2-Chlorobenzaldehyde
- CAS No.
- 89-98-5
- Chemical Name:
- 2-Chlorobenzaldehyde
- Synonyms
- ORTHO CHLORO BENZALDEHYDE;OCBA;O-CHLOROBENZALDEHYDE;OCAD;2-Clorobenzaldeide;usafm-7;USAF m-7;NSC 15347;AKOS BBS-00003191;2-Chlorbenzaldehyd
- CBNumber:
- CB9469909
- Molecular Formula:
- C7H5ClO
- Molecular Weight:
- 140.57
- MOL File:
- 89-98-5.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/8/21 22:41:43
Melting point | 9-11 °C (lit.) |
---|---|
Boiling point | 209-215 °C (lit.) |
Density | 1.248 g/mL at 25 °C (lit.) |
vapor density | 4.84 (vs air) |
vapor pressure | 1.27 mm Hg ( 50 °C) |
refractive index |
n |
Flash point | 190 °F |
storage temp. | Store in RT |
solubility | 1.8g/l |
form | Liquid |
color | Clear colorless to light yellow |
PH | 2.9 (H2O)(saturated aqueous solution) |
Water Solubility | 0.1-0.5 g/100 mL at 24 ºC |
Sensitive | Air Sensitive |
BRN | 385877 |
Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases, iron, strong reducing agents. Moisture and light-sensitive. |
LogP | 2.44 at 25℃ |
CAS DataBase Reference | 89-98-5(CAS DataBase Reference) |
NIST Chemistry Reference | Benzaldehyde, 2-chloro-(89-98-5) |
EPA Substance Registry System | 2-Chlorobenzaldehyde (89-98-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C,Xi | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 26-45 | |||||||||
RIDADR | UN 3265 8/PG 3 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | CU5075000 | |||||||||
F | 8-9-23 | |||||||||
Autoignition Temperature | 746 °F | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29130000 | |||||||||
Toxicity | LD50 orally in Rabbit: 2160 mg/kg | |||||||||
NFPA 704 |
|
2-Chlorobenzaldehyde price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 8.20276 | 2-Chlorobenzaldehyde for synthesis | 89-98-5 | 250ML | ₹3989.99 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 8.20276 | 2-Chlorobenzaldehyde for synthesis | 89-98-5 | 1L | ₹7460 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 124974 | 2-Chlorobenzaldehyde 99% | 89-98-5 | 100G | ₹1948.5 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 124974 | 2-Chlorobenzaldehyde 99% | 89-98-5 | 500G | ₹2284.08 | 2022-06-14 | Buy |
TCI Chemicals (India) | C0561 | 2-Chlorobenzaldehyde min. 99.0 % | 89-98-5 | 25G | ₹1500 | 2022-05-26 | Buy |
2-Chlorobenzaldehyde Chemical Properties,Uses,Production
Chemical Properties
2-Chlorobenzaldehyde is a colorless to yellowish liquid with a penetrating odor. Insoluble in water, soluble in benzene, alcohol and ether. 2-Chlorobenzaldehyde is considerably more resistant to oxidation than benzaldehyde. When it is heated with sodium sulfite solution under pressure, benzaldehyde-2-sulfonic acid forms.
Uses
2-Chlorobenzaldehyde can be used to make alcohols, acids, and dyes; used in the rubber, tanning, and paper industries; used as an intermediate for optical brighteners, agricultural chemicals, and pharmaceuticals.It can also be used to prepare triphenyl methane and related dyes, organic intermediate.
Preparation
2-Chlorobenzaldehyde is produced mainly by chlorination of 2-chlorotoluene to form 2-chlorobenzal chloride, which is then subjected to acid hydrolysis. Metal salts, such as iron(III) chloride, are used as catalysts. The hydrolysis can also be accomplished using formic acid without a catalyst.
2-Chlorobenzaldehyde can also be produced by oxidation of 2-chlorobenzyl chloride with N-oxides of tertiary amines or with dilute nitric acid.
https://pubchem.ncbi.nlm.nih.gov/compound/2-Chlorobenzaldehyde
Application
2-Chlorobenzaldehyde is used acid zinc plating brightener, also be used for organic synthesis, agricultural pesticide and pharmaceutical industries. It is used to synthesize the acaricides clofentezine and flutenzine. 2-Chlorobenzaldehyde undergoes alkynylation with phenylacetylene in the presence of catalytic ligands and dimethylzinc at 0°C to form binaphthyl-derived amino alcohols.
General Description
2-chlorobenzaldehyde is a clear colorless to yellowish liquid. (NTP, 1992)
Air & Water Reactions
2-Chlorobenzaldehyde is moisture and light sensitive. Slightly water soluble.
Reactivity Profile
2-Chlorobenzaldehyde reacts with iron and strong oxidizers, strong bases and strong reducing agents.
Health Hazard
Symptoms of exposure to 2-Chlorobenzaldehyde may include skin, eye and upper respiratory tract irritation. This compound may cause skin, eye and respiratory tract irritation. When heated to decomposition it emits toxic fumes.
Fire Hazard
2-Chlorobenzaldehyde is combustible.
Safety Profile
Poison by intraperitoneal and intravenous routes. When heated to decomposition it emits toxic fumes of Cl-. See also ALDEHYDES and CHLORIDES.
Purification Methods
Wash it with 10% Na2CO3 solution, then fractionally distil it in the presence of a small amount of catechol as stabiliser. [Beilstein 7 H 233, 7 IV 561.]
2-Chlorobenzaldehyde Preparation Products And Raw materials
Raw materials
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Supplier | Advantage |
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sheetalchemicals | 58 |
ANJI BIOSCIENCES | 58 |
JIVICHEM SYNTHESIS PVT LTD | 58 |
JSK Chemicals | 58 |
LANXESS India Pvt. Ltd. | 58 |
Shimmer Chemicals Pvt Ltd | 58 |
S D Fine Chem Limited | 58 |
Scientific OEM | 38 |
Anand Agencies | 58 |
Emco Dyestuff Pvt. Ltd. | 54 |
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