1,3,5-트라이메틸벤젠
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1,3,5-트라이메틸벤젠 속성
- 녹는점
- -45 °C
- 끓는 점
- 163-166 °C(lit.)
- 밀도
- 0.864 g/mL at 25 °C(lit.)
- 증기 밀도
- 4.1 (vs air)
- 증기압
- 14 mm Hg ( 55 °C)
- 굴절률
- n
20/D 1.499(lit.)
- 인화점
- 112 °F
- 저장 조건
- 2-8°C
- 용해도
- 알코올, 벤젠, 에테르(Windholz et al., 1983) 및 트리메틸벤젠 이성질체와 혼합 가능합니다.
- 물리적 상태
- 액체
- 산도 계수 (pKa)
- >14 (Schwarzenbach et al., 1993)
- 색상
- 무색의
- 폭발한계
- 0.88-6.1%, 100°F
- Odor Threshold
- 0.17ppm
- 수용성
- 2.9g/L(20℃)
- Merck
- 14,5907
- BRN
- 906806
- Henry's Law Constant
- 4.03, 4.60, 5.71, 6.73, and 9.63 at 10, 15, 20, 25, and 30 °C, respectively (EPICS, Ashworth et al.,1988)
- 노출 한도
- NIOSH REL: TWA 25 ppm (125 mg/m3); ACGIH TLV: TWA for mixed isomers 25 ppm (adopted).
- Dielectric constant
- 3.4(Ambient)
- 안정성
- 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다.
- InChIKey
- AUHZEENZYGFFBQ-UHFFFAOYSA-N
- LogP
- 3.42 at 20℃
- CAS 데이터베이스
- 108-67-8(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi,N,F,T | ||
---|---|---|---|
위험 카페고리 넘버 | 10-37-51/53-39/23/24/25-23/24/25-11-37/38 | ||
안전지침서 | 61-45-36/37-16-7 | ||
유엔번호(UN No.) | UN 2325 3/PG 3 | ||
OEB | A | ||
OEL | TWA: 25 ppm (125 mg/m3) | ||
WGK 독일 | 2 | ||
RTECS 번호 | OX6825000 | ||
F 고인화성물질 | 10 | ||
자연 발화 온도 | 1022 °F | ||
위험 참고 사항 | Irritant/Flammable | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | III | ||
HS 번호 | 29029080 | ||
유해 물질 데이터 | 108-67-8(Hazardous Substances Data) | ||
독성 | LD50 (inhalation) for rats 24 g/m3/4-h (quoted, RTECS, 1985). | ||
기존화학 물질 | KE-34411 |
1,3,5-트라이메틸벤젠 C화학적 특성, 용도, 생산
화학적 성질
Mesitylene is a clear, colorless liquid. Distinctive, aromatic odor.물리적 성질
Colorless liquid with a peculiar odor. An odor threshold concentration of 170 ppbv was reported by Nagata and Takeuchi (1990).용도
Mesitylene is used to make plastics and dyes. It acts as a solvent, ligand in organometallic chemistry and precursor to 2,4,6-trimethylaniline. It is also used as a developer for photopatternable silicones due to its solvent properties in the electronics industry. It is used as an internal standard in nuclear magnetic resonance (NMR) samples due to the presence of three equivalent protons in it. It is involved in the production of trimesic acid and antioxygen, epoxy firming agent and polyester resin stabilizers. Further, it is used as an additive and component in aviation gasoline blends.정의
ChEBI: A trimethylbenzene carrying methyl substituents at positions 1, 3 and 5.일반 설명
A colorless liquid with a peculiar odor. Insoluble in water and less dense than water. Flash point near 123°F. May be toxic by ingestion and inhalation. Used to make plastics and dyes.공기와 물의 반응
Flammable. Insoluble in water.반응 프로필
TRIMETHYLBENZENE is incompatible with the following: Oxidizers, nitric acid .위험도
Moderate fire hazard. Toxic by inhalation. Central nervous system impairment, asthma, and hematologic effects.건강위험
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.화재위험
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.Safety Profile
Poison by inhalation. Moderately toxic by intraperitoneal route. Human systemic effects by inhalation: sensory changes involving peripheral nerves, somnolence (general depressed activity), and structural or functional change in trachea or bronchi. Reports of leukopenia and thrombocytopenia in experimental animals. A mild skin and eye irritant. A flammable liquid when exposed to heat or flame; can react vigorously with oxidizing materials. Violent reaction with HNO3. To fight fire, use water spray, fog, foam, CO2. Emitted from modern buildmg materials (CENEAR 69,22,91). When heated to decomposition it emits acrid smoke and irritating fumes.잠재적 노출
Mesitylene is used as raw material in chemical synthesis and as ultraviolet stabilizer; as a paint thinner, solvent, and motor fuel component; as an intermediate in organic chemical manufacture.환경귀착
Biological. In anoxic groundwater near Bemidji, MI, 1,3,5-trimethylbenzene anaerobically biodegraded to the intermediate tentatively identified as 3,5-dimethylbenzoic acid (Cozzarelli et al., 1990).Photolytic. Glyoxal, methylglyoxal, and biacetyl were produced from the photooxidation of 1,3,5-trimethylbenzene by OH radicals in air at 25 °C (Tuazon et al., 1986a). The rate constant for the reaction of 1,3,5-trimethylbenzene and OH radicals at room temperature was 4.72 x 10-11 cm3/molecule?sec (Hansen et al., 1975). A rate constant of 2.97 x 10-8 L/molecule?sec was reported for the reaction of 1,3,5-trimethylbenzene with OH radicals in the gas phase (Darnall et al., 1976). Similarly, a room temperature rate constant of 6.05 x 10-11 cm3/molecule?sec was reported for the vapor-phase reaction of 1,3,5-trimethylbenzene with OH radicals (Atkinson, 1985). At 25 °C, a rate constant of 3.87 x 10-11 cm3/molecule?sec was reported for the same reaction (Ohta and Ohyama, 1985).
Chemical/Physical. 1,3,5-Trimethylbenzene will not hydrolyze because it does not contain a hydrolyzable functional group (Kollig, 1993).
운송 방법
UN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.Purification Methods
Dry it with CaCl2 and distil it from Na in a glass helices-packed column. Treat it with silica gel and redistil it. Alternative purifications include vapour-phase chromatography, or fractional distillation followed by azeotropic distillation with 2-methoxyethanol (which is subsequently washed out with H2O), drying and fractional distilling. More exhaustive purification uses sulfonation by dissolving in two volumes of conc H2SO4, precipitating with four volumes of conc HCl at 0o, washing with conc HCl and recrystallising from CHCl3. The mesitylene sulfonic acid is hydrolysed with boiling 20% HCl and steam distilled. The separated mesitylene is dried (MgSO4 or CaSO4) and distilled. It can also be fractionally crystallised from the melt at low temperatures. [Beilstein 5 IV 1016.]비 호환성
Vapors forms explosive mixture with air. Violent reaction with nitric acid. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides폐기물 처리
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.1,3,5-트라이메틸벤젠 준비 용품 및 원자재
원자재
1,2,4-트리메틸벤젠
Binder
2-Amino-3-chlorobenzoic acid
Heavy aromatics
프로필렌
에틸벤젠
나트륨
DOYLEDIRHODIUM촉매-RH2(4S-MEOX)4
1,2,4,5-사메틸 벤젠
준비 용품
1,3,5-트라이메틸벤젠 공급 업체
글로벌( 395)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
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SIMAGCHEM CORP | +86-13806087780 |
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Neostar United (Changzhou) Industrial Co., Ltd. | +86-519-519-85557386 |
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Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
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Taixing Foreign Trade Nanjing Co., Ltd. | +86-025-83346564; +8613182976929 |
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Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
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Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
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Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 |
sales@tjzxchem.com | China | 562 | 58 |