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Uranium tetrafluoride

Uranium tetrafluoride Structure
CAS No.
10049-14-6
Chemical Name:
Uranium tetrafluoride
Synonyms
Uranium(IV) fluoride.;Uranium tetrafluoride;Uranium fluoride(UF4);Uran(IV) tetrafluoride
CBNumber:
CB5852233
Molecular Formula:
F4U
Molecular Weight:
314.02
MOL File:
10049-14-6.mol
Modify Date:
2024/7/11 15:00:05

Uranium tetrafluoride Properties

Melting point >1100°
Boiling point 1446.94°C (estimate)
Density 6.700
solubility soluble in concentrated acid solutions, alkaline solutions
form green monoclinic crystals
color green monoclinic crystals, crystalline
Water Solubility insoluble H2O; soluble conc acids, alkalies, but decomposes [MER06]
EPA Substance Registry System Uranium tetrafluoride (10049-14-6)

SAFETY

Risk and Safety Statements

RIDADR  2912
HazardClass  7

Uranium tetrafluoride Chemical Properties,Uses,Production

Description

Uranium tetrafluoride, with the molecular formula of UF4, is a green, nonvolatile, crystalline powder that is insoluble in water. It is highly corrosive and is also a radioactive poison.

Chemical Properties

Green, nonvolatile, crystalline powder. Insoluble in water.

Uses

Intermediate in preparation of uranium metal. See uranium hexafluoride.

Preparation

Dichlorodifluoromethane (Freon 12) is passed through a Hg pressure release valve, a bubble counter and aPsO5 tube into a glass or quartz reaction tube (diameter 2.5 cm, length 40 cm.) The reaction tube is inserted into a short electric furnace which can be heated to a temperature of 400℃. Powdered UO3 is placed in the reaction tube between glass-wool plugs. The escaping gases are led to the hood.
At the beginning, dry oxygen is passed through the apparatus for one hour, while the furnace is heated to 400℃. The oxygen flow is then replaced with CF2Cl2, which is introduced at a rate of one liter per hour. The reaction starts as soon as the temperature reaches 400°C. The progress of the reaction can be followed as the color of the product changes to green.
On completion of the reaction, the product is cooled in a stream of CF2Cl2; very pure UF4 is obtained. The yield is almost quantitative. preparation of Uranium tetrafluoride

Hazard

Highly corrosive, radioactive poison.

Uranium tetrafluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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10049-14-6(Uranium tetrafluoride)Related Search:

Uranium tetrafluoride Uranium(IV) fluoride. Uran(IV) tetrafluoride Uranium fluoride(UF4) 10049-14-6