ChemicalBook > Product Catalog >Organic Chemistry >Heterocyclic Compounds >3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol

3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol

3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol Structure
CAS No.
1266084-47-2
Chemical Name:
3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol
Synonyms
3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol;3,3-Dimethyl-6-Nitrobenzo[C][1,2]Oxaborol-1(3H)-Ol(WXC00403);1,3-dihydro-1-hydroxy-3,3-dimethyl-6-nitro-2,1-Benzoxaborole;2,1-Benzoxaborole, 1,3-dihydro-1-hydroxy-3,3-dimethyl-6-nitro-
CBNumber:
CB32684496
Molecular Formula:
C9H10BNO4
Molecular Weight:
206.99
MOL File:
1266084-47-2.mol
Modify Date:
2023/10/17 10:05:41

3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol Chemical Properties,Uses,Production

Chemical Properties

Yellow solid

Synthesis

At -40°C, to 100% fuming nitric acid (10 mL) was added dropwise a solution of 3,3-dimethylbenzo[c][l,2]oxaborol-l(3H)-ol (XCVI) (1.37 g, 0.0085 mol) in carbon tetrachloride (40 mL), maintaining the temperature below -40°C. After 20 min, the yellow solution was poured into ice and was stirred for 10 min at RT. The mixture was extracted with EtOAc. 1M aqueous NaOH was added to the organic layer to adjust the pH=7. The organic layer was separated, and washed with water, dried over MgS04, and filtered, and the solvent was removed in vacuo to give an orange viscous oil. The oily residue was triturated with hexane to give pure 3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol.3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol

3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol Preparation Products And Raw materials

3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol Suppliers

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Shanghai Boc Chemical Co., Ltd. 021-34975602; +8618721111801 China 138 58 Inquiry
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Aikon International Limited 025-58851090 15955137747 China 15951 58 Inquiry
3,3-diMethyl-6-nitrobenzo[c][1,2]oxaborol-1(3H)-ol 1,3-dihydro-1-hydroxy-3,3-dimethyl-6-nitro-2,1-Benzoxaborole 3,3-Dimethyl-6-Nitrobenzo[C][1,2]Oxaborol-1(3H)-Ol(WXC00403) 2,1-Benzoxaborole, 1,3-dihydro-1-hydroxy-3,3-dimethyl-6-nitro- 1266084-47-2