ChemicalBook > Product Catalog >Organic Chemistry >Alcohols,Phenols,Phenol alcohols >cyclopropanol

cyclopropanol

cyclopropanol Structure
CAS No.
16545-68-9
Chemical Name:
cyclopropanol
Synonyms
cyclopropyl alcohol;opropanoL;cyclopropanol;2-Cyclopropanol;Cyclopropane-1-ol;(1α)-Cyclopropanol;Hydroxycyclopropane;16545-68-9, CFCD16545689;Cyclopropanol (7CI, 8CI, 9CI, ACI);1H-Benzimidazole-1-carboxylicacid,2,3-dihydro-3-oxo-,ethylester
CBNumber:
CB91318019
Molecular Formula:
C3H6O
Molecular Weight:
58.08
MOL File:
16545-68-9.mol
Modify Date:
2024/1/8 11:28:09

cyclopropanol Properties

Melting point 180℃
Boiling point 101-102℃ (760 Torr)
Density 9.9110 g/cm3
refractive index 1.4129 (589.3 nm 20℃)
storage temp. 2-8°C
pka 15.31±0.20(Predicted)
InChI InChI=1S/C3H6O/c4-3-1-2-3/h3-4H,1-2H2
InChIKey YOXHCYXIAVIFCZ-UHFFFAOYSA-N
SMILES C1(O)CC1

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS06
Signal word  Danger
Hazard statements  H318-H301
Precautionary statements  P280-P305+P351+P338-P310-P264-P270-P301+P310-P321-P330-P405-P501
RIDADR  UN1993

cyclopropanol Chemical Properties,Uses,Production

Description

Cyclopropanols can be readily synthesized via synthetic transformations such as the Kulinkovich cyclopropanation and the Simmons-Smith reaction [1]. Due to the high strains built intrinsically in the three-membered ring, cyclopropanols and their derivatives are highly reactive and can undergo various ring opening/expansion/fragmentation reactions. A significant amount of these ring opening/expansion/fragmentation reactions are catalyzed/promoted by transition metal complexes. In many of these cases, cyclopropanols and their derivatives are considered as the equivalents of homoenolates or β-alkyl radicals.

Uses

Cyclopropanol is a basic building block.

References

[1] Xinpei Cai, Mingji Dai, Weida Liang. “Total syntheses via cyclopropanols.” Tetrahedron 75 2 (2019): Pages 193-208.

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cyclopropanol Spectrum

16545-68-9(cyclopropanol)Related Search:

cyclopropanol (1α)-Cyclopropanol Cyclopropane-1-ol 2-Cyclopropanol Hydroxycyclopropane 16545-68-9, CFCD16545689 opropanoL cyclopropyl alcohol 1H-Benzimidazole-1-carboxylicacid,2,3-dihydro-3-oxo-,ethylester Cyclopropanol (7CI, 8CI, 9CI, ACI) 16545-68-9