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ChemicalBook > Product Catalog >Organic Chemistry >Organosilicon compounds >(S)-2-(tert-Butyldimethylsilyloxy)propanal

(S)-2-(tert-Butyldimethylsilyloxy)propanal

(S)-2-(tert-Butyldimethylsilyloxy)propanal Structure
CAS No.
87727-28-4
Chemical Name:
(S)-2-(tert-Butyldimethylsilyloxy)propanal
Synonyms
(S)-2-(tert-Butyldimethylsilyloxy)propanal;(S)-2-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-PRO;(S)-2-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-PROPIONALDEHYDE;Propanal, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (2S)-
CBNumber:
CB72461075
Molecular Formula:
C9H20O2Si
Molecular Weight:
188.34
MOL File:
87727-28-4.mol
Modify Date:
2023/11/1 11:43:43
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(S)-2-(tert-Butyldimethylsilyloxy)propanal Properties

Boiling point 67-68 °C(Press: 14 Torr)
Density 0.868±0.06 g/cm3(Predicted)
InChI InChI=1S/C9H20O2Si/c1-8(7-10)11-12(5,6)9(2,3)4/h7-8H,1-6H3/t8-/m0/s1
InChIKey YMIIHJBTQLZXBV-QMMMGPOBSA-N
SMILES C(=O)[C@@H](O[Si](C(C)(C)C)(C)C)C

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H319-H335-H226-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362

(S)-2-(tert-Butyldimethylsilyloxy)propanal Chemical Properties,Uses,Production

storage

Inert atmosphere,Store in freezer, under -20C

Synthesis

Ethyl ester 3 (4.00 g, 17.2 mmol) was added to diethyl ether (70 mL) and cooled to -78 °C. DIBAL-H (1M in hexane, 20 mmol, 20 mL) was added cautiously dropwise over 1 h. The solution was stirred for a further 4 h at -78 °C before being quenched with MeOH (40 mL) and warmed to room temperature. Saturated potassium sodium tartrate solution (60 mL) was added and the mixture was left to stir for 12 h before being extracted with diethyl ether (3 x 15 mL). The organic extracts were dried with MgSO4, filtered, and concentrated under reduced pressure to give the crude (S)-2-(tert-Butyldimethylsilyloxy)propanal (3.22 g, 99%) as a clear oil.
(S)-2-(tert-Butyldimethylsilyloxy)propanal

(S)-2-(tert-Butyldimethylsilyloxy)propanal Preparation Products And Raw materials

Raw materials

(S)-2-((tert-butyldimethylsilyl)oxy)propan-1-ol

Preparation Products

(S)-2-(tert-Butyldimethylsilyloxy)propanal Suppliers

Global( 26)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Huida Pharmaceutical Technology (Shanghai) Co., Ltd. +8613601750004 China 439 58 Inquiry
Shenzhen Nexconn Pharmatechs Ltd +86-755-89396905 +86-15013857715 China 10312 58 Inquiry
Jinan Carbotang Biotech Co.,Ltd. +8615866703830 China 7621 58 Inquiry
Shanxi Tihondan Pharmaceutical Technology Co., Ltd +8618235132063 China 3725 58 Inquiry
Bide Pharmatech Ltd. 400-1647117 15221909166 China 63720 58 Inquiry
Yantai Sheng Kai Lun Biological Products Co. , Ltd. 3119594100 China 7779 58 Inquiry
Shanghai Haohong Pharmaceutical Co., Ltd. 400-8210725 4008210725 China 40035 58 Inquiry
Shanghai Fengji Pharmaceutical Technology Co., Ltd 15555063509 China 2728 58 Inquiry
SuZhou Medinoah Co.,LTD. 0512-0512-69561983 13914027025 China 3475 58 Inquiry
Huida Medical Technology (Shanghai) Co., LTD 13601750004 China 565 58 Inquiry
Supplier Advantage
Huida Pharmaceutical Technology (Shanghai) Co., Ltd. 58
Shenzhen Nexconn Pharmatechs Ltd 58
Jinan Carbotang Biotech Co.,Ltd. 58
Shanxi Tihondan Pharmaceutical Technology Co., Ltd 58
Bide Pharmatech Ltd. 58
Yantai Sheng Kai Lun Biological Products Co. , Ltd. 58
Shanghai Haohong Pharmaceutical Co., Ltd. 58
Shanghai Fengji Pharmaceutical Technology Co., Ltd 58
SuZhou Medinoah Co.,LTD. 58
Huida Medical Technology (Shanghai) Co., LTD 58
(S)-2-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-PROPIONALDEHYDE Propanal, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, (2S)- (S)-2-(TERT-BUTYL-DIMETHYL-SILANYLOXY)-PRO (S)-2-(tert-Butyldimethylsilyloxy)propanal 87727-28-4