ブチルリチウム

ブチルリチウム 価格 もっと(30)

メーカー	製品番号	製品説明	CAS番号	包装	価格	更新時間	購入
富士フイルム和光純薬株式会社(wako)	W01W0102-1907	1.6mol/L n-ブチルリチウム-ヘキサン溶液 1.6mol/L n-Butyllithium-Hexane Solution	109-72-8	100mL	￥8600	2024-03-01	購入
富士フイルム和光純薬株式会社(wako)	W01W0102-1907	1.6mol/L n-ブチルリチウム-ヘキサン溶液 1.6mol	109-72-8	250mL	￥13000	2024-03-01	購入
富士フイルム和光純薬株式会社(wako)	W01W0102-0585	1.6mol/l n-ブチルリチウム ヘキサン溶液 14.5～17.0% (Titration) 1.6mol/l n-Butyllithium Hexane Solution 14.5～17.0% (Titration)	109-72-8	250mL	￥11000	2023-06-01	購入
富士フイルム和光純薬株式会社(wako)	B4697	Butyllithium (ca. 20% in Cyclohexane, ca. 2.3mol	109-72-8	25ML	￥3100	2024-03-01	購入
富士フイルム和光純薬株式会社(wako)	B0396	Butyllithium (ca. 15% in Hexane, ca. 1.6mol	109-72-8	25ML	￥3000	2024-03-01	購入

ブチルリチウム MSDS

n-Butyllithium

ブチルリチウム 化学特性,用途語,生産方法

外観

うすい黄赤色～黄色～緑色透明液体～濁った液体

溶解性

水, アルコールにより分解。炭化水素, エーテルに易溶。炭化水素及びエーテル類に極めて溶けやすく、水によって急速に分解し、エタノール又は酸によって激しく分解する。

用途

有機合成試薬。

用途

共役ジエンのアニオン重合開始剤、飽和および不飽和カルボニル化合物のアルキル化反応などに用いられる。

使用上の注意

不活性ガス封入

化学的特性

n-Butyllithium is a colorless crystalline solid or clear yellow solution. Due to its high reactivity and extreme solubility, even in its impurities, it is commonly thought to be a viscous liquid.

使用

n-Butyllithium is used as a polymerization initiator in the production of elastomers like polybutadiene and styrene- butadiene- styrene. As a strong base, it is utilized in the synthesis of organic compounds. It undergoes thermal decomposition to prepare 1-butene.

製造方法

Industrially, n-butyllithium is produced by the reaction of n-butyl chloride with lithium metal dispersion in various hydrocarbon solvents. Hexane is the most commonly used solvent. Up to one-half of the lithium is replaced with sodium in order to lower the cost of the butyllithium and increase the reactivity of the dispersion. The reaction is carried out below the boiling point of the solvent.
The laboratory procedure is essentially the same except that pentane and diethyl ether are two of the more popular solvents. The preparation runs smoothly in ether at lower temperatures but the product must either be used immediately or kept refrigerated due to the rapid cleavage of ether by n-butyllithium.

燃焼性と爆発性

The risk of fire or explosion on exposure of butyllithium solutions to the atmosphere depends on the identity of the organolithium compound, the nature of the solvent, the concentration of the solution, and the humidity. t-Butyllithium solutions are the most pyrophoric and may ignite spontaneously on exposure to air. Dilute solutions (1.6 M, 15% or less) of n-butyllithium in hydrocarbon solvents, although highly flammable, have a low degree of pyrophoricity and do not spontaneously ignite. Under normal laboratory conditions (25 °C, relative humidity of 70% or less), solutions of -20% concentration will usually not ignite spontaneously on exposure to air. More concentrated solutions of n-butyllithium (50 to 80%) are most dangerous and will immediately ignite on exposure to air. Contact with water or moist materials can lead to fires and explosions, and the butyllithiums also react violently with oxygen.

貯蔵

In particular, butyllithium should be stored and handled in areas free of ignition sources, and containers of butyllithium should be stored under an inert atmosphere. Work with butyllithium should be conducted in a fume hood under an inert gas such as nitrogen or argon. Safety glasses, impermeable gloves, and a fire-retardant laboratory coat are required.

不和合性

The butyllithiums are extremely reactive organometallic compounds. Violent explosions occur on contact with water with ignition of the solvent and of the butane produced. t-Butyllithium will ignite spontaneously in air. The butyllithiums ignite on contact with water, carbon dioxide, and halogenated hydrocarbons. The butyllithiums are incompatible with acids, halogenated hydrocarbons, alcohols, and many other classes of organic compounds.

廃棄物の処理

Excess butyllithium solution can be destroyed by dilution with hydrocarbon solvent to a concentration of approximately 5 wt %, followed by gradual addition to water with vigorous stirring under an inert atmosphere. Alternatively, the butyllithium solution can be slowly poured (transfer by cannula for s- or tbutyllithium) into a plastic tub or other container of powdered dry ice.
The residues from the above procedures and excess butyllithium should be placed in an appropriate container, clearly labeled, and handled according to your institution's waste disposal guidelines.

ブチルリチウム 上流と下流の製品情報

原材料

準備製品

ブチルリチウム 生産企業

名前	電話番号	電子メール	国籍	製品カタログ	優位度
ShanDong Look Chemical Co.,Ltd.	+8617653113219	sales01@sdlookchemical.com	China	2737	58
LEAP CHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	24727	58
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8812	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5893	58
Anhui Ruihan Technology Co., Ltd	+8617756083858	daisy@anhuiruihan.com	China	973	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20287	58
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1803	55
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	FandaChem@Gmail.com	China	9214	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +8618949832763	info@tnjchem.com	China	2986	55

109-72-8(ブチルリチウム)キーワード:

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• 109-72-8
• LITHIUMBUTYL
• N-BUTYLLITHIUM
• BUTYLLITHIUM SOLUTION, ~2.7 M IN HEPTANE
• N-BUTYLLITHIUM, 2.2M SOLUTION IN CYCLOHEXANE
• n-Butyllithium1.6M solution in hexanesAcroSeal§3
• n-Butyllithium2.5M solution in hexanesAcroSeal§3
• n-Butyllithium2.2M solution in cyclohexaneAcroSeal§3
• n-Butyllithium2.6M solution in tolueneAcroSeal§3
• n-Butyllithium, 2.2M in hexane, packaged under Argon in resealable ChemSeal^t bottles
• n-Butyllithium, 2.5M solution in hexanes, AcroSeal?
• n-Butyllithium, 1.6M in hexane, packaged in resealable septum cap bottle
• n-Butyllithium, 2.5M in hexane, packaged in resealable septum cap bottle
• n-Butyllithium , 2.5M solution in hexanes [2.5M solution in hexanes]
• n-Butyllithium [2.4M solution in hexanes]
• n-Butyllithium, 1.6M soln. in hexanes
• n-Butyllithium, 2.5M soln. in hexanes
• n-Butyllithium solution, 2.5M in hexane
• n-Butyllithium solution, 1.6M in hexane
• n-Butyllithium solution, 2.2M in hexane
• n-Butyllithium, 2.6M solution in toluene
• n-Butyllithium,15%inhexane(1.6M)
• n-butyllithium, 1.6m in hexane
• n-butyllithium, 10.0m in hexanes
• n-butyllithium, 2.2m in hexane
• n-butyllithium, 2.2m in hexane, packaged under argon in resealable chemseal
• n-butyllithium, 2.5m in hexane
• BUTYLLITHIUM, 2.0M SOLUTION IN PENTANE
• BUTYLLITHIUM, 1.6M SOLUTION IN HEXANES
• BUTYLLITHIUM SOLUTION, ~1.6 M IN HEXANE
• BUTYLLITHIUM, 2.0M SOLUTION IN CYCLOHEXA NE
• ブチルリチウム (約15%ヘキサン溶液, 約1.6mol/L)
• N-ブチルリチウム
• nブチルリチウム
• N-ブチルリチウム,N-ヘキサン溶液,1.6MOL/L
• N-ブチルリチウム,N-ヘキサン溶液,2.6MOL/L
• ブチル リチウム
• n-ブチルリチウムヘキサン溶液
• ブチルリチウム (約20%シクロヘキサン溶液, 約2.3mol/L)
• ブチルリチウム
• N‐ブチルリチウム,N‐ヘキサン溶液,1.6MOL/L
• N‐ブチルリチウム,N‐ヘキサン溶液,2.6MOL/L
• ブチルリチウム(15%ヘキサン溶液)
• 1.6MOL/L N-ブチルリチウム ヘキサン溶液
• 1.6MOL/L N-ブチルリチウム-ヘキサン溶液
• ブチルリチウム 溶液
• リチウム化合物
• 典型金属化合物
• 構造分類
• 金属別化合物
• 有機合成化学
• アルキル金属
• グリニャール試薬 & アルキル金属