ChemicalBook > Product Catalog >Organic Chemistry >Amides >Acyclic polyamines and their derivatives >N,N-Diethyl-1,1,1-trimethylsilylamine

N,N-Diethyl-1,1,1-trimethylsilylamine

N,N-Diethyl-1,1,1-trimethylsilylamine Structure
CAS No.
996-50-9
Chemical Name:
N,N-Diethyl-1,1,1-trimethylsilylamine
Synonyms
DK436;TMSDEA;CD4450;(CH3)3SiN(C2H5)2;Trimethylsilyl-diethylamin;TRIMETHYLSILYLDIETHYLAMINE;DIETHYLAMINOTRIMETHYLSILANE;Diethyl(trimethylsilyl)amine;Trimethyl(diethylamino)silane;Diethyl-trimethylsilanyl-amine
CBNumber:
CB3771284
Molecular Formula:
C7H19NSi
Molecular Weight:
145.32
MOL File:
996-50-9.mol
MSDS File:
SDS
Modify Date:
2024/11/8 10:59:09

N,N-Diethyl-1,1,1-trimethylsilylamine Properties

Melting point -10°C
Boiling point 125-126 °C(lit.)
Density 0.767 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
refractive index n20/D 1.411(lit.)
Flash point 50 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Sparingly), DMSO (Slightly), Ethyl Acetate (Slightly)
form clear liquid
pka 11.27±0.70(Predicted)
Specific Gravity 0.763
color Colorless to Light yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 635718
CAS DataBase Reference 996-50-9(CAS DataBase Reference)
NIST Chemistry Reference N,N-Diethyl-1,1,1-trimethylsilylamine(996-50-9)
EPA Substance Registry System Silanamine, N,N-diethyl-1,1,1-trimethyl- (996-50-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H225-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-34
Safety Statements  26-36/37/39-45-24/25-16
RIDADR  UN 2733 3/PG 2
WGK Germany  3
10-21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29310095
NFPA 704
3
3 0

N,N-Diethyl-1,1,1-trimethylsilylamine price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 127256 N,N-Diethyltrimethylsilylamine 97% 996-50-9 25G ₹4081.03 2022-06-14 Buy
Sigma-Aldrich(India) 127256 N,N-Diethyltrimethylsilylamine 97% 996-50-9 100G ₹9341.98 2022-06-14 Buy
ALFA India ALF-A18149-22 N-(Trimethylsilyl)diethylamine, 98% 996-50-9 100g ₹9324 2022-05-26 Buy
ALFA India ALF-A18149-14 N-(Trimethylsilyl)diethylamine, 98% 996-50-9 25g ₹3907 2022-05-26 Buy
TCI Chemicals (India) T0492 N-(Trimethylsilyl)diethylamine min. 98.0 % 996-50-9 25ML ₹3800 2022-05-26 Buy
Product number Packaging Price Buy
127256 25G ₹4081.03 Buy
127256 100G ₹9341.98 Buy
ALF-A18149-22 100g ₹9324 Buy
ALF-A18149-14 25g ₹3907 Buy
T0492 25ML ₹3800 Buy

N,N-Diethyl-1,1,1-trimethylsilylamine Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

Trimethylsilyldiethylamine is a reagent used as an electrophilic trimethylsilyl source for cleavage of cyclic ethers, esters, oxazolidines, and cyclic acetals; also as a nucleophilic source of the diethylamino group, participating in the following synthesis reactions: Trimethylsilyl Group Transfer, Diethylamino Group Transfer, Trimethylsilyldiethylamine as Halosilane Equivalent, Silylation of Alcohols, Mild Generation of Phosphonochloridates, Silylation of Amines, Diethylamino Group Transfer, Conjugate Addition, Aminoalkylation of Aldehydes, Enamine and Silyl Enol Ether Preparation, Mediation of 1,4-Conjugate Additions, etc.

Definition

ChEBI: An N-silyl compound that is diethylamine in which the amino hydrogen is replaced by a trimethylsilyl group. N-(trimethylsilyl)diethylamine is a derivatisation agent used in gas chromatography/mass spectrometry applicat ons.

General Description

N,N-Diethyltrimethylsilylamine is a silylating agent used to derivatize polar organic compounds.

Purification Methods

Fractionate it through a 2ft vacuum-jacketed column containing Helipak packing with a reflux ratio of 10:1. [Sauer & Hasek J Am Chem Soc 68 241 1946, Langer et al. J Org Chem 23 50 1958, Rühlmann J Prakt Chem 9 315 1959, Beilstein 4 IV 4010.]

N,N-Diethyl-1,1,1-trimethylsilylamine Preparation Products And Raw materials

Global( 245)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6768 58 Inquiry
Alfa Aesar 1 800 209 7001 Maharashtra, India 6905 58 Inquiry
Sisco Research Laboratories Pvt. Ltd. +91-22-4268 5800 Mumbai, India 4315 58 Inquiry
Triveni chemicals 08048762458 New Delhi, India 6088 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6257 58 Inquiry
Hebei Weibang Biotechnology Co., Ltd +8615531157085 China 8813 58 Inquiry
Hebei Mojin Biotechnology Co., Ltd +86 13288715578 +8613288715578 China 12840 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 18781 58 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32951 60 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29884 58 Inquiry
Silanamine, N,N-diethyl-1,1,1-trimethyl- Silanamine,N,N-diethyl-1,1,1-trimethyl- Trimethylsilyl-diethylamin (Diethylamino)trimethylsilane, N-(Trimethylsilyl)diethylamine, TMSDEA N,N-DiethylaminotrimethylsilaneTMSDEAN,N-Diethyltrimethylsilylamine Trimethylsilyldiethylamine (TMSDEA) Diethyl(trimethylsilyl)amine N,N-DIETHYLTRIMETHYLSILYLAMINE, DERIVATI ZATION GRADE N,N-DIETHYL-1,1,1-TRIMETHYLSILYLAMINE 98+% TMSDEA N,N-DIETHYL-TRIMETHYLSILYLAMINE TRIMETHYLSILYLDIETHYLAMINE TRIMETHYL-N,N-DIETHYLAMINOSILANE TMSDEA (CH3)3SiN(C2H5)2 CD4450 Diethyl-trimethylsilanyl-amine DIETHYLAMINOTRIMETHYLSILANE N,N-DIETHYLAMINOTRIMETHYLSILANE N,N-DIETHYLTRIMETHYLSILYLAMINE N,N-DIETHYL-1,1,1-TRIMETHYLSILYLAMINE N-(TRIMETHYLSILYL)DIETHYLAMINE N,N-Diethyl(trimethyl)silanamine n,n-diethyl-1,1,1-trimethyl-silanamin N,N-diethyl-1,1,1-trimethyl-Silanamine Trimethyl(diethylamino)silane N,N-Diethyl-1,1,1-triMethylsilylaMine, 98+% 25GR Diethylaminotrimethylsilane TMS-DEA DIETHYLAMINOTRIMETHYLSILANE FOR SYNTHESI N,N-Diethyltrimethylsilylamine ,97% N, N-(triMethylsilyl) diethylaMine N-(Trimethylsilyl)diethylamine N,N-Diethyltrimethylsilylamine 97% Diethylaminotrimethylsilane for synthesis N-(Trimethylsilyl)diethylamine > N,N-Diethyl-1,1,1-trimethylsilylamine ISO 9001:2015 REACH N-(Trimethylsilyl)diethylamine (TMSDEA) extrapure, 97% N-ethyl-N-trimethylsilylethanamine DK436 996-50-9 C2H52NSiCH33 C7H19NSi C7H19NSiC CH33SiNCH2CH32 C7 Amines Building Blocks Nitrogen Compounds Organic Building Blocks Protected Amines Si-N Compounds Silicon Compounds (for Synthesis) Trimethylsilylation (GC Derivatizing Reagents) Silylation (GC Derivatizing Reagents) GC Derivatizing Reagents Aminosilanes Si (Classes of Silicon Compounds) Halogenated Heterocycles Building Blocks