ロジアシン

ロジアシン 価格

メーカー	製品番号	製品説明	CAS番号	包装	価格	更新時間	購入

ロジアシン 化学特性,用途語,生産方法

説明

This bisbenzylisoquinoline alkaloid from Ocotea rodiaei was originally considered to have the formulae C36H4006N2 or C36H4406N2. When crystallized from EtOH it yields cubic crystals but from MeOH it forms slender needles. It has [α]¹⁸_D + 134° (c 0.63, CHCI3) or + 157° (c 1.0, CHCI3). The ultraviolet spectrum in EtOH has absorption maxima at 233 and 285 ITlJ.1 with a shoulder at 292 mJ.1. The monohydrochloride forms cubic crystals from EtOH, m.p. 255-9°C (dec.); [α]_D + 74° (c 1.0, H20); the dimethiodide, m.p. 321°C (dec.); [α]²⁰_D+ 68° (c 0.147, H20); the dimethochloride, m.p. 286°C (dec.); [α]_D + 81.5° (c 0.98, H20) and the dimethopicrate, existing in two crystal forms, m.p. 180°C and 253°C respectively. Four methoxyl groups and one phenolic hydroxyl group are present, the alkaloid furnishing the O-methyl derivative, m.p. 172-3°C; [α]_D + 85° (c 0.57, CHCI 3) which also yields crystalline salts, e.g. the hydrochloride, m.p. 232-6°C (dec.) and the dimethiodide, m.p. 294-8°C (dec.); [α]_D + 47° (H20).

参考文献

McKennis et aI., 1. Arner. Chern. Soc., 78,245 (1956)
Grundon, McGarvey.,1. Chern. Soc., 27 39 (1960)
Hearst.,1. Org. Chern., 29,466 (1964)
Structure:
Grundon, McGarvey.,J. Chern. Soc., C, 1082 (1966)
Chan et ai., ibid, 2479 (1967)

ロジアシン 上流と下流の製品情報

原材料

準備製品

ロジアシン 生産企業

名前	電話番号	電子メール	国籍	製品カタログ	優位度

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• 6391-64-6
• 7-O-Methylantioquine
• Rodiasine
• 2H,16H-1,24-Etheno-6,10:11,15-dimethenopyrido[2',3':17,18]oxacycloeicosino[2,3,4-ij]isoquinolin-9-ol, 3,4,4a,5,16a,17,18,19-octahydro-12,21,22,26-tetramethoxy-4,17-dimethyl-, (4aR,16aS)-
• ロジアシン
• 7-O-メチルアンチオキン
• (1R,14S)-9,20,21,25-テトラメトキシ-15,30-ジメチル-23-オキサ-15,30-ジアザヘプタシクロ[22.6.2.13,7.18,12.114,18.027,31.022,33]ペンタトリアコンタ-3,5,7(35),8(34),9,11,18,20,22(33),24(32),25,27(31)-ドデカエン-6-オール