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(+)-ISOPINOCAMPHEOL

(+)-ISOPINOCAMPHEOL Structure
CAS No.
27779-29-9
Chemical Name:
(+)-ISOPINOCAMPHEOL
Synonyms
Nsc167499;3-PINANOL;(+)-ISOPINOCAMPHEOL;(+)-Isopinocampheol;ISOPINOCAMPHEOL, (+)-;3-Pinanol, stereoisomer;ISOPINOCAMPHEOL, (-)-(SG);(1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%;(1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol;(1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
CBNumber:
CB8441753
Molecular Formula:
C10H18O
Molecular Weight:
154.25
MOL File:
27779-29-9.mol
Modify Date:
2023/5/25 18:01:20

(+)-ISOPINOCAMPHEOL Properties

Melting point 52-55 °C
Boiling point 219 °C(lit.)
Density 0.8389 (rough estimate)
refractive index 1.4710 (estimate)
Flash point 93 °C
pka 15.35±0.60(Predicted)
LogP 2.805 (est)

SAFETY

Risk and Safety Statements

WGK Germany  3

(+)-ISOPINOCAMPHEOL Chemical Properties,Uses,Production

Uses

(1S,2S,3S,5R)-(+)-Isopinocampheol may be used in the preparation of

  • thermotropic chiral nematic side-chain copolymers
  • ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
  • O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect

General Description

(1S,2S,3S,5R)-(+)-Isopinocampheol is a chiral terpenol.

Purification Methods

Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.]

(+)-ISOPINOCAMPHEOL Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-ISOPINOCAMPHEOL Suppliers

Global( 32)Suppliers
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SIMAGCHEM CORP +86-13806087780 China 17367 58 Inquiry
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Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076 China 9977 58 Inquiry
ISOPINOCAMPHEOL, (+)- (1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol ISOPINOCAMPHEOL, (-)-(SG) (1S,2S,3S,5R)-3-Pinanol, 3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol (1S,2S,3S,5R)-3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1.alpha.,2.beta.,3.alpha.,5.alpha.)- Nsc167499 (1S,2S,3S,5R)-(+)-IsopinocaMpheol 98% 3-PINANOL 3-Pinanol, stereoisomer (+)-ISOPINOCAMPHEOL (1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1R,2R,3R,5S)-rel- (+)-Isopinocampheol 27779-29-9 Alcohols Organic Building Blocks Asymmetric Synthesis Chiral Building Blocks