(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS Structure
CAS No.
486429-99-6
Chemical Name:
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
CBNumber:
CB6139371
Molecular Formula:
C39H32O2P2
Molecular Weight:
594.62
MOL File:
486429-99-6.mol
Modify Date:
2024/6/19 22:55:17

(R)-C3-TUNEPHOS Properties

Melting point 153-161 °C(lit.)
Boiling point 709.9±60.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
Sensitive air sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3

(R)-C3-TUNEPHOS Chemical Properties,Uses,Production

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Reactant for:

  • Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
  • Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates

Precatalyst for:
  • Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate

Catalyst for:
  • Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-C3-TUNEPHOS Suppliers

Global( 27)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
XINXIANG RUNYU MATERIAL CO., LTD. +86-13592593621; +8613592593621 China 428 58 Inquiry
Aladdin Scientific +1-+1(833)-552-7181 United States 57511 58 Inquiry
ABCR GmbH & CO. KG 49 721 95061 0 Germany 6846 75 Inquiry
Aikon International Limited 025-66113011 18112977050 China 16028 58 Inquiry
Bide Pharmatech Ltd. 400-1647117 15221909166 China 41438 60 Inquiry
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 China 29778 58 Inquiry
Sigma-Aldrich 021-61415566 800-8193336 China 51471 80 Inquiry
Henan Weitesi Chemical Technology Co. LTD 0371-0371-55135753 18003832934 China 9993 58 Inquiry
Bide Pharmatech Ltd. 400-6005915 China 39661 58 Inquiry
Beijing Solarbio Science & Tecnology Co., Ltd. 010-50973130 17801761073 China 50751 58 Inquiry
(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (S)-C3-TUNEPHOS (R)-C3-TUNEPHOS (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,95%(S)-C3-TUNEPHOS (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- 1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine 1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine 486429-99-6 C39H32O2P2 Privileged Ligands ChiralQuest Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand