ステモニジン

ステモニジン 化学構造式
85700-47-6
CAS番号.
85700-47-6
化学名:
ステモニジン
别名:
(2R,3'S,4S,8'S,9'aR)-8'-メトキシ-4-メチル-3'-[(2S,4S)-4-メチル-5-オキソオキソラン-2-イル]-オクタヒドロスピロ[オキソラン-2,9'-ピロロ[1,2-a]アゼピン]-5-オン;ステモニジン;(2R,3′S,4S,8′S,9′aR)-デカヒドロ-8′-メトキシ-4-メチル-3′-[(2S,4S)-4-メチル-5-オキソテトラヒドロフラン-2-イル]スピロ[フラン-2(5H),9′-[9H]ピロロ[1,2-a]アゼピン]-5-オン
英語名:
STEMONIDINE
英語别名:
STEMONIDINE;Spiro[furan-2(5H),9'-[9H]pyrrolo[1,2-a]azepin]-5-one, decahydro-8'-methoxy-4-methyl-3'-[(2S,4S)-tetrahydro-4-methyl-5-oxo-2-furanyl]-, (2R,3'S,4R,5R,8'R,9'aS)-
CBNumber:
CB1414796
化学式:
C19H29NO5
分子量:
351.44
MOL File:
Mol file

ステモニジン 物理性質

融点 :
116°C
CAS データベース:
85700-47-6

安全性情報

ステモニジン 価格

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入

ステモニジン 化学特性,用途語,生産方法

説明

This alkaloid occurs in the roots of Stemona japonica and behaves as a tertiary base. It has [α]25D - 7.65°C and is characterized as the hydrochloride which decomposes at 2600 C and the methiodide, decomposing at 2480 C. The alkaloid is not affected by HCI in either AcOH or EtOH and the oxidation products formed with KMn04 depend upon the conditions. If the oxidation is carried out in Me2CO a base is obtained which yields a crystalline methiodide, m.p. 235°C. On the other hand, KMn04 in dilute H2 S04 at lOoC yields two substances (a) a neutral compound, C16H230sN, m.p. 208°C; [α]D - 58.30 which contains a lactone ring and one methoxyl group and (b) a substance CllH170 4N, m.p. 202°C; [α]D - 24.17° which yields a semicarbazone, m.p. 258°C but contains no lactone group.
There is still ~ome doubt concerning the plant identity from which this alka_x0002_loid was isolated. Investigation by Suzuki suggested that it is not Stemona japonica as stated above but Stemona ovata Nakai.

参考文献

Suzuki.,J. Pharm. Soc., Japan, No. 352, 567 (1921)
Suzuki., ibid, 49, 78,457 (1929)
Suzuki., ibid, 51,43 (1931)
Suzuki., ibid, 54, 101 (1934)
Suzuki., ibid, 59, 184(1939)

ステモニジン 上流と下流の製品情報

原材料

準備製品


ステモニジン 生産企業

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85700-47-6(ステモニジン)キーワード:


  • 85700-47-6
  • STEMONIDINE
  • Spiro[furan-2(5H),9'-[9H]pyrrolo[1,2-a]azepin]-5-one, decahydro-8'-methoxy-4-methyl-3'-[(2S,4S)-tetrahydro-4-methyl-5-oxo-2-furanyl]-, (2R,3'S,4R,5R,8'R,9'aS)-
  • (2R,3'S,4S,8'S,9'aR)-8'-メトキシ-4-メチル-3'-[(2S,4S)-4-メチル-5-オキソオキソラン-2-イル]-オクタヒドロスピロ[オキソラン-2,9'-ピロロ[1,2-a]アゼピン]-5-オン
  • ステモニジン
  • (2R,3′S,4S,8′S,9′aR)-デカヒドロ-8′-メトキシ-4-メチル-3′-[(2S,4S)-4-メチル-5-オキソテトラヒドロフラン-2-イル]スピロ[フラン-2(5H),9′-[9H]ピロロ[1,2-a]アゼピン]-5-オン
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