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(S)-(-)-LIMONENE

(S)-(-)-LIMONENE Structure
CAS No.
5989-54-8
Chemical Name:
(S)-(-)-LIMONENE
Synonyms
L-LIMONENE;(-)-Limonene;(S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-1-ene;beta-limonene;(s)-(-)-p-mentha-8-diene;(-)-1,8-p-menthadiene,(S)-(-)-limonene;(S)-(-)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE;1-methyl-4-(1-methylethenyl)-,(S)-Cyclohexene;cyclohexene,1-methyl-4-(1-methylethenyl)-,(S)-;LIMONENER
CBNumber:
CB5178359
Molecular Formula:
C10H16
Molecular Weight:
136.23
MOL File:
5989-54-8.mol
MSDS File:
SDS
Modify Date:
2024/4/26 21:57:37

(S)-(-)-LIMONENE Properties

Melting point -74°C
Boiling point 175-177 °C(lit.)
alpha -99.5 º (C=NEAT)
Density 0.844 g/mL at 25 °C(lit.)
vapor density 4.7 (vs air)
vapor pressure <3 mm Hg ( 14.4 °C)
refractive index n20/D 1.471(lit.)
Flash point 119 °F
storage temp. Sealed in dry,Store in freezer, under -20°C
solubility Chloroform (Sparingly), Ethanol (Slightly), Methanol (Slightly)
form Liquid
color Clear colorless to pale yellow
Odor at 100.00 %. terpene pine herbal peppery
Odor Type terpenic
explosive limit 0.7-6.1%(V)
optical activity [α]20/D 94±4°, c = 10% in ethanol
Water Solubility Insoluble
Merck 14,5493
BRN 2323991
Stability Stable. Incompatible with strong oxidizing agents. Flammable.
LogP 4.38 at 37℃
CAS DataBase Reference 5989-54-8(CAS DataBase Reference)
NIST Chemistry Reference Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (S)-(5989-54-8)
EPA Substance Registry System Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)- (5989-54-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H226-H304-H317-H400
Precautionary statements  P210-P273-P280-P301+P310+P331-P302+P352
Hazard Codes  Xi,N
Risk Statements  10-38-43-50/53
Safety Statements  24-37-60-61
RIDADR  UN 2052 3/PG 3
WGK Germany  2
RTECS  OS8350000
8-10-23
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29029090
NFPA 704
2
2 0

(S)-(-)-LIMONENE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) W504505 (S)-(−)-Limonene ≥95%, FG 5989-54-8 1SAMPLE-K ₹4880.63 2022-06-14 Buy
Sigma-Aldrich(India) W504505 (S)-(−)-Limonene ≥95%, FG 5989-54-8 1KG ₹7120.58 2022-06-14 Buy
Sigma-Aldrich(India) 62128 (S)-(−)-Limonene analytical standard 5989-54-8 1ML ₹4274.4 2022-06-14 Buy
Sigma-Aldrich(India) 62128 (S)-(−)-Limonene analytical standard 5989-54-8 5ML ₹11949.83 2022-06-14 Buy
Sigma-Aldrich(India) 218367 (S)-(−)-Limonene 96% 5989-54-8 50G ₹1993.35 2022-06-14 Buy
Product number Packaging Price Buy
W504505 1SAMPLE-K ₹4880.63 Buy
W504505 1KG ₹7120.58 Buy
62128 1ML ₹4274.4 Buy
62128 5ML ₹11949.83 Buy
218367 50G ₹1993.35 Buy

(S)-(-)-LIMONENE Chemical Properties,Uses,Production

Description

ι-Limonene has a pleasant, lemon-like odor free from camphora ceous and turpentine-like notes. The most important and wide spread terpene; it is known in the d- and ι- optically active forms and in the optically inactive dl-form (known as dipentene); it has been reported found in more than 300 essential oils in amounts ranging from 90 - 95% (lemon, orange, mandarin) to as low as 1% (palmarosa);1 the most widespread form is the d-limonene, followed by the racemic form, and then ι-limonene.

Chemical Properties

colourless liquid with lemon odour

Occurrence

It has been reported found in more than 300 essential oils in amounts ranging from 90 to 95% (lemon, orange, mandarin) to as low as 1% (palmarosa); the most widespread form is the d-limonene, followed by the racemic form and then l-limo nene. Also reported found in ginger, nutmeg, pepper, mace, hop oil, coriander seed, calamus, dill herb, caraway seed and rosemary.

Uses

(S)-(-)-Limonene is used to inhibit the proliferation of colon cancer cells. It is also used in artificial essential oils in order to produce (+)-carvone. It is an active component of turpentine. Further, it is used in flavorings, fragrances, and cosmetics. It finds application as a solvent and wetting agent. In addition to this it is used to produce resins.

Preparation

d-Limonene may be obtained by steam distillation of citrus peels and pulp resulting from the production of juice and cold pressed oils, or from deterpenation of citrus oils; it is sometimes redistilled.

Definition

ChEBI: An optically active form of limonene having (4S)-configuration.

General Description

(S)-(-)-Limonene, a monoterpenoid compound, is mostly used in perfumery and in flavoring. On irradiation, it undergoes radiolysis, which leads to a reduction in the optical purity. (S)-(-)-Limonene also shows potent antimicrobial activity.

Contact allergens

Limonene is a racemic form of dand l-limonene. d-Limonene is contained in Citrus species such as citrus, orange, mandarin, and bergamot. l-Limonene is contained in Pinus pinea.

Safety Profile

A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Global( 248)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
NEERU MENTHOL PRIVATE LIMITED +91-8884114465 +91-8884114465 Uttar Pradesh, India 44 58 Inquiry
Neeru Menthol Pvt Ltd +91-8884114465 +91-9837322285 New Delhi, India 70 58 Inquiry
D D Shah Essential Oil Co +91-2222850577 +91-2222850577 Maharashtra, India 34 58 Inquiry
Sharp Mint Limited +91-1142290700 +91-1142290700 New Delhi, India 9 58 Inquiry
Star Iris Exports Pvt Ltd +91-9837506000 +91-9837506000 Uttar Pradesh, India 18 58 Inquiry
Samde Aromatic Pvt Ltd +91-9351546864 +91-9351546864 Rajasthan, India 21 58 Inquiry
Privi Speciality Chemicals Ltd. +91-2233043500 +91-2233043500 Mumbai, India 63 58 Inquiry
Bhagat Aromatics Ltd +91-1204044300 +91-9321155125 Uttar Pradesh, India 24 58 Inquiry
Jindal Drugs Limilted +91-2243418888 +91-2243418888 Maharashtra, India 11 58 Inquiry
Himachal Terepene Products Pvt Ltd +91-9805022389 +91-9816380001 Himachal Pradesh, India 16 58 Inquiry
(S)-(-)-1-methyl-4-(1-methylethenyl)cyclohexene (s)-(-)-p-mentha-1,8-diene (s)-1-methyl-4-(1-methylethenyl)cyclohexene p-Mentha-1,8-diene, (S)-(-)- p-mentha-1,8-diene,(S)-(-)- (s)-cyclohexen LIMONENE, S-(-)- L-P-MENTHA-1,8-DIENE (-)-CARVENE S-(-)-CARVENE (S)-(-)-LIMONENE (S)-4-ISOPROPENYL-1-METHYL CYCLOHEXENE Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4S)- (4S)-1-methyl-4-prop-1-en-2-yl-cyclohexene LIMONENE, S-(-)-(SG) LIMONENER LIMONEN TECHN. Cyclohexene, 1-methyl-4-(1-methyle LIMONENE P&F FCC (D-) (S)-(-)-LIMONENE 95+% FCC (S)-(-)-4-Isopropenyl-1-methylcyclohexene~(-)-p-Mentha-1,8-diene S-(-)-LIMONENE WITH GC L-LIMONENE, NATURAL (-)-p-Mentha-1,8-diene, (-)-Carvene, (S)-4-Isopropenyl-1-methyl cyclohexene (-)-Dipentene (-)-LiMonene, 92% 100ML (S)-(-)-LIMONENE FOR SYNTHESIS (S)-(-)-LiMonene 96% (S)-(-)-LiMone (4S)-limonene (-)-Limonene,92% (-)-Limonene> (-)-p-Mentha-1,8-diene (S)-p-Mentha-1,8-dien (-)-1,8-p-menthadiene,(S)-(-)-limonene (s)-(-)-p-mentha-8-diene beta-limonene cyclohexene,1-methyl-4-(1-methylethenyl)-,(S)- 1-methyl-4-(1-methylethenyl)-,(S)-Cyclohexene L-LIMONENE (S)-(-)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE (-)-Limonene (S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-1-ene Lemon oil essence 5989-54-8 5898-27-5 5989-48-5 138863 5989548 Organic Building Blocks Monocyclic Monoterpenes Terpenes Alkenes Alphabetic Analytical Chromatography Product Catalog Analytical Standards Asymmetric Synthesis Chiral Building Blocks