Berkessel ligand 98% 化学特性,用途語,生産方法
使用
Developed by Albrecht Berkessel′s lab, this is the first catalyst system that allows catalytic enantioselective epoxidation of non-conjugated terminal double bonds with hydrogen peroxide as the oxidant. Eradicating multiple steps and kinetic resolution, this chiral ligand, when used with Ti(OiPr)
4 provides a one-step route to enantiopure epoxides that are important intermediates for synthesis of bioactive compounds. Catalyst is recyclable under some conditions. For best results, pentafluorobenzoic acid (
P5360) or tetra-
n-butylammonium hydrogensulfate (
155837) is recommended as a co-catalyst.
Berkessel ligand 98% 上流と下流の製品情報
原材料
準備製品