1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE
|
- $160 - $1280
- Product name: 1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE
- CAS: 10000-20-1
- MF: C12H32N2Si2
- MW: 260.57
- EINECS:
- MDL Number:MFCD07369154
- Synonyms:1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE;Hydrazine, 1,2-bis[(1,1-dimethylethyl)dimethylsilyl]-
9 prices
Selected condition：
Brand
- AK Scientific
- American Custom Chemicals Corporation
- Biosynth Carbosynth
- Medical Isotopes, Inc.
- TRC
Package
- 250MG
- 500mg
- 1g
- 2g
- 5G
- ManufacturerAK Scientific
- Product number0239CT
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging500mg
- Price$455
- Updated2021-12-16
- Buy
- ManufacturerAmerican Custom Chemicals Corporation
- Product numberORS0003707
- Product description1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE 95.00%
- Packaging250MG
- Price$284.55
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB18753
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging250mg
- Price$160
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB18753
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging500mg
- Price$250
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB18753
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging1g
- Price$380
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB18753
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging2g
- Price$700
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB18753
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging5G
- Price$1280
- Updated2021-12-16
- Buy
- ManufacturerMedical Isotopes, Inc.
- Product number7455
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging1g
- Price$490
- Updated2021-12-16
- Buy
- ManufacturerTRC
- Product numberB415375
- Product description1,2-Bis-(tert-butyldimethylsilyl)hydrazine
- Packaging1g
- Price$215
- Updated2021-12-16
- Buy
| Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|
| AK Scientific | 0239CT | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 500mg | $455 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | ORS0003707 | 1,2-BIS-(TERT-BUTYLDIMETHYLSILYL)HYDRAZINE 95.00% | 250MG | $284.55 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 250mg | $160 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 500mg | $250 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 1g | $380 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 2g | $700 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB18753 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 5G | $1280 | 2021-12-16 | Buy |
| Medical Isotopes, Inc. | 7455 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 1g | $490 | 2021-12-16 | Buy |
| TRC | B415375 | 1,2-Bis-(tert-butyldimethylsilyl)hydrazine | 1g | $215 | 2021-12-16 | Buy |
Properties
Boiling point :60-62°C/ 1-2 mm Hg
Density :0.825±0.06 g/cm3(Predicted)
storage temp. :Refrigerator, Under Inert Atmosphere
solubility :Chloroform (Slightly)
form :Oil
pka :10.62±0.70(Predicted)
color :Colourless
Density :0.825±0.06 g/cm3(Predicted)
storage temp. :Refrigerator, Under Inert Atmosphere
solubility :Chloroform (Slightly)
form :Oil
pka :10.62±0.70(Predicted)
color :Colourless
Safety Information
| Symbol(GHS): | ||||||||
|---|---|---|---|---|---|---|---|---|
| Signal word: | ||||||||
| Hazard statements: |
|
|||||||
| Precautionary statements: |
|
Description
1,2-Bis(t-butyldimethylsilyl)hydrazine is a source of latent hydrazine used in the preparation of stable alkyl and aryl N-silyl hydrazones, gem-dihalides, vinyl halides, and room temperature Wolff–Kishner reductions.Wolff–Kishner Reduction.
A particularly useful reaction of the N-silyl hydrazones is their use as substrates in the Wolff– Kishner reaction, where reduction of the corresponding carbonyl compound can be accomplished at relatively modest temperatures. This is in marked contrast to the more traditional Wolff– Kishner reaction, and its Huang–Minlon modification, which require high temperatures and the use of potassium hydroxide.Room temperature conditions for the Wolff–Kishner reaction, previously reported by Cram and co-workers, were adapted by Myers and Furrow to the current N-silyl hydrazone methodology (eq 4).
