 58 | Inquiry |
| Otto Chemie Pvt. Ltd. | +91 9820041841 | Mumbai, India | 5873 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Triveni chemicals | 58 |
| A. B. Enterprises | 58 |
| Poly Dye Chem Corporation | 58 |
| Shriji Chemicals | 58 |
| Watertech Servicing & Engineers | 58 |
| Oswal Udhyog | 58 |
| Organic Chemicals | 58 |
| Otto Chemie Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
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