TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- CAS No.
- 370-69-4
- Chemical Name:
- TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE
- Synonyms
- TTFP;Phosphite, tris(2,2,2-trifluoroethyl);Tris(2,2,2-trifluoroethyl) phosphite 99%;TTEP;TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE;Ethanol, 2,2,2-trifluoro-, phosphite (3:1);TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE, 99 %
- CBNumber:
- CB7449383
- Molecular Formula:
- C6H6F9O3P
- Molecular Weight:
- 328.07
- MOL File:
- 370-69-4.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/5/21 21:50:59
| Boiling point | 130-131 °C743 mm Hg(lit.) |
|---|---|
| Density | 1.487 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| BRN | 1714041 |
| InChI | InChI=1S/C6H6F9O3P/c7-4(8,9)1-16-19(17-2-5(10,11)12)18-3-6(13,14)15/h1-3H2 |
| InChIKey | CBIQXUBDNNXYJM-UHFFFAOYSA-N |
| SMILES | P(OCC(F)(F)F)(OCC(F)(F)F)OCC(F)(F)F |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| F | 10-21 |
| HS Code | 2920290090 |
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE price More Price(2)
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Chemical Properties,Uses,Production
Uses
Tris(2,2,2-trifluoroethyl) phosphite was used in the synthesis of N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide via the Arbuzov reaction with 2-bromo-N-methoxy-N-methylacetamide.
Purification Methods
Fractionate it through a 10inch Helipak column [Krogh et al. J Org Chem 19 1124 1954]. Tris-[(3-trifluoromethylhydroxymethylene)-d-camphorato] europium (III) [Eu(tfc)3] [34830-11-0] M 893.6, m 195-299o (dec), ~220o, [ ] D +152o (c 2, CCl4, and varies markedly with concentration). Purify it by extraction with pentane, filter and the filtrate is evaporated and the residual bright yellow amorphous powder is dried at 100o/0.1mm for 36hours. A sample purified by fractional molecular distillation at 180-200o/0.004mm gave a liquid which solidified and softened at ~130o, and melted at ~180o and was analytically pure. IR (CCl4) 1630-1680cm-1 and NMR (CCl4) broad: -1.3 to 0.5, -0.08 (s), 0.41 max (s), 1.6-2.3 and 3.39 (s). [McCreary et al. J Am Chem Soc 96 1038 1974, Goering et al. J Am Chem Soc 93 5913 1971.]
TRIS(2,2,2-TRIFLUOROETHYL) PHOSPHITE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Hubei Yiling biotechnology Co Ltd | +86-18163349544 +86-18163349544 | China | 480 | 58 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 18628 | 58 | Inquiry |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | China | 21665 | 55 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29888 | 58 | Inquiry |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | China | 39916 | 58 | Inquiry |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | China | 49392 | 58 | Inquiry |
| Shaanxi Dideu Medichem Co. Ltd | 18192627656 | China | 3002 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | China | 13182 | 58 | Inquiry |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 50003 | 58 | Inquiry |