フッ化スズ(Ⅱ) 化学特性,用途語,生産方法
外観
白色~ほとんど白色, 粉末
溶解性
水に可溶 (42g/100g水), エタノールに溶けにくい。
解説
SnF2(156.71).酸化スズ(Ⅱ)をフッ化水素酸に溶解し,窒素気流中で濃縮冷却すると得られる.フッ化スズ(Ⅱ)は,無色の単斜晶系結晶.融点213 ℃.空気中で加熱するとSnOF2になる.すず(II)ジフルオリド, 水に易溶,エタノールに不溶.歯のカルシウム分が溶け出すのを予防するのに有用で,練り歯磨きに用いられる.[CAS 7783-47-3]
森北出版「化学辞典(第2版)
用途
歯磨き粉添加剤に用いられる。(本品は試薬につき、人体塗布・投与目的の使用はできません)
効能
齲蝕予防薬
化学的特性
white crystals or powder
使用
Tin(II) fluoride is used in the prevention of dental caries. It is an active ingredient in toothpastes.
一般的な説明
White crystalline solid. Sinks and mixes with water.
空気と水の反応
Water soluble.
反応プロフィール
Tin(II) fluoride, a strong reducing agent, is incompatible with oxidizers. Avoid contact with acids - HF fumes may be produced [USCG, 1999].
危険性
Toxic by ingestion, strong irritant to skin
and tissue.
健康ハザード
EYES: Severe irritation - corrosive, irreversible. SKIN: Corrosive on abraded skin, no effect on intact skin.
安全性プロファイル
Poison by ingestion and
intraperitoneal routes. Questionable
carcinogen. Mutation data reported. When
heated to decomposition it emits toxic
fumes of F-. See also TIN COMPOUNDS.
職業ばく露
Stannous fluoride is used in dental caries (tooth decay); as an ingredient of cavity-preventing toothpastes.
輸送方法
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2923 Corrosive solids, toxic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 6.1Poisonous material, Technical Name Required
不和合性
A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Reacts with acids, forming hydrogen fluoride fumes. Reacts violently with chlorine and metal nitrates. Reacts with metals releasing flammable hydrogen gas.
参考文献
G. Will, M.O. Bargouth, Z. Krystallogr., 153, 89 (1980), DOI: 10.1524/zkri.1980.153.14.89.
フッ化スズ(Ⅱ) 上流と下流の製品情報
原材料
準備製品