p-Anisaldehyde manufacturers and suppliers

p-Anisaldehyde suppliers

Properties

Melting point:: -1 °C

Boiling point:: 248 °C(lit.)

Density: 1.121

vapor density: 4.7 (vs air)

vapor pressure: <1 hPa (20 °C)

refractive index: n20/D 1.573(lit.)

FEMA: 2670 | P-METHOXYBENZALDEHYDE

Flash point:: 228 °F

storage temp.: Store below +30°C.

solubility: 2g/l

form: Liquid

color: Clear colorless to yellow

PH: 7 (2g/l, H2O, 20℃)

Odor: sweetish odor

explosive limit: 1.4-5.3%(V)

Odor Type: anisic

Water Solubility: Miscible with acetone, alcohol, ether, chloroform and benzene. Immiscible with water.

Decomposition: > 160°C

Sensitive: Air Sensitive

Merck: 14,663

JECFA Number: 878

BRN: 471382

Dielectric constant: 15.8（20℃）

InChIKey: ZRSNZINYAWTAHE-UHFFFAOYSA-N

LogP: 1.56 at 25℃

CAS DataBase Reference: 123-11-5(CAS DataBase Reference)

NIST Chemistry Reference: Benzaldehyde, 4-methoxy-(123-11-5)

EPA Substance Registry System: Benzaldehyde, 4-methoxy- (123-11-5)

Safety Information

Symbol(GHS): GHS07,GHS02,GHS05,GHS08

Signal word: Danger

Hazard statements: H412

Precautionary statements: P273-P501

Hazard Codes: Xn,Xi,T,F

Risk Statements: 22-36/37/38-39/23/24/25-23/24/25-11-R22-36/38

Safety Statements: 26-36-45-36/37-16-7

WGK Germany: 1

RTECS: BZ2625000

F: 10-23

Autoignition Temperature: 220 °C

TSCA: Yes

HazardClass: IRRITANT

HS Code: 29124900

Hazardous Substances Data: 123-11-5(Hazardous Substances Data)

Toxicity: LD50 orally in rats: 1510 mg/kg (Jenner)

Use

p-Anisaldehyde occurs in many essential oils, often together with anethole. It is a colorless to slightly yellowish liquid with a sweet, mimosa, hawthorn odor. p-Anisaldehyde can be hydrogenated to anise alcohol and readily oxidizes to anisic acid when exposed to air. Synthetic routes to anisaldehyde start from p-cresyl methyl ether, which is oxidized, for example, by manganese dioxide or by oxygen or peroxy compounds in the presence of transition metal catalysts .Another industrial process uses electrochemical oxidation in the presence of lower aliphatic alcohols via the corresponding anisaldehyde dialkyl acetal . Anisaldehyde may also be produced by methylation of 4-hydroxybenzaldehyde, which is easily obtained by oxidation of p-cresol or by Vilsmeier formylation of anisol.

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