7-hydroxynaphthalene-2-sulphonic acid

7-hydroxynaphthalene-2-sulphonic acid Structure
CAS No.
92-40-0
Chemical Name:
7-hydroxynaphthalene-2-sulphonic acid
Synonyms
2-Naphthol-7-sulfonic acid;2-Hydroxynaphthlene-7-sulfonic acid;2-Hydroxynaphthalene-7-sulfonicacid;7-Hydroxynaphthalene-2-sulfonic acid;2-Hydroxy-7-naphthalenesulfonic acid;7-hydroxynaphthalene-2-sulphonic acid;2-Naphthalenesulfonic acid, 7-hydroxy-;(4Z)-4-(phenylmethylene)oxolane-2,3-dione
CBNumber:
CB7939158
Molecular Formula:
C10H8O4S
Molecular Weight:
224.23
MOL File:
92-40-0.mol
Modify Date:
2023/11/1 14:34:00

7-hydroxynaphthalene-2-sulphonic acid Properties

Density 1.549±0.06 g/cm3(Predicted)
pka 0.21±0.40(Predicted)
EPA Substance Registry System 2-Naphthalenesulfonic acid, 7-hydroxy- (92-40-0)

SAFETY

Risk and Safety Statements

RIDADR  1759
HazardClass  8
PackingGroup  III

7-hydroxynaphthalene-2-sulphonic acid Chemical Properties,Uses,Production

Chemical Properties

2-Hydroxynaphthalene-7-sulfonic acid [92- 40-0]. (7-hydroxynaphthalene-2-sulfonic acid), F acid, Cassella acid, C10H8O4S, Mr 224.23, is soluble in water, from which it can be recrystallized as the monohydrate (mp 89℃). The sodium and potassium salts are also readily soluble, but the barium salt is sparingly soluble. Iron(III) chloride gives a dark blue color with neutral solutions of 2-Hydroxynaphthalene-7-sulfonic acid. Azo coupling and nitrosation occurs in the 1-position. Sulfonation gives a variety of products depending on the conditions.

Uses

2-Hydroxynaphthalene-7-sulfonic acid is used as an intermediate in the production of 2-aminonaphthalene-7-sulfonic acid, 2-hydroxynaphthalene-3,7-disulfonic acid, and 2,7-dihydroxynaphthalene. It has minor uses as an azo coupling component.

Preparation

Naphthalene-2,7-disulfonic acid is heated with aqueous sodium hydroxide under pressure at 230℃ for 5 h and then at 260℃ for another 5 h. After neutralizing and screening, the liquor is acidified to precipitate the product, which is isolated after boiling off the sulfur dioxide and cooling to 30℃.

7-hydroxynaphthalene-2-sulphonic acid Preparation Products And Raw materials

7-hydroxynaphthalene-2-sulphonic acid Suppliers

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7-hydroxynaphthalene-2-sulphonic acid 2-Naphthol-7-sulfonic acid 2-Hydroxynaphthalene-7-sulfonicacid 2-Hydroxy-7-naphthalenesulfonic acid 7-Hydroxynaphthalene-2-sulfonic acid 2-Naphthalenesulfonic acid, 7-hydroxy- (4Z)-4-(phenylmethylene)oxolane-2,3-dione 2-Hydroxynaphthlene-7-sulfonic acid 92-40-0