N- 프로필 아세테이트
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N- 프로필 아세테이트 속성
- 녹는점
- -95 °C (lit.)
- 끓는 점
- 102 °C (lit.)
- 밀도
- 0.888 g/mL at 25 °C (lit.)
- 증기 밀도
- 3.5 (vs air)
- 증기압
- 25 mm Hg ( 20 °C)
- 굴절률
- n
20/D 1.384(lit.)
- 인화점
- 55 °F
- 저장 조건
- Store below +30°C.
- 용해도
- 물에 용해
- 물리적 상태
- 액체
- 색상
- APHA: ≤15
- Specific Gravity
- 0.889 (20/4℃)
- 냄새
- 가벼운 과일향.
- 폭발한계
- 1.7%, 37°F
- Odor Threshold
- 0.24ppm
- ?? ??
- 과일 같은
- 수용성
- 2g/100mL(20℃)
- Merck
- 14,7841
- JECFA Number
- 126
- BRN
- 1740764
- Henry's Law Constant
- 5.54 at 37 °C (static headspace-GC, van Ruth et al., 2001)
- 노출 한도
- TLV-TWA 200 ppm (~840 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 250 ppm (~1050 mg/m3) (ACGIH); IDLH 8000 ppm (NIOSH).
- Dielectric constant
- 6.3(20℃)
- 안정성
- 안정적인. 가연성이 높습니다. 산화제와 격렬하게 반응할 수 있음. 공기와 폭발성 혼합물을 형성할 수 있음. 강한 산화제, 산, 염기와 호환되지 않습니다.
- LogP
- 1.4 at 25℃
- CAS 데이터베이스
- 109-60-4(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 11-36-66-67 | ||
안전지침서 | 16-26-29-33 | ||
유엔번호(UN No.) | UN 1276 3/PG 2 | ||
OEB | A | ||
OEL | TWA: 200 ppm (840 mg/m3), STEL: 250 ppm (1050 mg/m3) | ||
WGK 독일 | 1 | ||
RTECS 번호 | AJ3675000 | ||
자연 발화 온도 | 842 °F | ||
위험 참고 사항 | Irritant/Highly Flammable | ||
TSCA | Yes | ||
HS 번호 | 2915 39 00 | ||
위험 등급 | 3 | ||
포장분류 | II | ||
유해 물질 데이터 | 109-60-4(Hazardous Substances Data) | ||
독성 | LD50 in rats, mice (mg/kg): 9370, 8300 orally (Jenner) | ||
IDLA | 1,700 ppm | ||
기존화학 물질 | KE-29778 |
N- 프로필 아세테이트 C화학적 특성, 용도, 생산
물성
N- 프로필 아세테이트 (NPAC) 동의어 아세트산 프로필 에스테르; 프로필 에타 노 에이트; 배의 특징적인 냄새가 나는 깨끗하고 무색의 액체이다. 그것은 일반적으로 방향제와 향료 첨가제로 사용됩니다.용도
N-Propyl Acetate (NPAC)는 모든 일반적인 유기 용제 (알코올, 케톤, 글리콜, 에스테르)와 매우 혼합되지만 물에는 약간의 혼 화성이 있습니다. N-Propyl Acetate의 주요 용도는 코팅 및 인쇄 산업에서 용매로서 사용됩니다. 또한 에어로졸 스프레이, 네일 케어 및 향기 용제로 사용됩니다. 또한 배와 유사한 냄새 때문에 향료 첨가제로 사용할 수 있습니다. 주요 사용자 최종 시장은 인쇄, 코팅, 래커, 화장품 및 향료 산업입니다.용도
코팅제, 잉크, 니트로 페인트, 바니시 및 다양한 수지 용제로 널리 사용되며 향료 및 향료 업계에서 사용됩니다.포장, 보관 및 운송
저장은 일반적으로 차가운 건조하고 통풍이 잘되는 곳에서 산화제가 떨어져 있어야합니다. 정상 프로필 아세테이트는 직사광선, 열 및 화염에 노출되지 않도록해야합니다.개요
Propyl acetate, also known as propyl ethanoate, is an organic compound with a molecular formula of C5H10O2. It is a clear and colourless liquid with with a mild fruity odor. It is highly flammable with a flash point of 14°C and a flammability rating of 3. It is highly miscible with all common organic solvents (alcohols, ketones, glycols, esters) but has only slight miscibility in water. Propyl acetate is found in apple and formed by the esterification of acetic acid and 1-propanol (known as acondensation reaction), often via Fischer–Speier esterification, with sulfuric acid as a catalyst and water produced as a byproduct. It is primarily intended as a solvent in the coatings and printing inks industries. It is widely used in fragrances and as a flavor additive due to its odor. It also acts as a good solvent for cellulose nitrate, acrylates, alkyd resins, rosin, plasticizers, waxes, oils and fats.화학적 성질
Propyl acetate has a fruity (pear–raspberry) odor with a pleasant, bittersweet flavor reminiscent of pear on dilution. The Odor Threshold is 70 milligram per cubic meter and 2.8 milligram per cubic meter (New Jersey Fact Sheet).물리적 성질
Clear, colorless, flammable liquid with a pleasant, pear-like odor. Experimentally determined detection and recognition odor threshold concentrations were 200 μg/m3 (48 ppbv) and 600 μg/m3 (140 ppbv), respectively (Hellman and Small, 1974). An odor threshold concentration of 240 ppbv was determined by a triangular odor bag method (Nagata and Takeuchi, 1990). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 17,575 ppmv.출처
Reported found in apple, apple juice, apricot, banana, black currants, guava, grapes, melon, peach, pears, pineapple, plum, strawberry, tomato, vinegar, wheat and rye bread, feta cheese, Gruyere cheese, domiati cheese, yogurt, beef fat, beer, cognac, bourbon and malt whiskey, cider, grape wines, cocoa, potato chips, honey, passion fruit, starfruit, fig, prickly pear, jackfruit, litchi, sake, loquat, mountain papaya, arrack, nectarine and pepino fruit.용도
n-Propyl acetate is used as a solvent for cellulose derivatives, plastics, and resins; in flavors and perfumes; and in organic synthesis.제조 방법
Propyl Acetate is formed by the esterification of acetic acid and 1-propanol with sulfuric acid as a catalyst and water produced as a byproduct. or By direct acetylation of propyl alcohol.생산 방법
n-Propyl acetate is manufactured from acetic acid and a mixture of propene and propane in the presence of a zinc chloride catalyst. It is used as a solvent for nitrocellulose- based lacquers, waxes, polyamide inks, acrylic inks, and insecticide formulations .Manufacturers include Eastman Chemical Company, Hoechst Celanese Corporation, and Union Carbide Corporation.
정의
ChEBI: Propyl acetate is an acetate ester obtained by the formal condensation of acetic acid with propanol. It has a role as a fragrance and a plant metabolite. It derives from a propan-1-ol.일반 설명
N-propyl acetate appears as a clear colorless liquid with a pleasant odor. Flash point 58°F. Less dense than water, Vapors are heavier than air.공기와 물의 반응
Highly flammable. Slightly soluble in water.반응 프로필
Propyl acetate is an ester. Propyl acetate is colorless, highly flammable liquid, moderately toxic. Dangerous fire hazard when exposed to heat, flame, sparks, or strong oxidizers. When heated to decomposition Propyl acetate emits acrid smoke and irritating fumes [Lewis, 3rd ed., 1993, p. 1093].위험도
Flammable, dangerous fire risk, explosive limits in air 2–8%. Eye and upper respiratory tract irritant.건강위험
The acute toxicity of n-propyl acetate islow in test animals. The toxicity, however,is slightly greater than ethyl acetate andisopropyl acetate. Exposure to its vaporsproduces irritation of the eyes, nose, andthroat and narcotic effects. A 5-hour expo sure to 9000- and 6000-ppm concentrationsproduced narcotic symptoms in cats andmice, respectively (Flury and Wirth 1933).A 4-hour exposure to 8000 ppm was lethalto rats. Ingestion of the liquid can cause narcotic action. A high dose can cause death. Adose of 3000 mg/kg by subcutaneous admin istration was lethal to cats. The liquid maycause mild irritation upon contact with skinLD50 value, oral (mice): 8300 mg/kg.
화재위험
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.Safety Profile
Moderately toxic by intraperitoneal and subcutaneous routes. Mildly toxic by ingestion and inhalation. Human systemic effects by inhalation: lachrymation, cough. A skin irritant. A narcotic at high concentrations. Isopropyl acetate is slightly less narcotic than normal propyl acetate. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidizers. Explosive in the form of vapor when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.잠재적 노출
Propyl acetate is a used as a solvent for plastics and cellulose ester resins; perfume ingredient; component of food flavoring. It is also used as a chemical intermediate.환경귀착
Photolytic. Reported rate constants for the reaction of n-propyl acetate and OH radicals in the atmosphere and aqueous solution are 2.7 x 10-12 cm3/molecule?sec (Hendry and Kenley, 1979) and 2.30 x 10-13 cm3/molecule?sec (Wallington et al., 1988b).Chemical/Physical. Slowly hydrolyzes in water forming acetic acid and 1-propanol.
At an influent concentration of 1,000 mg/L, treatment with GAC resulted in an effluent concentration of 248 mg/L. The adsorbability of the carbon used was 149 mg/g carbon (Guisti et al., 1974).
운송 방법
UN1276 n-Propyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid.Purification Methods
Wash the ester with saturated aqueous NaHCO3 until neutral, then with saturated aqueous NaCl. Dry it with MgSO4 and fractionally distil it. [Beilstein 2 IV 138.]비 호환성
Contact with nitrates, strong oxidizers; strong alkalis; strong acids; may pose risk of fire and explosions. Attacks plastic.폐기물 처리
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.N- 프로필 아세테이트 준비 용품 및 원자재
원자재
준비 용품
N- 프로필 아세테이트 공급 업체
글로벌( 635)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Shandong Yanshuo Chemical Co., Ltd. | +86-18678179670 +86-18615116763 |
sales@yanshuochem.com | China | 101 | 58 |
Henan Xiangduo Industry Co., Ltd. | +86-15981848961 +86-15981848961 |
sales@xiangduochem.com | China | 497 | 58 |
Yixing Wencheng Chemical Co., Ltd | +undefined+86-13961572207 |
David@un-wencheng.com | China | 124 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 |
abby@weibangbio.com | China | 8807 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5889 | 58 |
AS WATER CO., LTD. | +86-18994963526 +8618994963526 |
1346073549@qq.com | United Kingdom | 176 | 58 |
Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 |
sales@qdrenas.com | China | 476 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21634 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29880 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |