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1,3,5-Triazine

1,3,5-Triazine Structure
CAS No.
290-87-9
Chemical Name:
1,3,5-Triazine
Synonyms
TRIAZINE;S-TRIAZINE;Triazin(sym.);Cyanidine;sym-Triazine;1,3,5-Triazin;s-Triazin;vedita250;Vedita 250;MelaminePure
CBNumber:
CB9203224
Molecular Formula:
C3H3N3
Molecular Weight:
81.08
MOL File:
290-87-9.mol
MSDS File:
SDS
Modify Date:
2024/4/23 16:18:34

1,3,5-Triazine Properties

Melting point 77-83 °C (dec.)(lit.)
Boiling point 114°C
Density 1,38 g/cm3
refractive index 1.5060 (estimate)
Flash point 114°C
storage temp. Inert atmosphere,Room Temperature
solubility methanol: 0.1 g/mL, clear
form powder to crystal
pka 2.07±0.10(Predicted)
color White to Orange to Green
Sensitive Moisture Sensitive
Merck 14,9602
BRN 104790
CAS DataBase Reference 290-87-9(CAS DataBase Reference)
NIST Chemistry Reference 1,3,5-Triazine(290-87-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335
Precautionary statements  P280-P301+P312+P330-P302+P352-P305+P351+P338+P310
Hazard Codes  Xn,C
Risk Statements  22-37/38-41-34
Safety Statements  22-24/25-39-26-45-36/37/39-27
RIDADR  UN2928
WGK Germany  3
RTECS  XY2957000
HazardClass  6.1
PackingGroup  II
HS Code  29339900
NFPA 704
1
2 0

1,3,5-Triazine price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) T46051 s-Triazine 97% 290-87-9 1G ₹1980.98 2022-06-14 Buy
Sigma-Aldrich(India) T46051 s-Triazine 97% 290-87-9 5G ₹6765.63 2022-06-14 Buy
TCI Chemicals (India) T0339 1,3,5-Triazine min. 98.0 % 290-87-9 1G ₹2300 2022-05-26 Buy
TCI Chemicals (India) T0339 1,3,5-Triazine min. 98.0 % 290-87-9 5G ₹7500 2022-05-26 Buy
TCI Chemicals (India) T0339 1,3,5-Triazine min. 98.0 % 290-87-9 25G ₹31900 2022-05-26 Buy
Product number Packaging Price Buy
T46051 1G ₹1980.98 Buy
T46051 5G ₹6765.63 Buy
T0339 1G ₹2300 Buy
T0339 5G ₹7500 Buy
T0339 25G ₹31900 Buy

1,3,5-Triazine Chemical Properties,Uses,Production

Chemical Properties

White crystal

Application

1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.

Uses

1,3,5-Triazine is a reagent in oxidation reactions, in synthesis of heterocycles. Triazine derivatives are used as herbicides, pharmaceuticals, complexation agents, peptidomimetic building blocks, and dyes.

Definition

1,3,5-Triazine, also known as s-triazine, is a six-membered ring organic compound, which is one of the isomers of triazine.

Preparation

Symmetrical 1,3,5-triazines are prepared by trimerization of certain nitriles such as cyanogen chloride or cyanimide. Benzoguanamine (with one phenyl and 2 amino substituents) is synthesised from benzonitrile and dicyandiamide. In the Pinner triazine synthesis (named after Adolf Pinner) the reactants are an alkyl or aryl amidine and phosgene. Insertion of an N-H moiety into a hydrazide by a copper carbenoid, followed by treatment with ammonium chloride also gives the triazine core.
Amine-substituted triazines called Guanamines are prepared by the condensation of cyanoguanidine with the corresponding nitrile:
(H2N)2C=NCN + RCN → (CNH2)2(CR)N3

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