3,6-Dichloro-1,2-benzenedithiol
- CAS No.
- 87314-49-6
- Chemical Name:
- 3,6-Dichloro-1,2-benzenedithiol
- Synonyms
- 3,6-Dichloro-1,2-benzenedithiol;3,6-DICHLORO-BENZENE-1,2-DITHIOL;1,2-Benzenedithiol, 3,6-dichloro-;3 6-DICHLORO-1 2-BENZENEDITHIOL 95;3 6-DICHLORO-1 2-BENZENEDITHIOL 95%
- CBNumber:
- CB8499325
- Molecular Formula:
- C6H4Cl2S2
- Molecular Weight:
- 211.13
- MOL File:
- 87314-49-6.mol
- Modify Date:
- 2024/2/13 10:22:13
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H301-H312-H315-H319-H330-H335-H361-H373-H411 |
| Precautionary statements | P202-P273-P280-P302+P352+P312-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| RIDADR | UN 3335 |
| WGK Germany | 3 |
3,6-Dichloro-1,2-benzenedithiol Chemical Properties,Uses,Production
Uses
3,6-Dichloro-1,2-benzenedithiol is a stain/dye. Dyes and metabolites.
Application
3,6-Dichloro-1,2-benzenedithiol has been used as a ligand in thiolate complexes and a series of homo-chalcogenide and mixed-chalcogenide ligand complexes. For example, Direct reaction between Cu(ClO4)2 and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in the presence of basic salts leads to a series of bis(dithiolato)cuprate(III) [Cu(SC6H2Cl2S)2]? coordination complexes and coordination polymers. In addition, One-pot reactions between Ni(II), Pd(II), or Pt(II) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymer[1-2].
References
[1] Amo-Ochoa, Pilar et al. “Copper dithiolene [Cu(SC6H2Cl2S)2]? units connected to alkaline/copper complexes: from ionic assemblies to discrete molecular entities and coordination polymers?.” CrystEngComm 6 (2018): 957–963.
[2] Delgado, Esther et al. “Unprecedented layered coordination polymers of dithiolene group 10 metals: magnetic and electrical properties?.” Dalton Transactions 15 (2016): 6696–6701.
3,6-Dichloro-1,2-benzenedithiol Preparation Products And Raw materials
Raw materials
Preparation Products
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