4-メチルモルホリンN-オキシド
4-メチルモルホリンN-オキシド 価格
もっと(19)
メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
富士フイルム和光純薬株式会社(wako)
|
W01AFAA19802 |
4-メチルモルホリンN-オキシド, 50% w/w aq. soln.
4-Methylmorpholine N-oxide, 50% w/w aq. soln. |
7529-22-8 |
100g |
¥10950 |
2024-03-01 |
購入 |
富士フイルム和光純薬株式会社(wako)
|
W01AFAA19802 |
4-メチルモルホリンN-オキシド, 50% w/w aq. soln.
4-Methylmorpholine N-oxide, 50% w/w aq. soln. |
7529-22-8 |
250g |
¥15440 |
2024-03-01 |
購入 |
東京化成工業
|
M0981 |
4-メチルモルホリン N-オキシド (50%水溶液, 約4.8mol/L)
4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L)
|
7529-22-8 |
25mL |
¥2600 |
2024-03-01 |
購入 |
東京化成工業
|
M0981 |
4-メチルモルホリン N-オキシド (50%水溶液, 約4.8mol/L)
4-Methylmorpholine N-Oxide (50% in Water, ca. 4.8mol/L)
|
7529-22-8 |
500mL |
¥9100 |
2024-03-01 |
購入 |
関東化学株式会社(KANTO)
|
20834-2A |
4‐メチルモルホリン4‐オキシド 97%
4‐Methylmorpholine 4‐oxide 97% |
7529-22-8 |
100g |
¥24530 |
2024-07-01 |
購入 |
4-メチルモルホリンN-オキシド 化学特性,用途語,生産方法
外観
白色~うすい黄褐色、結晶~結晶性粉末
用途
有機合成原料。
用途
N-メチルモルホリン N-オキシド (N-methylmorpholine N-oxide) は、有機化合物の一種で、有機合成において酸化剤として用いられる試薬。
化学的特性
Clear colorless to yellow solution
使用
4-Methylmorpholine N-Oxide is a metabolite of Morpholine (M723725). N-Methylmorpholine N-Oxide is commonly used to dissolve cellulose as well as in the dissolution of of scleroproteins.
一般的な説明
4-Methylmorpholine?
N-oxide is an organic compound used as a co-oxidant along with OsO
4 and ruthenates in organic synthesis. In recent studies, it has been used as a catalyst in silylcyanation of aldehydes and ketones. Lyocell, a regenerated cellulose fiber, can be prepared using 4-methylmorpholine?
N-oxide in an eco-friendly manner.
合成
A preparation method of N-methylmorpholine-N-oxide comprises the following steps: (1) adding the nano metal oxide into N-methyl morpholine (NMM) and mixing and stirring to uniformly mix the nano metal oxide with the NMM; (2) dropwise adding a hydrogen peroxide solution into a mixed solution of NMM and a catalyst; (3) raising the temperature to accelerate the reaction process; (4) and (4) filtering and distilling the solution prepared in the step (3) under reduced pressure to obtain the required NMMO solution. The method for preparing NMMO provided by the present disclosure has the advantages of a fast reaction rate, low reaction temperature, few byproducts, etc.
純化方法
When the oxide is dried for 2-3hours at high vacuum, it dehydrates. Add MeOH to the oxide and distil off the solvent under vacuum until the temperature is ca 95o. Then add Me2CO at reflux and cool to 20o. The crystals are filtered off, washed with Me2CO and dried. The degree of hydration may vary and may be important for the desired reactions. [van Rheenan et al. Tetrahedron Lett 1973 1076, Schneider & Hanze US Pat 2 769 823; see also Sharpless et al. Tetrahedron Lett 2503 1976.]
4-メチルモルホリンN-オキシド 上流と下流の製品情報
原材料
準備製品
4-メチルモルホリンN-オキシド 生産企業
Global( 444)Suppliers
4-メチルモルホリンN-オキシド スペクトルデータ(1HNMR、13CNMR、IR、Raman)
7529-22-8(4-メチルモルホリンN-オキシド)キーワード:
- 7529-22-8
- 4-methyl-morpholin4-oxide
- Morpholine, 4-methyl-, 4-oxide
- Morpholine,4-methyl-,4-oxide
- N-Methylmorpholine oxide
- N-METHYLMORPHOLINE 4-OXIDE
- NMO
- 4-METHYLMORPHOLINE N-OXIDE
- 4-METHYLMORPHOLINE 4-OXIDE
- METHYL MORPHOLINE OXIDE
- 4-MethylMorpholine N-Oxide 
- NSC 73198
- NSC 82153
- 4-METHYLMORPHOLINE N-OXIDE, 50 WT. % SOL UTION IN WATER
- 4-MethylMorpholine N-oxide, 50 wt.% solution in H2O
- 4-MethylMorpholine N-oxide solution 50 wt. % in H2O
- N- MethylMorpholine oxide -N-
- NMMO solution
- OTHER DERIVATIVES OF PYRIDINES STERO NMMO
- 4-Methylmorpholine N-oxide, w/w aq. soln.
- 4-Methylmorpholine N-oxide solution, 50 wt. % in water
- ine N-oxide
- 4-METHYLMORPHOLINE-4-OXIDE SOLUTION, ~50 % IN WATER
- N-MethylMorpholineOxide50%(Nmmo)
- 4-MethlMorpholine-N-Oxide99%
- N-Methyl morpholine-N-oxide, 60% w/w soln. in water
- N-MethylMorpholineOxide(NMMO)
- N-MethylmorpholineN-oxide,50%w/waq.soln.
- 4-methylmorpholine n-oxide solution
- nmo solution
- N-METHYLMORPHOLINE N-OXIDE: 50% W/W AQUEOUS SOLUTION
- 4-メチルモルホリンN-オキシド (50%水溶液, 約4.8mol/L)
- 4-メチルモルホリン=4-オキシド
- 4-メチルモルホリン4-オキシド
- 4-メチルモルホリン-4-オキシド
- 4-オキシラト-4-メチルモルホリン-4-イウム
- 4-メチル-4-オキシラトモルホリニウム
- N-メチルモルホリンN-オキシド
- 無水 4-メチルモルホリン N-オキシド
- 4-メチルモルホリン N-オキシド (50%水溶液, 約4.8mol/L)
- 4-メチルモルホリン N-オキシド
- 4‐メチルモルホリン4‐オキシド
- 4-メチルモルホリンN-オキシド, 50% W/W AQ. SOLN.
- 4-メチルモルホリンN-オキシド 溶液
- 4-メチルモルホリンN-オキシド
- 酸化反応
- 有機合成化学