Thiomorpholine

Thiomorpholine Structure
CAS No.
123-90-0
Chemical Name:
Thiomorpholine
Synonyms
thiazinane;1,4-Thiazane;TETRAHYDRO-2H-1,4-THIAZINE;1,4-Thiazan;Parathiazan;ThiomorphoL;hiomorpholine;THIAMORPHOLINE;THIOMORPHOLINE;thiazolidinane
CBNumber:
CB3266519
Molecular Formula:
C4H9NS
Molecular Weight:
103.19
MOL File:
123-90-0.mol
MSDS File:
SDS
Modify Date:
2023/4/23 13:52:06

Thiomorpholine Properties

Melting point 166-168
Boiling point 169 °C (lit.)
Density 1.026 g/mL at 25 °C (lit.)
refractive index n20/D 1.538(lit.)
Flash point 140 °F
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility organic solvents: miscible(lit.)
pka 9.14±0.20(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
Water Solubility Miscible with waterMiscible with water and organic solvents.
Sensitive Air Sensitive
Merck 14,9300
BRN 102550
InChIKey BRNULMACUQOKMR-UHFFFAOYSA-N
CAS DataBase Reference 123-90-0(CAS DataBase Reference)
NIST Chemistry Reference Thiomorpholine(123-90-0)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P501
Hazard Codes  C,Xi
Risk Statements  34-37-36/37/38-R37-R34
Safety Statements  26-36/37/39-45-36-S45-S36/37/39-S26
RIDADR  UN 3267 8/PG 3
WGK Germany  3
10-13-23
Hazard Note  Irritant
HazardClass  8
PackingGroup  III
HS Code  29349990
NFPA 704
1
3 0

Thiomorpholine price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 196274 Thiomorpholine 98% 123-90-0 5G ₹7501.73 2022-06-14 Buy
Sigma-Aldrich(India) 196274 Thiomorpholine 98% 123-90-0 25G ₹21065.45 2022-06-14 Buy
ALFA India ALF-L19470-14 Thiomorpholine, polymer-supported, 0.8-1.1mmol/g on Merrifield resin 123-90-0 25g ₹42929 2022-05-26 Buy
ALFA India ALF-L19470-06 Thiomorpholine, polymer-supported, 0.8-1.1mmol/g on Merrifield resin 123-90-0 5g ₹11012 2022-05-26 Buy
ALFA India ALF-L19470-03 Thiomorpholine, polymer-supported, 0.8-1.1mmol/g on Merrifield resin 123-90-0 1g ₹3130 2022-05-26 Buy
Product number Packaging Price Buy
196274 5G ₹7501.73 Buy
196274 25G ₹21065.45 Buy
ALF-L19470-14 25g ₹42929 Buy
ALF-L19470-06 5g ₹11012 Buy
ALF-L19470-03 1g ₹3130 Buy

Thiomorpholine Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

Thiomorpholine is used as an intermediate for blonanserin. It is used in the preparation of pyrrole derivatives, which acts as a antimycobacterial agent. It is further involved in the hypocholesterolemic activity.

Definition

ChEBI: A saturated organic heteromonocyclic parent that is an analogue of morpholine where the oxygen atom is replaced by sulfur.

General Description

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Purification Methods

Purify it by vacuum distillation. The hydrochloride has m 179o (from isoPrOH or EtOH/Et2O/HCl). [Davies J Chem Soc 306 1920, Beilstein 27 II 4, 2 III/IV 636.]

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Tetrahydro-2H-1,4-thiazine, Thiamorpholine Thiomorpholine,97% ThioMorpholine, 97% 5GR Thiomorpholine ,98% 1,4-Thiazinane, Tetrahydro-2H-1,4-thiazine ThioMorpholine 98.0%Min ThioMorpholine 98% 4-THIOMORPHOLINE THIOMORPHOLINE THIAMORPHOLINE TETRAHYDRO-1,4-THIAZINE TETRAHYDRO-4H-1,4-THIAZINE 1,4-Thiazan 1,4-Thiazine, tetrahydro- 1-Thia-4-azacyclohexane Parathiazan thiazolidinane ThiomorphoL Thiomorpholine, 98%, for synthesis thiazinane 1,4-Thiazane TETRAHYDRO-2H-1,4-THIAZINE hiomorpholine sulfanylMorpholine Thiomorpholine, ≥ 98.0% 123-90-0 C4H9NS C4H10NS Morpholines Others S-Containing Building Blocks Heterocyclic Building Blocks AMINE Pyrimidines Building Blocks Chemical Synthesis Heterocyclic Building Blocks Others S-Containing Morpholines & Thiomorpholines Morpholines & Thiomorpholines Ring Systems